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Transcript of Tuyển tập một số bài toán hóa học hay và khó
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2012 by Box Ha hcwww.boxmath.vn
TUYN TP CC BI TP HA HC HAYV LI GII CA DIN N BOXMATH
(sa ln 1, ngy 17/04/2012)
BoxMath, thng 1 2012
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MC LC
LI NG ......................................................................................................................................................... 1
DANH SCH THNH VIN THAM GIA BIN SON........................................................................... 2
PHN 1. CC BI TON V C................................................................................................................. 3
Bi 1 10 ...................................................................................................................................................... 3
Bi 11 20 .................................................................................................................................................... 9
Bi 21 30 .................................................................................................................................................. 13
Bi 31 40 .................................................................................................................................................. 17
Bi 41 47 .................................................................................................................................................. 22
PHN 2. CC BI TON HU C............................................................................................................ 25
Bi 1 10 .................................................................................................................................................... 25
Bi 11 20 .................................................................................................................................................. 29
Bi 21 30 .................................................................................................................................................. 33
Bi 31 40 .................................................................................................................................................. 37
Bi 41 50 .................................................................................................................................................. 41
Bi 51 54 .................................................................................................................................................. 46
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LI NG
C nhiu ngi nhn xt Ha hc l b mn ca tr nh, hc ha phi nh rt nhiu th iu c thng, nhng cha phi l tt c. Ha hc giu trong lp o nng n ca nhng cng thc, nhng phn ng phc tp l mt v p tinh t ca s t duy logic. V p y c bit c hin din qua nhng bi ton ha, nhng bi ton cho bn rt nhiu con ng, nhng s ch c mt con ng p nht, ngn nht i n c chn l. Nhim v ca ngi hc ha l phi vn dng cc thao tc nh gi, phn on tm ra c con ng y, con ng khng ch a n kt qu m con a n mt nim vui, nim hng khi nh mt cht keo gn tri tim bn vi Ha hc.Tng c nhng giy pht v a trong sung sng tng c nhng khonh khc chi vi, b tc gia nhng s liu, nhng phng trnh phn ng Chng ti tin hnh lm tuyn tp ny vi mc ch u tin l nim mong mun ng cm, l kht khao chia s tnh yu Ha hc ca chng ti vi cc bn thng qua nhng bi tp ha mi l, nhng li gii hay.
Mi bi tp khng ch n gin l tnh ton, ng sau l nhng tng.
Mi li gii khng ch l p dng phng php m thc s l mt qu trnh phn tch v sng to.
Ha hc ang c tin hnh thi theo phng php trc nghim, th nhng li gii u tin m chng ti a ra vn lun lun l mt li gii y , i t nhng d kin ca bi ton n kt qu m hon ton khng ph thuc vo cc p n cho trc. Bi chng ti hiu v mong cc bn s hiu, ch c nh vy, chng ta mi c th i ht c v p ca ha hc, rn luyn c t duy suy lun logic cho bn thn, hc tp mt cch thc cht v sng to.
Tuyn tp ch yu l s tng hp v chn lc cc bi ton ha hc trn din n Boxmath.vn nm 2011. Chnh v vy, ban bin tp xin c chn thnh cm n s ng h ca ban qun tr din n, s tch cc vit bi v gii bi ca cc thnh vin trong sut mt nm qua. S n ch ca cc bn vi tuyn tp l mt ng lc rt ln gip ban bin tp c th hon thin cng vic nhiu ln tng chng nh phi b d dang.
Mc d c s c gng, xem xt k lng, nhng chc chn s khng trnh khi nhng khim khuyt, mong cc bn thng cm v gi li nhn xt bnh lun ca cc bn v cho chng ti tuyn tp c hon thin hn.
Mi kin xin gi v [email protected]
Thay mt ban bin tp ti xin chn thnh cm n.
