제49회 전국과학전람회 신제3기 흥해층에서 산출되는 거대 단괴(giant … · H...

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제49회 전국과학전람회 신제3기 흥해층에서 산출되는 거대 단괴(giant nodule) 생성 메카니즘 연구 (소 속) (직 위) 대구광역시 중리중학교 화원중학교 교사 교사 박희숙 손동일

Transcript of 제49회 전국과학전람회 신제3기 흥해층에서 산출되는 거대 단괴(giant … · H...

  • 2502

    49

    3

    (giant nodule)

    ( ) ( )

  • . 1

    . 1

    1. 1

    2. 1

    3. 1

    4. 2

    5. 3

    . 8

    1. 8

    1. 8

    2. 14

    3. 14

    4. 17

    2. 19

    1. 19

    2. 20

    3. 23

    1. XRF(X-ray fluorescence) 23

    2. XRD(X-ray Diffractometer: X ) 31

    4. 33

    . 38

    . 39

    40

    Plates 43

  • 1. 4

    2. 4

    3. 5

    4. Location 1 9

    5. Location 2 9

    6. Location 3 10

    7. Location 4 11

    8. Location 5 12

    9. Location 6 13

    10. 14

    11. 15

    12. 16

    13. 16

    14. 17

    15. - 18

    16. 19

    17. Septarian Nodule 19

    18. (diatom) 20

    19. 20

    20. Bedded Nodule 21

    21. 21

    22. Spherical Nodule 21

    23. - (open nicols) 22

    24. Septarian Nodule 24

  • 25. XRF 25

    26. Spherical Nodule 26

    27. Spherical Nodule 28

    28. Bedded Nodule 29

    29. mudstone mudstone 30

    30. XRD 31

    31. Spherical Nodule 35

    32. Bedded Nodule 36

    33. Septarian Nodule 37

    1. Tertiary Stratigraphy in the Pohang Area 6

    2. Stratigraphy of Pohang District 7

    3. 15

    4. mustone XRF (Nore -) 24

    5. Spherical Nodule XRF 27

    6. Spherical Nodule XRF 27

    7. Bedded Nodule XRF 29

    8. XRF 29

    9. mudstone mudstone 30

  • - 1 -

    .

    3

    .

    .

    , ,

    , .

    ,

    Hwang(1993) (1994) .

    ,

    .

    3 ,

    ,

    .

    3 (giant nodule)

    , ,

    .

    .

    1.

    1km

    1km 1 6

    .

    2.

    3 (giant nodule)

    3.

    1999 3 2003 8

  • - 2 -

    4.

    ,

    .

    Endo (1938, 1939, 1943, 1950,

    1953) , , 3

    Carpinus 4, Porana 1, Acer 5, Glyptostrobus orientalis

    . Kanehara (1935) 1:100,000

    50

    . Tanai (1953) Endo

    14 . 2(1964) 1:50,000

    , , , , ,

    .

    (1965, 1970, 1977, 1979) 66 179

    3 , , ,

    , 3 ,

    , , , , . Huzioka (1972) Oishi

    Endo 3 45 79 140

    3 5, 7

    .

    2(1992)

    . 10cm

    5m .

    , ,

    .

    2(2003 3)

    .

    4

    (type) , .

    /

    .

    .

    3 ,

    (), (), () ()

    (Yoon, S., 1975; Yoon, S., 1992b). (1964) ()

    () .

  • - 3 -

    1km

    3 E 12920 E 12925, N 3600 N 360

    5 .

    ( , 1964) ,

    .

    Propeamussium , Conchocele -

    Calyptogena Patinopecten-Modiolus

    (Yoon, S., 1979), (Yi, S. and Yun, H., 1995), (Kim,

    B.K., 1965), (Byun, H., 1995) .

    1, 2 .

    1:50,000 1:10,000

    10m

    .

    .

    ,

    , , .

    .

    6 Loc.3

    Loc.4

    .

    5.

    .

    .

    .

    .

  • - 4 -

    12 34 5

    6

    12 34 5

    6

    1.

