Influence of PANI Additions on Methanol Sensing Properties ...
Study on Electronic Properties of - chemistry.or.jp Journal Report 2013.pdf · Study on Electronic...
Transcript of Study on Electronic Properties of - chemistry.or.jp Journal Report 2013.pdf · Study on Electronic...
Study on Electronic Properties of Composite Clusters toward Nanoscale Functional Advanced Materials
Atsushi NakajimaBull. Chem. Soc. Jpn. 2013, 86, 414–437.
Toward an Atomic-Level Understanding of Size-Specific Properties of Protected and Stabilized Gold Clusters
Tatsuya Tsukuda
Electroconductive π-Junction Au Nanoparticles
Masayuki Kanehara; Jun Takeya; Takafumi Uemura; Hideyuki Murata; Kazuo Takimiya; Hikaru Sekine; Toshiharu Teranishi
Nanooptical Studies on Physical and Chemical Characteristics of Noble Metal Nanostructures
Hiromi OkamotoBull. Chem. Soc. Jpn. 2013, 86, 397–413.
doi: 10.1246/bcsj.20120298
doi: 10.1246/bcsj.20110227
doi: 10.1246/bcsj.20120103
doi: 10.1246/bcsj.20120268
Award Accounts Open Access
Open Access Award Accounts
Nanoclusters
CSJ Journal Report
H. Okamoto
Nanocluster Surface
photon/ spin
Gas Phase Synthesisof Composite Clusters
Na
Al13
SAMSelf-Assembled
Monolayer
Substrate
Selective Soft-Landing
-1
+2+2
+2+2
-2-2-2-1
SubstrateMolecular Self-Assembly
100 nm 200 nm
gold nanorod gold nanosphere dimers
E
Award Accounts Open Access
A. Nakajima
Carrier Conduction
e-
Open Access Selected Papers
M. Kanehara
T. Tsukuda
Near-Field Nanooptics
Composite Clusters
Au Nanoparticles
Size-Controlled Au Clusters
− 1 −
Bull. Chem. Soc. Jpn. 2012, 85, 957–961.
Bull. Chem. Soc. Jpn. 2012, 85, 151–168.
CSJ Journal Report
Eff ect of Charge of a Matrix Polymer on the Electronic States of Single-Walled Carbon Nanotubes
Yasuhiko Hirana; Yasuro Niidome; Naotoshi Nakashima
Formation of Au Nanostructure by Electrodeposition in a Mesoporous Silica Film with Interconnected Cage-Type Mesopores
Yosuke Kanno; Kazuyuki Kuroda
Fabrication and Photocatalytic Properties of TiO2 Nanotube Arrays Modifi ed with Phosphate
Kazuya Nakata; Baoshun Liu; Yosuke Ishikawa; Munetoshi Sakai; Hidenori Saito; Tsuyoshi Ochiai; Hideki Sakai; Taketoshi Murakami; Masahiko Abe; Katsuhiko Takagi; Akira Fujishima
CVD Synthesis of Highly Graphitized Single-walled Carbon Nanotubes Using Nitrogen-pretreated Fe–Mo/MgO Catalyst
Gaurav Patil; Chetan Sarode; Rahul Patil; Suresh Gokhale
doi: 10.1246/bcsj.20120116
doi: 10.1246/bcsj.20120358
doi: 10.1246/cl.2011.1107
doi: 10.1246/cl.2012.871
BCSJ Award Article
Letter
Editor’s Choice Open Access
Selected Papers
Nanotubes
S. Gokhale
Open Access
Mesoporous Materials
Nitrogen pretreatment of Fe–Mo/MgO catalyst promotes the growth of SWNTs. It enhances the structural features, graphitization, and thermal properties of the nanotubes.
TiO2 nanotube arrays prepared by anodization in HF/H3PO4 mixed electrolyte show highly efficient photocatalytic decomposition of acetaldehyde. The combined morphology of the TiO2 nanotubes and presence of phosphorus ions on their surface may contribute to their excellent photocatalytic performance.
N. Nakashima
K. Kuroda
K. Nakata
Nanoarchitectonics for Mesoporous Materials
Katsuhiko Ariga; Ajayan Vinu; Yusuke Yamauchi; Qingmin Ji; Jonathan P. Hill
doi: 10.1246/bcsj.20110162 Open Access Accounts
K. Ariga
Solubilized SWNT
Graphitized SWNT
TiO2 Nanotube
Silica Film
Nanoarchitectonics
− 2 −
Bull. Chem. Soc. Jpn. 2012, 85, 1262–1267.