H Ni, ngy 18/1/2012
i din nhm bin son
Ch bin
F7T7
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DANH SCH THNH VIN THAM GIA BIN SON
1. Ph Tin Cng THPT chuyn i hc S phm H Ni
2. Thi Mnh Cng THPT chuyn Phan Bi Chu, Ngh An
3. Trn Bo Dng THPT Ng Quyn, B Ra Vng Tu
4. Nguyn Th Thu Hi THPT Trn Ph, H Tnh
5. Nguyn Quc Oanh THPT So Nam, Qung Nam
6. Nguyn Hu Ph THPT Ty Sn, Lm ng
7. Phan Qunh Nga THPT Hng Kh, H Tnh
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PHN 1. CC BI TON V C
Bi 1 10
Bi 1. _________________________________________________________________________________Hn hp A gm mui sunfit, hidrosunfit v sunfat ca cng mt kim loi kim M. Cho 17,775 gam hn hp A vo dung dch 2( )Ba OH d, to thnh 24,5275 gam hn hp kt ta. Lc kt ta, ra sch v cho kt ta
tc dng vi dung dch HCl d, thy cn 2,33 g cht rn. Kim loi kim M lA. Li B. K C. Rb D. Na
Li gii.Phng trnh phn ng
2 24 4Ba SO BaSO
+ -+ 2
3 2 3OH HSO H O SO- -+ +
2 23 3Ba SO BaSO
+ -+
Cht rn cn li l 4BaSO : 42,33
0,01( )233BaSO
n mol= =
3
(24,5275 2,33)0,1023( )
217BaSOn mol
-= =
17,775158
0,1023 0,01M = =
+trung binh
Ta c 80 158 2 96TBM M M+ < < += . Ch c M = 39 tha mn iu kin ny. Chn p n B.
Bi tp tng t. Hn hp X gm 2 3 3,M CO MHCO v MCl (M l kim loi kim). Cho 32,65 gam X tc
dng va vi dung dch HCl thu c dung dch Y v c 17,6 gam 2CO thot ra. Dung dch T tc dng
vi dung dch 3AgNO d c 100,45 gam kt ta. Kim loi M l
A. Na B. Li C. K D. Rb
Bi 2. ______________________________________________________________________________Cho mt hp cht ca st tc dng vi 2 4H SO c nng, to ra 2SO (sn phm kh duy nht). Nu t l
2 4H SO em dng v 2SO to ra l 2 4 2: 4 :1H SO SOn n = th cng thc phn t ca X l:
A. Fe B. FeS C. FeO D. Fe3O4Li gii.
t ( )2SO
n a mol= Ta c:
Nu X l oxit ca st th ta c qu trnh kh l
( ) ( )6 4
2a2
mol a molS e S+ ++
( )2 4
4 3H SOn a a a mol == -tao muoi
( ) ( )32 4 3( )
2Fe SO Fen a mol n a mol+ = =
( ) ( )
3
2 22 2(3 ) 2x
a mol a molFe x e Fe+ ++ -
2x =Ngoi ra khng cn nguyn t no nhng hay nhn eVy cng thc X l FeO
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Nu X l mui sunfua ca st th X c CTPT dng x yFe S (a mol)
Ta c cc qu trnh oxi ha kh
( ) ( )6 4
22
mo bb l molS e S+ ++
( (
2
) ) ( )
3 1ax mol ax mol ax molFe eFe+ + +
24
4
( ) ( )
2 ( )
24
ay mol ay mol
ay ax mo
y
l
xx
S S ey
++
-
+ -
Vy 2
( )SOn ay b mol= + , ( )6 22 4 432H SO S SO taomuoiax
n n n b mol+ -= + = +
Suy ra ( )3 4( ) 12ax
b ay b+ = +
Theo nh lut bo ton electron ta li c ( )2 (4 2 ) 2b ax ay ax= + -
Gii h phng trnh (1) v (2) suy ra 10 3
, : 10 : 3b b
x y x ya a
= = = (khng tn ti hp cht no
tha mn iu ny). Vy trng hp th hai khng tha mn.Kt lun: Ch c FeO tha mn bi. Chn p n C.Bnh lun: Vi trng hp X l oxit ca st, d nhn thy 2 3Fe O phn ng khng to ra 2SO , ch xt FeO
v 3 4Fe O . Ta thy 1 mol ca hai cht ny khi phn ng u nhng 1 mol electron. Vy nu t
( )2SO
n a mol= th s mol ca FeO v 3 4Fe O u l 2 ( )a mol . Nhng ch c FeO mi to ra c mui
cha 243 ( )a mol SO- tha mn yu cu bi ra. Chn ngay FeO, p n B.