    2.

  • - 5 -

    3.

    1: , 2: , 3: , 4: , 5: , 6: , 7: , 8:

    , 9: , 10: , 11; , 12: , 13: , 14:

    , 15: , 16: , 17: , 18: , 19: , 20:

    , 21: , 22: , BG: , HG: , Ib:, Yo:

    (Yoon, 1992b )

  • - 6 -

    1. Tertiary Stratigraphy in the Pohang Area

    Geologic

    age

    Stratigraphic terminology

    Thickness

    (meters)Um et al. (1964) ;

    Reedman & Um (1975)Kim (1965, 1970)

    Miocene

    Yeonil

    Group

    Yeonam

    Formation

    Yeonil

    Group

    Oomockdong

    Formation50

    Duho FormationPohang

    Formation150 - 280

    Eedong

    Formation

    Eedong

    Formation150 - 200

    Hyunghae

    Formation

    Daegock

    Formation180 - 200

    Hagrim

    Formation

    Songhacdong

    Formation100 - 180

    Cheonbug

    Conglomerate

    Seoan

    Conglomerate120 - 250

    (Garrison et al., 1979)

  • - 7 -

    2. Stratigraphy of Pohang District

    Quaternary Alluvium

    Dilluvium

    Unconformity

    Yeonil Basalt & two pyroxene andesite

    Intrusion

    Basalt

    Intrusion

    Pohang Formation

    Terdtiary Eedong Formation

    Hyunghae Formation Yeonil Group

    Songhackdong Formation

    Seoam Conglomerate

    Relation unknown

    Nultairi trachyte Changgi Group

    Nultairi trachte tuffite

    Unconformity

    Quartz vein

    Liparite

    Felsite Bulgugsa Igneous rocks

    Biotite granite

    Cretaceous Agglomerate quartz porphyry

    Intrusion

    Purple shale & grey sandstone-Gyeongsang Group

  • - 8 -

    .

    1

    1. 1999 3 2003 8 .

    1:25,000 2 rout map .

    3 (giant nodule)

    ( 2)

    .

    2. 300

    150

    .

    3. ,

    , ,

    , / / .

    .

    4.

    ,

    .

    1. (giant nodule)

    6 .

    . Location 1

    N 52E, 20SE

    .

    (nodule) .

  • - 9 -

    [ 4-a]

    - 150 cm, - 50 cm

    sea level 1655 825 cm

    ,

    .

    .

    [ 4-b]

    - 320 cm, - 100 cm

    [Fig. 1-a] 12m sea

    level 800 cm .

    - 60 cm, - 3040 cm

    [Fig. 1-b] 20 cm sea

    level 770 cm .

    [ 4-c] . - . - 500 cm

    , sea level 200 cm . - - 200 cm

    , () . .

    . Location 2

    N 50E, 16SE .

    [ 5]

    100 cm, 50 cm .

    , .

    .

  • - 10 -

    . Location 3

    N 42E, 14SE, 17 m .

    5 .

    [ 6-a]

    - 200 cm, - 80 cm

    .

    [ 6-b]

    [Fig. 3-a] 5 m .

    - 400 cm, - 200 cm

    .

    [ 6-c]

    - 170 cm, - 110 cm

    [Fig. 3-b] 50 cm .

    ,

    ,

    .

    [ 6-d]

    - 110 cm, - 60 cm

    .

    [ 6-e]

    & & .

    .

    [ 6-e]

  • - 11 -

    [ 6-e]

    [ 6-e]

    . Location 4

    N 50E, 18SE, 10 m.

    , .

    [ 7-a]

    nodule

    , .

    .

    2

    .

    [ 7-b]

    .

    .

    . Location 5

    .

    N52E, 16SE, 16m.

    (nodule) .

  • - 12 -

    [ 8-a]

    sea level 160 cm

    - 1000 cm, - 120 cm

    .

    [ 8-b]

    sea level 100 cm

    - 450 cm, - 120 cm

    [ 8-c]

    - 200 cm, - 120 cm

    .