Chem. Lett. 2012, 41, 871–873.
Bull. Chem. Soc. Jpn. 2013, 86, 583–585.
Bull. Chem. Soc. Jpn. 2012, 85, 1–32.
Chem. Lett. 2011, 40, 1107–1109.
Supramolecules
Metal–Organic Frameworks (MOF)
Organic FET
CSJ Journal Report
Bioinspired Supramolecular Materials
Masato Ikeda
Organic Single-Crystal Transistors Based on π-Extended Heteroheptacene Microribbons
Yu Seok Yang; Takuma Yasuda; Chihaya Adachi
Control over Flexibility of Entangled Porous Coordination Frameworks by Molecular and Mesoscopic Chemistries
Shuhei Furukawa; Yoko Sakata; Susumu Kitagawa
Elaborate Metallosupramolecular Architectures through Desymmetrization Self-assembly of Symmetric Building Blocks
Takashi Nakamura; Hitoshi Ube; Mitsuhiko Shionoya
doi: 10.1246/bcsj.20120254
doi: 10.1246/bcsj.20120178
doi: 10.1246/cl.130357
doi: 10.1246/cl.130189
Award Accounts
BCSJ Award Article
Highlight Review
Open Access
Open Access
M. Shionoya
Highlight Review
M. Ikeda
T. Yasuda
S. Kitagawa
Nanospace
Bioinspired Materials
Single-Crystal Transistors
Entangled Porous Frameworks
− 3 −
Chem. Lett. 2013, 42, 328–334.
Bull. Chem. Soc. Jpn. 2013, 86, 10–24.
Chem. Lett. 2013, 42, 570–576.
Bull. Chem. Soc. Jpn. 2012, 85, 1186–1191.
C–H Bond Activation
CSJ Journal Report
Cu–Rh Redox Relay Catalysts for Synthesis of Azaheterocycles via C–H Functionalization
Shunsuke Chiba
Oxidative C–H/C–H Coupling of Azine and Indole/Pyrrole Nuclei: Palladium Catalysis and Synthesis of Eudistomin U
Atsushi D. Yamaguchi; Debashis Mandal; Junichiro Yamaguchi; Kenichiro ItamiChem. Lett. 2011, 40, 555–557.
Ruthenium-catalyzed Oxidative Alkenylation of Arenes via Regioselective C–H Bond Cleavage Directed by a Nitrogen-containing Group
Yuto Hashimoto; Takumi Ueyama; Tatsuya Fukutani; Koji Hirano; Tetsuya Satoh; Masahiro Miura
doi: 10.1246/cl.2012.1554
doi: 10.1246/cl.2011.555
doi: 10.1246/cl.2011.1165
Highlight Review
Editor’s Choice
Letter
Open Access
N
N2 cat. [Cp*RhCl2]2 cat. Cu(OAc)2
AcOH
DMF, 90 °C
NR'
R"
R
H
R
NOAc
R'
R"
+
cat. [Cp*RhCl2]2 cat. Cu(OAc)2
DMF, 60 °C
NR'
R"
RR
Oximessyn -anti mixtures
H
Cu-Rh relay catalysts
R'
R"
+
Vinyl Azides2 Cu(I)
2 Cu(II) Rh(I)
Rh(III)process Ireduction
process IIoxidationS. Chiba
K. Itami
M. Miura
Cu–Rh Redox Catalysis
Pd Catalysis
Ru Catalysis
− 4 −
Chem. Lett. 2011, 40, 1165–1166.
Chem. Lett. 2012, 41, 1554–1559.