Bi tp tng t. X l mt hp cht ca Fe. Cho X tc dng vi 2 4H SO c nng thy thot ra kh 2SO vi
t l mol X v 2SO l 2:9. X l:
A. 3 4Fe O B. FeS C. 2FeS D. FeO
p s: B. FeS
Bi 3. _____________________________________________________________________________Cho t t a gam st vo V ml dung dch 3HNO 1M khuy u cho n khi tan ht thy thot ra 0,448 lt kh
NO (ktc) ng thi thu c dung dch A . Dung dch A c kh nng lm my mu hon ton 10 ml dung
dch 4KMnO 0,3M trong mi trng axit. Gi tr ca a v V l:
A. a =1,4 gam; V = 80 ml B. a = 1,12 gam; V = 80 mlC. a = 0,56 gam; V = 56 ml D. a = 0,84 gam; V = 60 ml
Li gii.Ta c cc phng trnh th hin qu trnh oxi ha kh:
( )( )5 20,06 0,023 1N e N NO+ ++
( )333 2
x x xFe Fe e+ +
( )222 3
y y yFe Fe e+ +
7 2
0,003 0,0155 (4)Mn e M+ ++
2 3 1 (5)y y
Fe Fe e+ + +
Theo phn ng kh 4KMnO , t (4) v (5) ta c 0,015y =
Theo phn ng kh 3HNO , t (1), (2) & (3), ta c 3 2 0,06 0,01( )x y x mol+ = =
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Vy 0,025 1,4Fen m g= =
3 3 33 2 0,02 0,08( )HNO NO NOn n n x y mol- -= + = + + = tao muoi bi khu
Suy ra ( )80V ml=
Bi 4. _____________________________________________________________________________Hn hp X gm c , x yAl Fe O . Tin hnh nhit nhm hon ton ( )m g hn hp X trong iu kin khng c
khng kh thu c hn hp Y. Chia Y thnh hai phn.Phn 1. Cho tc dng vi NaOH d thu c 1,008 lt 2H (ktc) v cn li 5,04 gam cht rn khng tan.
Phn 2 c khi lng 29,79 gam, cho tc dng vi dung dch 3HNO long d thu c 8,064 lt NO (ktc,
l sn phm kh duy nht).Gi tr ca m v cng thc ca oxit st l
A. 39,72 gam & FeO B. 39,72 gam & 3 4Fe O
C. 38,91 gam & FeO D. 36,48 gam & 3 4Fe O
Li gii.Cch 1
2 32 3 3 (1)x yyAl Fe O yAl O xFe+ +
Phn ng nhit nhm hon ton m phn 1 to kh 2H nn hn hp Y gm 2 3, ,Al Fe Al Od Phn 1
( )Aln a mol= ; ( )Fen b mol= ; ( )2 3Al On c mol=Phng trnh phn ng
2 2 20,03 0,0452 2 2 2 3Al NaOH H O NaAlO H+ + +
5,04Fem m g= =ran . Suy ra ( )0,09Fen mol= Phn 2
( )Aln ka mol= ; ( )Fen kb mol= ; ( )2 3Al On kc mol=Theo nh lut bo ton electron ta c: ( )3 3 .0,123. 0,36.3 3NOk a b k n k+ = = =
29,79 (27.0,09 56.0,27)0,04( )
3.102c mol
- + = =
29,79.439,72
3m g = =
T (1) ta c 0,04.3 0,09 4 3x y x y= =Chn p n B
Cch 2. Phn 1
Sau khi tc dng vi NaOH to ra kh nn sau khi nhit nhm th Al cn d 0,03Aln =
Cht rn cn li l Fe 0,09Fen mol =13
Al
Fe
nn
=
Phn 2Gi s mol ca Al l a th s mol ca Fe l 3a. Bo ton electron ta c:12 1,08 0,09a a= =
2 3 2 312,24 0,12Al O Al Om n = =
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Suy ra phn 1 c 2 3
0,04Al On =39,72( )m gam =
Da vo s mol ca O v Fe suy ra CTPT ca oxit l 3 4Fe O .