    [ 8-d]

    - 720 cm, - 150 cm

    cone-in-cone

    .

    [ 8-e]

    sea level 3 m

    - 150 cm, - 100 cm

    [ 8-e]

    nodule

    . Location 6

    N48E, 15SE .

    (nodule) , ,

    .

  • - 13 -

    nodule : , 10

    m.

    nodule : .

    nodule : - 1000 cm, - 160 cm

    nodule : - 180 cm, - 80 cm

    nodule : ,

    - 700 cm, - 80 cm

    nodule : - 700 cm, - 120 cm

    nodule : - 350 cm, - 150 cm

    nodule : - 300 cm, - 100 cm

    [ 9-a]

    nodule

    [ 9-a]

    Fig. 6-a

  • - 14 -

    2.

    10

    , (, ) = (60cm, 35cm)(1000cm, 160cm)

    .

    10.

    3.

    3 . ,

    /, , / .

    Septarian Nodule

    .

    3 ,

    ,

    .

    /, ,

    / Spherical Nodule .

    Bedded Nodule .

    2

    .

    , /, , /

    .

    40% . 10, 11, 12, 13, 3

    , cm 10m .

  • - 15 -

    11.

    3.

    nodule 1- 150 50 0.67 /

    nodule 1- 320 100 0.68 /

    nodule 1- 60 35 0.42

    nodule 1- 500 200 0.60

    nodule 2- 100 50 0.50

    nodule 3- 200 80 0.60

    nodule 3- 400 200 0.50

    nodule 3- 170 110 0.35 /

    nodule 3- 110 60 0.45

    nodule 5- 1000 120 0.88

    nodule 5- 450 120 0.73 /

    nodule 5- 200 120 0.40 /

    nodule 5- 720 150 0.79 /

    nodule 5- 150 100 0.33 /

    nodule 6- 1000 160 0.84

    nodule 6- 180 80 0.56

    nodule 6- 700 80 0.89

    nodule 6- 700 120 0.83

    nodule 6- 350 150 0.57

    nodule 6- 300 100 0.67 /

    388.00 109.25 0.61 /

    / : 0.20.4 : 0.40.6

    / : 0.60.8 : 0.81

  • - 16 -

    Spherical

    Nodule

    /

    /

    Bedded

    Nodule

    .

    Septarian Nodule

    12.

    13.

  • - 17 -

    4.

    .

    .

    .

    ,

    ,

    ( 14&15).

    Spherical NoduleSpherical Nodule

    14.

    (A), (B) Spherical Nodule .

    (C) Spherical Nodule .

    (D) Bedded Nodule .

  • - 18 -

    15. -

    1. 3 , cm

    10m . , ,

    Spherical Nodule, Bedded Nodule, Septarian Nodule

    Spherical Nodule .

    2.

    ,

    .

  • - 19 -

    2

    ,

    ,

    .

    .

    .

    1.

    . , , , ,

    .

    ( 16). Septarian Nodule

    ( 17).

    16.

    (A) . (B) . (C) .

    17. Septarian Nodule

    (A) Septarian Nodule. (B) . (C) .

    5cm 1cm 5cm

    1cm1cm

    A B C

    A B C

  • - 20 -

    . ,

    ( 18).

    18. (diatom)

    . , ,

    .

    2.

    .

    .

    , .

    Septarian Nodule ( 19).

    19.

    (A) Spherical Nodule .

    (B) Septarian Nodule : Dolomite(D), Smectite(S), Tridymite(T)

    (C) .

    . ,

    Bedded Nodule

    ( 20).

    0.01mm0.01mm 0.01mm

    A B C

    0.01mm 0.01mm 0.01mm

    A B C

    D

    T S

  • - 21 -

    20. Bedded Nodule (A) . (B) - . (C) .

    . Spherical Nodule

    ,

    ( 21&22).

    10

    11

    5

    12

    13

    1 2 3 4 6 7 8 9

    21.