Cross Coupling
Efficient Synthesis
C–C Bond Activation
CSJ Journal Report
Cross-coupling Reactions of Organoboranes: An Easy Method for C–C Bonding
Akira Suzuki; Yasunori Yamamoto
1,3-Dipolar Cycloaddition-based Synthesis of Diverse Heterocyclic Scaffolds
Wei Zhang
Nickel/Lewis Acid-Catalyzed Carbocyanation of Unsaturated Compounds
Yoshiaki Nakao
Kumada–Tamao–Corriu Coupling of Alkyl Halides Catalyzed by an Iron–Bisphosphine Complex
Takuji Hatakeyama; Yu-ichi Fujiwara; Yoshihiro Okada; Takuma Itoh; Toru Hashimoto; Shintaro Kawamura; Kazuki Ogata; Hikaru Takaya; Masaharu Nakamura
doi: 10.1246/cl.2011.894
doi: 10.1246/cl.130504
doi: 10.1246/bcsj.20120081
doi: 10.1246/cl.2011.1030
Highlight Review
Highlight Review
Award Accounts
Letter
Open Access
Open Access
Open Access
B R B B RC B
X R X X RCR-X
R-B
C-X
C-
NH
R1
CO2R
R2
NR3
O
O
R1
N
NHO
OR2
R3
O
R2
N N
O
O R4
N
O
O
N
R1 CO2R
O
OR3
H
R2
R1
R4 R3
[3+2] adductsN
O
ON
R2'
N
O
O
R2
R3 R3'R1
C CNR R
C CNRR+
Ni/Lewis acidcooperative
catalysis
Alkyl X + Alkyl Ar
cat. [FeCl2(SciOPP)](0.5–3.0 mol%)
THF, 25–40 °Cslow additionX = Cl, Br, I
ArMgBr PP
t-Bu
t-Bu
t-Bu
t-Bu
t-Bu
t-Bu
t-Bu
t-Bu
Fe
Cl Cl
[FeCl2(SciOPP)]
74–98% yield10 examples
A. Suzuki
W. Zhang
Y. Nakao
M. Nakamura
Suzuki Coupling
1,3-Dipolar Cycloaddition
Ni/Lewis Acid Catalysis
Fe Catalysis
− 5 −
Chem. Lett. 2011, 40, 894–901.
Chem. Lett. 2011, 40, 1030–1032.
Chem. Lett. 2013, 42, 676–681.
Bull. Chem. Soc. Jpn. 2012, 85, 731–745.
Asymmetric Catalysis
CSJ Journal Report
Stable Axial Chirality in Metal Complexes Bearing 4,4ʹ-Substituted BIPHEPs: Application to Catalytic Asymmetric Carbon–Carbon Bond-Forming Reactions
Kohsuke Aikawa; Yoshitaka Miyazaki; Koichi Mikami
Asymmetric Induction Arising from Enantiomerically Enriched Carbon-13 Isotopomers and Highly Sensitive Chiral Discrimination by Asymmetric Autocatalysis
Tsuneomi Kawasaki; Kenso Soai
Chemistry of Concerto Molecular Catalysis Based on the Metal/NH Bifunctionality
Takao Ikariya
Platinum Metals in the Catalytic Asymmetric Isomerization of Allylic Alcohols
Luca Mantilli; Clément Mazet
doi: 10.1246/bcsj.20110309
doi: 10.1246/bcsj.20110120
doi: 10.1246/bcsj.20100249
doi: 10.1246/cl.2011.341
Selected Papers
Award Accounts
Award Accounts
Highlight Review
Open Access
Open Access
Ph2P
PPh2
PdCl2
R
steric and electronic effect
t1/2 at 27 °C
R = t-Bu: 7 years
H: 17 years
Pd cat*
O
H CO2Et
OH
CO2EtOO
SiMe3
O
F3C 2Et CO2Et
HO CF3
0.05 mol%
Pd cat*
0.01 mol%
Pd cat*
up to 98% ee
up to 98% ee
+
+
TOF 58,200 h-1
R
CF3: 56 years
*
chirally stable
CO
X ∗ Y
12C 13C
Chiral Carbon Isotopomer
X ∗ Y
13C 12C
N
N
t-Bu
CHON
N
t-Bu
∗
OH
+ i-Pr2Zn
Asymmetric Autocatalysiswith Amplification of ee
R2 OH
R1
R2 O
R1
R3 R3
H/R4 H/R4Rh
Ru
Ir
K. Mikami
K. Soai
T. Ikariya
C. Mazet
C– C Bond-Forming Reactions
Asymmetric Autocatalysis
M/NH Bifunctional Catalysis
Asymmetric Isomerization
− 6 −
Bull. Chem. Soc. Jpn. 2012, 85, 201–208.
Bull. Chem. Soc. Jpn. 2011, 84, 879–892.
Chem. Lett. 2011, 40, 341–344.
Bull. Chem. Soc. Jpn. 2011, 84, 1–16.