Bi 5. ______________________________________________________________________________in phn in cc tr dung dch cha 0,2 mol 3AgNO vi cng dng in 2,68 A, trong thi gian t
(gi) thu c dung dch X (hiu sut ca qu trnh in phn l 100%). Cho 16,8 gam bt Fe vo X thy thot ra kh NO (sn phm kh duy nht) v sau cc phn ng hon ton thu c 22,7 gam cht rn. Gi trca t l:
A. 2,00 B. 1,00 C. 0,50 D. 0,25Li gii.
3 2 3 24 2 4 4AgNO H O Ag HNO O+ + +
Gi x l s mol 3AgNO d v y l s mol 3HNO to ra. Tng s mol ca 3AgNO d v 3HNO chnh bng s
mol 3NO- khng i. Do , ta c
30, 2
NOx y n -+ = =
Ag ti a to ra cng ch 0,2 mol tc l khi lng cht rn sau phn ng nh hn 21,6 gam. Vy trong
cht rn cn Fe d.22 2Fe Ag Fe Ag+ ++ +
3 3 3 24 ( ) 2Fe HNO Fe NO NO H O+ + +
Suy ra s mol Fe phn ng l3
0.58y
x +
S mol Ag to ra l x, vy c 3
108 (0.5 .56) 22,7 16,88y
x x- + = -
T tm c 0,1x y= = hay 3600( ) 1( ).t s h= =
Bi 6. _______________________________________________________________________________Cho 8,64 gam Al vo dung dch X (X c to thnh bng 74,7 gam hn hp Y gm 2CuCl v 3FeCl vo
nc). Kt thc phn ng thu c 17,76 gam cht rn gm hai kim loi. T l mol ca 3 2:FeCl CuCl trong
hn hp Y l:A. 2:1 B. 3:2 C. 3:1 D. 5:3
Li gii.- Nu d Al th chc chn hn hp kim loi phi cha c 3 kim loi Al, Cu v Fe. Do Al phi ht
sau phn ng v hai kim loi cn li l Cu v Fe .- Do Fe nn chc chn c 3 phn ng sau xy ra theo th t:
3 3 2
3
3 e 3 ex xx
Al F Cl AlCl F Cl+ +
2 323
2 3 2A 3yyy
Al CuCl lCl Cu+ +
2 3 32
2 3 3 3z x z
Al FeCl AlCl Fe+ + ( y 32
x z , do Al phn ng ht.
Ta c 2
0,32( ) 0,323 3Alx
n mol y z= + + =
Khi lng hai mui ban u l 74,7 gam, suy ra .162,5 .135 74,7x y+ =
Khi lng hai kim loi thu c l 17,76, suy ra 3
64 56. 17,762
x z+ =
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Gii h ba phng trnh trn suy ra: 0,36; 0,12; 0,12x y z= = =Vy : 3 :1x y = . Chn p n C.
Bi 7. _______________________________________________________________________________ Cho 240 ml dung dch 2( )Ba OH 1M vo 200 ml dung dch hn hp 3AlCl a mol/lt v 2 4 3( )Al SO 2a mol/lt
thu c 51,3 gam kt ta. Gi tr ca a l:A. 0,12 B. 0,15 C. 0,16 D. 0,2
Li gii.
Trong cc dung dch c 0,24 mol 2 ;Ba + 0,48 mol ,OH - a mol 3 ;Al + 0,6a mol ;Cl - 1,2a mol 24SO- .