    22. Spherical Nodule (A) #2. (B) #5. (C) #8. (D) #10.

    0.01mm 0.01mm 0.01mm

    A B C

    0.01mm 0.01mm

    0.01mm 0.01mm

    A B

    DC

  • - 22 -

    .

    , ( 23).

    23. - (open nicols)(A) Spherical Nodule . (B) Spherical Nodule .

    . Septarian Nodule

    .

    Location 3 N29

    1 ,

    2 . ,

    ( 24).

    24. Septarian Nodule (A) . (B) (A) . (C)

    . (D) (C) 2 tridymite smectite.

    0.01mm 0.01mm

    A B

    0.01mm 0.01mm

    0.04mm1cm

    A B

    DC T S

    D

    D

    D

    TS

  • - 23 -

    1. , ,

    , Mg 30%

    .

    2. ,

    Septarian Nodule .

    Bedded

    Nodule . Septarian Nodule

    .

    3

    1.

    80

    XRF(X-ray fluorescence) .

    2.

    ,

    XRD(X-ray Diffractometer: X ) .

    3.

    .

    1. XRF(X-ray fluorescence)

    . mudstone

    4 .

  • - 24 -

    4. mudstone XRF (Norm -)

    Constituent Mudstone Nod 1 Nod 10 Nod 14 Nod 23 Nod 29 Nod 32 Nod 39 Nod 45 Nod 49 Nod 57 Nod 61 Nod 68

    SiO2 84.56 7.80 10.40 10.44 13.51 11.06 9.26 10.46 11.94 11.22 9.99 10.46 9.28

    Al2O3 7.8 2.68 3.00 3.01 2.79 2.46 3.77 1.76 3.44 3.16 3.36 1.78 3.18

    Fe2O3 4.37 3.95 6.55 7.01 6.29 6.21 6.56 2.03 6.54 7.55 4.06 2.04 8.62

    Cl 0.43 - - - - - - - - - - - -

    MgO - 32.36 30.12 29.64 28.01 30.12 29.66 33.70 26.97 26.88 32.35 32.72 26.84

    CaO 0.20 51.91 48.45 48.51 47.55 48.77 48.58 50.77 49.60 49.22 48.44 51.76 50.42

    K2O 1.51 0.33 0.46 0.45 0.48 0.47 0.49 0.35 0.53 0.48 0.43 0.30 0.48

    TiO2 0.31 - - - - - - - - - - - -

    P2O3 0.30 0.19 0.22 0.23 0.33 0.22 0.23 0.26 0.27 0.22 0.31 0.25 0.26

    SO3 0.53 0.50 0.59 0.52 0.51 0.50 0.51 0.44 0.53 0.60 0.60 0.46 0.70

    SrO - 0.28 0.21 0.18 0.18 0.22 0.23 0.22 0.18 0.21 0.22 0.23 0.23

    Total 100.01 100 100 99.99 99.65 100.03 99.29 99.99 100 99.54 99.76 100 100.01

    4

    . Si mudstone 80%

    10% , Ca mudstone

    50% .

    Mg 30% mudstone

    .

    (open system)

    ( 25).

    2

    . Ca 50%

    ,

    Ca .

  • - 25 -

    25-a. XRF - Si

    Si mudstone 80%

    10% data .

    mudstone Si

    .

    25-b. XRF - Ca

    Ca mudstone

    , Ca 50%

    .

    25-c. XRF - Mg

    Mg mudstone

    , Mg 30%

    .

    25-d. XRF - Fe

    Fe

    mudstone .

    25-e. XRF - Al

    Al

    mudstone 23

    . mudstone Al

    .

    25-f. XRF - K

    K mudstone

    mudstone

    35 . mudstone

    K

    .

  • - 26 -

    25-g. XRF - Ti

    Ti mudstone

    Ti

    .

    25-h. XRF -Sr

    Sr mudstone

    .

    25-i. XRF - P

    P

    mudstone .

    25-j. XRF - S

    S

    mudstone .

    . Spherical Nodule

    , XRF 5, 6, 7, 8 .