Xt bng sau da theo cc gi tr ca aa 0,12 0,16 0,2
Nhn xt 4 0,48;a < 1,2 0,24a (loi)
TH2: to 3CH OH trong phn ng vi KOH
Khi lng cht rn khan thu c l:74 0,7.0,2.56 32 12,88 0,12; 8,88m a a a m g= + = + = =
p n 8,88 gam.Bnh lun. Bi ton t ra hai thao tc, trong vic xc nh c CTPT ca este l thao tc u tin v mu cht. tm c CTPT ca este ta phi gii mt bi ton v phn ng chy m hon ton c th ng ring ra lm thnh mt bi ton c lp. Bi tp trn thc ra khng kh, nhng li c t vo hai bi ton khc nhau, tnh ton li kh di dng, nn li tr thnh bi tp kh.
Bi 26. ______________________________________________________________________________________Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81% . Ton b lng 2CO hp th hon
ton vo dung dch nuc vi trong, thu c 550 g kt ta v dung dich Y . un k dung dch Y thu thm 100 gam kt ta. Khi lng m l bao nhiu ?
Li giiCc phng trnh phn ng:
2 2 3 25,5 5,5
( )Ca OH CO CaCO H O+ +
1 12 2 2 3 2( ) ( )Ca OH CO H O Ca HCO+ +
21
3 3 2 21
( )Ca HCO CaCO H O CO + +
Tng s mol 2CO phn ng l
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( )
( ) ( )2
5,5 1.2 7,5
1257,5 : 2 :81% 750
27
CO
tinh bot tinh bot
n mol
n mol m gam- -
= + =
= = =
Bi 27.______________________________________________________________________________________Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55gam hn hp mui khan. Khi lng NaOH tham gia phn ng l:
A. 31 gam B. 32,36 gam C. 30 gam D. 31,45 gamLi gii
1 g cht bo cn trung ha bi 7 mg KOHSuy ra 200 g s cn 1400 mg KOH tc l cn 0,025 mol KOH
20,025 0,025R COOH NaOH R COONa H O- + - +
x3 3 5 3 5 33( ) 3 3 ( )
xRCOO C H NaOH RCOONa C H OH+ +
Ta c 1400
0,025( )56.1000KOH NaOH
n n mol= = =
p dng LBT KL: 200 0,025.40 120 207,55 18.0,025 92 0,025( )x x x mol+ + = + + =
3.0,25.40 0,025.40 31NaOHm g= + = .Chn p n C.
Bi 28. ______________________________________________________________________________________Khi thu phn kim 265,2 g cht bo to bi mt axitcacboxylic thu uc 288 gam mui kali. Cht bo ny c tn gi l:
A. glixerol tristearat B. glixerol trioleat C. glixerol trilinoleat D. glixerol tripanmitat
Li giiDng phng php tng gim khi lng vi X l s mol ca este.(393 41) 288 265,2 22,8 0,3x x mol- = - = =
17 33884 .axitM C H COOH= Chn p n B.
Bi 29. _____________________________________________________________________________________A l mt hn hp gm hai cht thuc dy ng ng ca stiren c khi lng phn t hn km nhau 14
vC. t chy hon ton m gam A bng 2O d. Cho sn phm chy hp th vo 300ml dung dch NaOH
2M. Khi lng bnh ng dung dch tng 22,44 gam v thu c dung dch D. Cho 2BaCl d vo dung
dch D thu c 35,46 gam kt ta. cc phn ng Xy ra hon ton. Tm CTPT ca 2 hidrocacbon trong A.Li gii
Gi CTPT trung bnh ca A l 2 8n nC H -
3 2
2 2 2
35,460,18( ) 0,18 (0,3.0,2 0,182) 0,42( )
1970,42 0,22
44 18 22,44 0,22( ) 0,054
0,428,4
0,05
BaCO CO
CO H O H O A
n mol n mol
n n n mol n
n
= = = + - =
-+ = = = =
= =
Suy ra hai hidrocacbon cn tm l 8 8 9 10,C H C H
Bi 30. _____________________________________________________________________________________
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Hp cht X mch h c CTPT l 4 9 2C H NO . Cho 10,3 g X phn ng va vi dung dch NaOH sinh ra 1
cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm qu tm m chuyn mu Xanh. dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m g mui khan. Gi tr m?