    10

    11

    5

    12

    13

    1 2 3 4 6 7 8 9

    26. Spherical Nodule

  • - 27 -

    5. Spherical Nodule XRF

    Constituent 1 2 3 4 5 6 7 8 9

    MARGIN CORE MARGIN

    SiO2 13.16 15.93 16.75 16.97 17.63 17.01 16.57 16.73 15.69

    Al2O3 1.93 1.78 1.72 1.83 2.50 1.88 1.75 1.97 1.89

    Fe2O3 5.24 3.53 3.33 2.85 2.31 3.86 4.22 4.58 6.08

    Cl - - - - - - - - -

    MgO 27.23 27.91 28.13 29.43 30.11 28.17 27.90 27.19 27.11

    CaO 50.12 49.02 47.91 47.78 46.26 47.66 47.87 47.97 47.52

    K2O 0.36 0.40 0.34 0.39 0.53 0.28 0.37 0.33 0.33

    TiO2 - - - - - - - - -

    P2O3 0.49 0.56 0.46 0.48 0.45 0.46 0.62 0.48 0.45

    SO3 0.81 0.67 0.67 0.65 0.59 0.59 0.61 0.66 0.71

    SrO 0.21 0.19 0.21 0.22 0.18 0.19 0.18 0.18 0.17

    Total 99.55 99.8 99.52 100.38 100.38 99.91 99.91 99.91 99.78

    6. Spherical Nodule XRF

    Constituent 10 11 5 12 13

    MARGIN CORE MARGIN

    SiO2 15.32 16.26 18.63 16.38 13.01

    Al2O3 2.42 2.03 2.50 1.87 2.59

    Fe2O3 5.13 1.98 3.33 2.33 6.47

    Cl - - - - -

    MgO 26.32 28.65 27.91 28.23 27.04

    CaO 48.39 47.45 45.76 48.92 48.52

    K2O 0.50 0.33 0.59 0.30 0.48

    TiO2 - - - - -

    P2O3 0.53 0.47 0.50 0.50 0.52

    SO3 1.32 0.62 0.67 0.57 0.67

    SrO 0.18 0.21 0.18 0.21 0.21

    Total 99.93 97.79 99.89 99.1 99.3

  • - 28 -

    27. Spherical Nodule

    (A) Mg. (B) Fe. (C) Si. (D) S.

    Spherical Nodule

    27

    . Spherical Nodule Ca

    Mg . Mg

    . Fe

    . 2

    XRF Fe

    .

    Si .

    . ,

    .

    A B

    DC

  • - 29 -

    7. Bedded Nodule XRF 8. XRF

    Constituent 1 2 3 4 5

    MARGIN CORE

    SiO2 14.16 14.93 15.75 16.07 16.12

    Al2O3 1.72 1.88 1.93 2.06 2.60

    Fe2O3 6.14 5.53 3.88 3.49 2.29

    Cl - - - - -

    MgO 27.23 27.86 28.88 29.11 29.76

    CaO 48.88 47.98 47.91 47.78 47.86

    K2O 0.36 0.39 0.34 0.35 0.43

    TiO2 - - - - -

    P2O3 0.53 0.51 0.46 0.48 0.44

    SO3 0.85 0.67 0.60 0.52 0.49

    SrO 0.21 0.19 0.21 0.22 0.18

    Total 100.08 99.75 99.96 99.86 99.99

    Constituent 10 11 5

    MARGIN CORE

    SiO2 15.32 16.36 16.12

    Al2O3 2.42 2.13 2.60

    Fe2O3 5.56 3.88 2.29

    Cl - - -

    MgO 26.38 28.75 29.76

    CaO 48.11 47.35 47.86

    K2O 0.50 0.43 0.43

    TiO2 - - -

    P2O3 0.43 0.47 0.44

    SO3 1.28 0.62 0.49

    SrO 0.18 0.21 0.18

    Total 100 99.99 99.99

    28. Bedded Nodule

    (A) Mg. (B) Fe. (C) Si. (D) S.

    Bedded Nodule

    Spherical Nodule , 28

    . Spherical Nodule

    Ca Mg . Bedded Nodule Spherical

    Nodule . , Bedded Nodule

    Spherical Nodule .

    A B

    DC

  • - 30 -

    9. mudstone mudstone

    Constituent Mudstone 1 Mudstone 2 Mudstone 3 Mudstone 4 Mudstone 5 Mudstone 6

    SiO2 84.31 85.97 82.61 82.53 84.57 83.28

    Al2O3 8.28 8.63 9.08 10.34 9.23 10.07

    Fe2O3 2.55 1.88 3.57 3.52 2.92 2.70

    Cl - - - - - -

    MgO - - - - - -

    CaO 0.55 0.84 0.53 0.40 0.42 0.73

    K2O 1.46 1.76 1.83 1.92 1.83 1.92

    TiO2 0.32 0.33 0.37 0.43 0.38 0.40

    P2O3 0.12 - 0.62 - - 0.32

    SO3 2.40 0.60 1.40 0.86 0.64 0.59

    SrO - - - - - -

    Total 99.99 100.01 100.01 100 99.99 100.01

    29. mudstone mudstone

    mudstone mudstone

    XRF

    ( 29, 9). ,

    Ca Mg Mudstone1 Mudstone6

    .

    Ca Ca .

    Ca .

    Mg Mg

    30% . Mg

    , .

  • - 31 -

    2. XRD(X-ray Diffractometer: X )

    30. XRD . (A) nodule. (B) mudstone.

    : Dolomite(D), Ankerite(A), Quartz(Q), Montmorillonite(M), Tridymite(T)

    D

    D

    D

    D

    D

    D A

    D

    DDA A

    Q

    M

    T

    Q

    M

    Q Q

    T

    T Q Q Q T QT Q

    QM

    (B)

    (A)

  • - 32 -

    (mudstone) XRD

    , Dolomite Ankerite .

    (mudstone) , Quartz,

    Tridymite Montmorillonite(smectite) .

    Dolomite .

    Spherical Nodule Bedded Nodule 26

    XRF

    Fe .

    Dolomite

    Ankerite ,

    .

    Dolomite Dolomite

    Mg . Dolomite

    .

    1. Ca

    Mg .

    (open

    system) .

    2. Ca 50% ,

    Ca .

    3. XRF

    . Mg Si

    , Fe . Bedded Nodule

    Spherical Nodule .

    4. Dolomite, Ankerite, Siderite,

    Mg-calcite . Dolomite

    Dolomite Mg ,

    ,

    .

  • - 33 -

    4

    .

    , ,

    Spherical Nodule, Bedded Nodule, Septarian Nodule

    .

    .

    , .

    ,

    ,

    .

    , Mg .

    Mg

    . Mg

    .

    , .

    ,

    .

    , 2 . 2

    Septarian Nodule

    .

    Spherical Nodule

    Spherical Nodule

    .

    ,

    Mg .

    Spherical Nodule (micrite)

    (microspar) .

    .

    Ca C .

    Spherical Nodule 31 .

  • - 34 -

    Bedded Nodule

    Bedded Nodule Spherical Nodule

    . Spherical Nodule nodule

    Bedded Nodule , .

    Bedded Nodule

    .

    ,

    . , Bedded Nodule

    , 32 .

    Septarian Nodule

    Septarian Nodule

    .

    Septarian Nodule Spherical Nodule Bedded Nodule

    .

    .

    ,

    .

    . Septarian Nodule

    , 33 .

    , Mg , , 2

    . Spherical Nodule Bedded Nodule

    ,

    Bedded Nodule . Spherical

    Nodule Bedded Nodule Septarian Nodule

    . Septarian Nodule

    ,

    . Septarian Nodule

    .

  • - 35 -

    (A) .

    (B) .

    (C) .

    (D) Spherical Nodule

    31. Spherical Nodule

  • - 36 -

    (A) .

    (B) .

    (C) .

    (D) Bedded Nodule

    32. Bedded Nodule

  • - 37 -

    (A) Septarian Nodule .

    (B) .