Li gii
Kh Y nng hn khng kh, lm qu tm m chuyn mu Xanh suy ra: 3 2CH NH
Dung dch Z c kh nng lm mt mu nc brom suy ra phi c lin kt i C C= . Suy ra X l
2 3 2CH CHCOONH CH= .
Do 10,3
94 .94 9,4103muoi muoi muoi X
m n M n g= = = =
Bi 31 40
Bi 31. ____________________________________________________________________________Aminoaxit Y cng thc c dng ( )x y mNC H COOH . Ly mt lng axit aminoaxetic ( X ) v 3,104 gam Y. Bit X v Y c cng s mol. t chy hon ton lng X v Y trn, th tch 2O cn dng t chy Y
nhiu hn X l 1,344l (ktc). CTCT thu gn ca Y l:
3 2.A CH NHCH COOH 2 2 2.B H NCH CH COOH
( )3 3.C N CH COOH ( )4 8 2.D NC H COOHLi gii.
t:
1: : ( )x y zY C H O N k mol
2 5 2: : ( )X C H O N k mol
1 2 2 2 2
1( )
4 2 2 2x y zy z y
C H O N x O xCO H O N+ + - + +
2 5 2 2 2 2 2
5 2 5 1(2 ) 2
4 2 2 2C H O N O CO H O N+ + - + +
5 2 1,344(2 ). ( ). (1)
4 2 22,4 4 2y z
k x k + - + = + - vi 3,104 3,10412 16 14 Y
kx y z M
= =+ + +
Thay vo ta c:
( ) ( )3,104 9 4x 2z 0,06 15. 12x 16z 14 194 9 4x+ 2z12x 16z 14 4
596x 179 628z 1956 0
yy y
y
y
- - + = - + + + = - + - + + + + - - =
T y suy ra 4y , ch c p n C tha mn. Th li p n ny, ta chn C l ph hp.
Bi 32. _____________________________________________________________________________Cho 0,02 mol mt este X phn ng va ht vi 200 ml dung dch NaOH 0,2M, sn phm to ra ch 1 mui v mt ancol u c s mol bng s mol este, u c cu to mch thng. Mt khc khi x phng ho hon ton 2,58 gam este bng 20 ml dung dch KOH 1,5M va thu c 3,33 gam mui. Vy X l:
A. etilenglicol oxalat B. etilenglicol adipatC. imetyl adipat D. ietyl oxalat
Li gii.
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TN1. Do 12este NaOH
n n= , nn este phi l este hai chc hoc l este ca phenol.
Li c muoi ancol esten n n= = , nn este phi l este ca ancol hai chc v axit hai chc.
Suy ra CTPT ca este l 2( )R COO R .
TN2.
Ta c 1
0,0152este muoi KOH
n n n mol= = =
T tnh ra c 4 8R C H= v 2 4R C H = . Suy ra este l C. imetyl adipat.
Bi 33. ____________________________________________________________________________Mt este A ( khng cha chc khc) c to nn t 1 axit hu c B v 1 ancol C. Ly m gam A cho tc dng vi KOH d thu c m1 gam mui. Ly m gam A cho tc dng vi 2( )Ca OH d thu c 2m gam
mui. Bit 2 1m m m< < . CT thu gn ca C l:
A. 2 5C H OH B. 3CH OH
C. 3 7C H OH D. 4 8C H OH
Li gii.
1m gam m gamRCOOR RCOOK
Ta c 1m m> nn 39R nn 2 40R >
Vy 20 39R< =
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Bi 35. ____________________________________________________________________________un 0,4 mol hn hp 2 ancol no, n chc, mch h k tip trong dy ng ng bng dung dch 2 4H SO
140o C thu c 7,704 g hn hp 3 ete. Tham gia phn ngs ete ho c 50% s mol ancol c khi lng phn t ln v 40% ancol c khi lng phn t nh. Xc nh cng thc hai ancol.