    (a)

    (b)

    (C) (a) . (b)

    .

    33. Septarian Nodule

  • - 38 -

    .

    1. 3 , cm

    10m . , ,

    Spherical Nodule, Bedded Nodule, Septarian Nodule

    Spherical Nodule .

    2.

    ,

    .

    3. , ,

    , Mg 30%

    .

    4. ,

    Septarian Nodule .

    Bedded

    Nodule . Septarian Nodule

    .

    5. Ca

    Mg .

    (open

    system) .

    6. Ca 50% ,

    Ca .

    7. XRF

    . Mg Si

    , Fe . Bedded Nodule

    Spherical Nodule .

  • - 39 -

    8. Dolomite, Ankerite, Siderite,

    Mg-calcite . Dolomite

    Dolomite Mg ,

    ,

    .

    9.

    , Mg , , 2

    . Spherical Nodule Bedded Nodule

    ,

    Bedded Nodule .

    Spherical Nodule Bedded Nodule Septarian Nodule

    . Septarian Nodule

    ,

    . Septarian Nodule

    .

    .

    1.

    .

    2. 3

    .

  • - 40 -

    2, 2003,

    , 39 1, p.1-24

    , , 1997, , .

    , 33, 210-219

    2, 1992,

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    , 1982, 3 ,

    14, p.7-23.

    , , , p.274306.

    , 1982, ,

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    of the Pohang Area, Korea. Seoul Univ. J.

    2, 1964, Explanatory text of the geological map of Pohang Sheet, Sheet

    7022 - II 1:50,000. Geological Survey of Korea

    Dilcher D. L., 1974, Approaches to the identificaltion of Angiosperm leaf remains.

    The botanical review, Vol.40, No. 1, p.1 157.

    Esplanatory text of the geological map of Pohang Sheet, Sheet 7022 - II 1 :

    50,000. Goeolgical Survey of Korea. 1964.

    Endo. S., Cenozoic plants from Tyosen (Korea) (in Japanese). Jour. Geol. Soc.

    Japan, Vol.. 45, No. 532; No.534. 1938

    Huzioka K., 1972, The tertiary floras of Korea. J. Min coll. Akita Univ., Ser. A,

    Vol. V, No. 1, p.1 83

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    concretions from the Kimmeridge Clay, England. Sedimentology, 35,

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    deep-sea sediments - Evidence from Sr/Ca rations and interstitial

    dissolved Sr2- data. Journal of Sedimentary Petrology, 52, 71-82.

    Boles, J.R., Landis, C. and Dales, P., 1985, The Moeraky boulders: Anatomy of

    some septarian concretions. journal of Sedimentary Petrology. 55, 398-406.

    Calver, C.R. and Baillie, P.W., 1990, Early diagenetic concretions associated with

    intrastratal shrinkage cracks in an Upper Proterozoic dolomite, Tasmania,

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    Coleman, M.L and Raiswell, R., 1981, Carbon, oxygen and sulphur isotope

    variations in concretions from the Upper Lias of NE England. Geochimica

    Acta, 45, 329-340.

    Gautier, D.L., 1982, Siderite concretions: indicators of early diagenesis in the

    Gammon Shale (Cretaceous). Journal of Sedimentary Petrology, 52,

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    Gautier, D.L. and Claypool, G.E., 1984, Interpretation of methanic diagenesis in

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    margin. Sedimentary Geology, 143, 265-285.

  • - 43 -

    Plate 1

  • - 44 -

    Plate 2

  • - 45 -

    Plate 3

    5cm

    1cm 1cm

    1cm

  • - 46 -

    Plate 4

    0.01mm0.01mm

    0.01mm

    1cm 1cm

    1cm

    1cm

  • - 47 -

    Plate 5

    0.01mm

    0.01mm

    0.01mm

    0.01mm

    0.01mm 0.01mm

    0.01mm 0.01mm

  • - 48 -

    Plate 6

    0.01mm 0.01mm

    0.01mm 0.01mm

    0.01mm 0.01mm

    0.01mm 0.01mm