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A.Metylic v etylic B. etylic v n-propylicC. n-propylic v n-butylic D. propan-2-ol v butan-2-ol
Li gii.
Gi hn hp 2 ancol l ROH vi 14 1R n= + (do hai ancol no, n chc, h)Hai ancol l ROH (x mol), R OH (y mol). Vi R R >Ta c h phng trnh h phng trnh
0,4
0,5 0,4(2 16)( ) 7,704
2
x y
x yR
+ = +
+ =
12,848 0,320,2 1,6
Rx
R-
=+
T iu kin 0 0,4 30,52 40,15x R< < < > nn khi t A th phi c 2 2H O COn n> .
t CTPT ca A l 2 3 2 2 2n n x y xC H O N+ - - , vi y l bt bo ho ca gc R ( 0;y x 1)
Nu 2x y+ th khi t A c 2 2H O CO
n n< .
Do vy 0, 1y x= = , khi A c CTPT: 2 1 2n nC H O N+Khi t chy th
2 22 2H O CO An n n- =
Vi B th 2 2H O CO
n n= .
Do vi 0,25 mol ban u c: ( )2.0,675 2.0,6 0,15 mol- = cht A.Nn 0,2 mol X s c 0,12 mol cht AX do vy s phn ng va vi ( )0,12a mol= HCl.
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42 http://boxmath.vn 17/04/2012
Bi 43. _____________________________________________________________________________Cho hn hp gm 2 este mch h l ng phn ca nhau. Ly 0,2 mol X cho phn ng hon ton vi 300 ml dung dch NaOH 1M, ri tin hnh chng ct c 8,5 gam hn hp hai ancol ng ng k tip nhau. C cn phn dung dch cn li sau chng ct c cht rn A. Nung A trong oxi d n phn ng hon ton c 22 gam 2CO v 7,2 gam 2H O cng 1 lng 2 3Na CO . Cng thc phn t ca hai este l:
A. 2 3 2 5C H COOC H & 3 5 3C H COOCH
B. 2 5 2 5C H COOC H & 3 7 3C H COOCH
C. 2 3 3 7C H COOC H & 3 5 2 5C H COOC H
D. 3 5 3 7C H COOC H & 4 6 2 5C H COOC H
Li gii. bi cho mt gi thit quan trng l hai ancol ng ng k tip nhau, ta ngh ngay ti vic li dng iu ny tm ra cng thc hai ancol thng qua khi lng mol trung bnh. Tuyt vi hn na, ta cng
c khi lng v s mol hai ancol ny. Vy d dng suy ra 8,5
42,50,2ancol
M = =
Suy ra hai ancol l 3CH OH v 2 5C H OH , loi p n C, D
Ta c s ng cho
( )
3
2 5
(32) 3,51
42,53
46 10,5
CH OH
C H OH
=
T l hai ancol cng chnh l t l hai este nn:Suy ra
3 2 50,05 0,15esteRCOOCH esteR COOC Hn n = =
Ch cn hai p n A, B. V chng ta cn phn ng th 2 cha s dng. Ta quan st hai mui to ra t cc este ca A, B ch khc nhau s nguyn t H. Ta s da vo s H chn p n ng. phn ng (2) ta bo ton nguyn t H.
22 0,7H trong muoi H O NaOH dun n n= - =
Vi cc s mol, ta th hai p n A, B th ch thy A to ra c 0,7. Chn A.Bnh lun. Ta c th gii nhanh hn da vo cc p n A, B, C, D nh sau:
Ta c: 0,2 ( )
:: 0,1 ( )
RCOONa molA
NaOH mol
d
S mol H trong mui 2
2 0,7 ( )H O NaOH duRCOONa n n mol= - =
S H trung bnh trong 0,7
3,50,2
RCOONa = = . Vy loi cc p n B, D
Th p n C xem ng khng nh.
t: 2 3 3 7 3 5 2 5
0, 2; (*)
60 46 8,5C H COOC H C H COOC Hx y
n x yx y
n+ =
= = + =Gii h (*) cho ta nghim m. Vy chn p n A.
Bi 44. _____________________________________________________________________________Ly 15,66g amin n chc, mch h X ( X c khng qu 4 lin kt p ) trn vi 168 lt khng kh (ktc). Bt tia la in t chy hon ton X , hn hp sau phn ng c a v 0 C, 1atm ngng t ht hi nc th c th tch l 156,912 lt. Xc nh s ng phn ca X.
A.2 B.17 C.16 D.8Li gii
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43 http://boxmath.vn 17/04/2012
Gi amin l 2 3 2 2 2 2 2323 3 1( 4)
2 2 2n n kn k
C H N k O nCO n k H O N+ -- +
+ + - + +
32 53 1 15,66. 0, 495
02 2 14 17 2
nn kn
kn k
=- + - - =
=+ -
5 13C H N
Cc ng phn lAmin bc 1: 5 11 2C H NH- c 8 ng phn (ging ancol)
Amin bc 2: 3 4 9CH NH C H- - c 1.4 4= ng phn (do 3CH c 1 ng phn v 4 9C H c 4 ng phn) ;
2 5 3 7C H NH C H- - c 1.2 2= ng phn
Amin bc 3: 3 2 3 7( )CH N C H- c 1.1.2 2= ng phn ; 3 2 5 2( )CH N C H- c 1.1.1 1= ng phn
Chn p n B.
Bi 45. _____________________________________________________________________________Oxi ha 38 gam hn hp propanal, ancol A no n chc bc 1 v este B (to bi mt axit ng ng ca axit acrylic v ancol A) c hn hp X gm axit v este. Mt khc, cho lng X phn ng vi 0,5 lt dung dch NaOH 1,5M th sau phn ng trung ha ht NaOH d cn 0,15 mol HCl c dung dch D. C cn D
c hi cht hu c E, cn li 62,775 gam hn hp mui. Cho E tch nc 140o C ( 2 4H SO c xc tc)
c F c t khi vi E l 1,61. A v B ln lt l:A. 2 5C H OH v 23 55C H COOC H C. 3CH OH v 4 7 3C H COOCH
B. 3CH OH v 3 5 3C H COOCH D. 2 5C H OH v 4 7 2 5C H COOC H
Li gii.
Ta nhn thy E chnh l ancol to este B. t CTPT ca E l ROH. Do 1,61 1FE
MM
= > nn F l ete, do
( )2 52 16
1,61 2917
RR C H
R+
= = -+
. Vy E hay ancol A chnh l 2 5C H OH . Loi p n B v C
Gi x, y, z ln lt l s mol ca 2 5 ,C H CHO 2 5 ,C H OH 2 1 2 5m mC H COOC H-(Lu , do axit to thnh este l ng ng ca axit acrylic nn 3m )Ta c 58 46 (72 14 ) 38x y z m+ + + =
Oxi ha hn hp s to ra hn hp X gm x mol 2 5 ,C H COOH y mol 3 ,CH COOH z mol este
S mol NaOH phn ng vi hn hp sn phm: 0,5.1,5 0,15 0,6( ) 0,6NaOHn mol x y z= - = + + = .
C cn D s to ra x mol 2 5 ,C H COONa y mol 3 ,CH COONa z mol 2 1m mC H COONa- v 0,15 mol
NaCl. Suy ra 96 82 (66 14 ) 0,15.78,5 64,775x y z m+ + + + =Nh vy ta c h 3 phng trnh:
38 5858 46 (72 14 ) 38 (1) (1')14
0,6 (2) 38 (2 ')
96 82 (66 14 ) 0,15.5
x 46 72zz
x 36 6z 16
08,5 62,775 (3) (3'),6
my
y
x y z
x y z m
x y z
x y z m
- -
+ - =+ + =
- =+ + + = + + =
+ + + + =
T (2) v (3) suy ra 2 17
36( ) 16 6 38( ) 36(0,6 ) 16 6 38(0,6 ) (*)15 110
x y z x y z z z z+ < + < + - < + < -