석유화학Plant.pdf

HVAC/Plant Eng. Lab., Hanyang Univ. - 1 -

Plant


Plant

TerminologyTerminologyDehydration; Sweetening; ( )Stripper; Cracking; (->)Visbraking; Coking; Reforming; ( )Fractionator; Molecular sieve; Hydrosulfurization; BPSD; Baral per dayFlash; , C2; C 2

ii; isoN; NormalMMSCFD; ft3/dayCascade process; AR; Atmosphric ResidiuumARU; Atmosphric Residiuum UnitOCU; Olefins Conversion UnitFCC; Fluidized Catalytic CrackingAR; Atmosphric ResiduumBTX; Bensen, Toluen, Xylen


Plant

AA : Acetic AnhydrideAB : AkylbenzeneABS : Acrylonitrile Butadiene Styrene

copolymerACP : AcetophenoneADN : Adiponitrile()AGO : Atmospheric Gas OilAN : AcrylonitrileBDO : Butanediol()BPA : BisphenolBR : Butadiene RubberBTX : Benzene Toluene XyleneCBA : 4-Carboxy benzaldehydeCHP : Cumene Hydroperoxide()CTBN : Carboxy-terminated

Butadiene AcrylonitrileDEA : DiethanolamineDIPA : Di-isopropylamineDMPC : DimethylphenylcarbinolDMT : Dimethyl Therephthalate

EBHP : Ethylbenzene HydroperoxydeEDC : Ethylene DichlorideEG : Ethylene GlycolEH : EthylhexanolEO : Ethylene OxideEPDM: Ethylene Propylene Diene MonomerEPR : Ethylene Propylene RubberEPT: Ethylene Propylene TerpolymerFCC : Fluid bed Catalytic CrackingFRN : Full Range naphthaFT : Fischer-TropschHCN : Hydrogen CyanideHAD : HydrodealkylationHDPE : High Density PolyethyleneHMDA : HexamethylenediamineHR : High ResiliencyIPA : Isopropyl AlcoholLAB : Linear AlkylbenzeneLAS : Linear Alkylbenzene SulfonateLDPE : Low Density Polyethylene


Plant

LGN : Liquefied Petroleum GasLVN : Light Virgin naththaMA : Maleic AnhydrideMDI : Methylene Diphenyl DiisocynateMEA : MonoethanolamineMEK : Methyl Ethyl KetoneMFI : Melt Fluid IndexMMA : Methyl MethacrylateMTBE : Methyl tert-Butyl EtherNBR : Acrylonitrile Butadiene BubberNGL : Natural Gas LiquidPA : Phthalic AnhydridePABA : p-Aminobenzoic Acid PAO : Poly-Alpha OlefinPBT : Polybutylene TerephthalathPET : Polyethylene TerephthalathPO; Propylene OxidePP : PolypropylenePS : PolystyrenePTA : Pure Terephthalic Acid

PTAL : p-TolualdehydePCV : Polyvinyl ChloridePX : ParaxyleneRIM : Reaction Injection MoldingRON : Research Octane NumberROSE : Residual Oil Supercritical

ExtractionSAN : Styrene AcrylonitrileSBA : Sec-Butyl AlcoholSBR : Styrene Butadiene RubberSCP : Single Cell Protein

SM : Stylene MonomaSN : Sulfer NitrideTAME : tert-Amylmethyl EtherTBA : tert-Butyl AlcoholTDI : Toluene DiisocyanateTPA : Terephthalic AcidTPR : Transpolypentamer RubberVCM : Vinyl Chloride MonomerVGO : Vacuum Gas Oil


Plant

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DCS; digital control systemDCS; digital control systemCAS; civil, architecture, steelCAS; civil, architecture, steelHVAC; heating ventilating and air conditioningHVAC; heating ventilating and air conditioning


Plant

Worldwide Engineering Company

UOP : http://uop.com/

ABB Lummus Global : http://group.abb.com/

Becthel : http://www.becthel.com/

Kellog Brown & Root : http://www.halliburton.com/kbr/

Flour Daniel : http://www.fluordaniel.com/

Axens (IFP Group) : http://www.axens-group.com/

Linde AG : http://www.linde.com/

Lurgi AG : http://www.lurgi.com/

Stone & Webster : http://www.shawgrp.com/StoneWebster/

HALLIBURTONKBR


Plant

2005 9 26

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-1LDPE

HDPE

EDC

VCM

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S B R

SB-LATEX

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NAPHTHA

GAS OIL

NAPHTHACRACKING

CENTER

To BTX Extraction Plant


Plant

NAPHTHA

GAS OIL

D N T

O-XYLENE

P-XYLENE

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NAPHTHACRACKING

CENTER

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BENZENEEXTRACTION

PLANT

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Plant

Gas PlantNo. Process Description Major Licensor

1 H2 Hydrogen Plant CDTech, Haldor Topsoe2 H2/CO CO2 Removal from H2 rich gas Haldor Topsoe3 SRU Sulfur Recovery Unit TPA, Lurgi4 AGRP Acid Gas Removal Plant5 LNG Liquified Natural Gas Plant6 LPG Liquified Petroleum Gas Plant7 PSA Pressure Swing Absorption UOP, Linde

Chemical PlantNo. Process Description Licensor

1 AMMONIA & UREA Urea : Snamprogetti2 SULFURIC ACID Monsanto3 NITRIC ACID4 PHOSPHORIC ACID5 SOLVENT RECOVERY Sumitomo Chemical6 ALCOHOL PROCESS7 DETERGENT8 9 10 MSG Mono Sodium Glutamate

, -1


Plant

Refinery ProcessProcess Description Major Licensor

1. CDU or Topping Unit Crude Distillation Unit2. VDU Vacuum Distillation Unit3. GCU Gas Concentration Unit

Gas Recovery Unit1. Naphtha HDS Naphtha Hydrosulfurization unit UOP: Unifiner

IFP: NHT2. Kerosene or Diesel HDS Kero/Diesel Hydrosulfurization unit UOP: MDU (Middle Distillate Unifiner)3. AR HDS Atmospheric Residuum

Hydrodesulfurization UnitChevron

1. LPG Sweetening Unit LPG Sweetening UOP: LPG MeroxMerichem: Napfining unit

2. Naphtha Sweetening LSR Naphtha Sweetening

1. Reformer Reforming Unit UOP: PlatformerIFP: AromizerChevron: RheniformerEngelhard: Magnaformer

2. Isomerization Paraffin Isomerization UOP, ShellBP

3. Alkylation Alkylation of Olefin with iso-paraffin UOP, Phillips

1. FCC/RFCC Fluid Catalytic Cracking UnitResiduum Fluid Catalytic Cracking Unit

UOP: RCC

2. VGO Hydrocracker Hydrocracking of H.C UOP: HydrocrackingUnocal: UnicrackingChevron: Isocracking

1. Visbreaking Unit Thermal cracking of H.C UOP : Thermal Process

2. Delayed Coker Thermal cracking to produce coke FW

L

B

O

1. Lube Base Oil Lube Base Oil Catalytic Dewaxing Unit Mobil, Chevron

1. MTBE Methyl Tertiary Butyl Ether Unit UOP, IFP, BP, CDTech2. TAME Tertiary Amyl Methyl Ether CDTech3. SWTU Sour Water Treating Unit4. Residue Solvent Deasphalting Unit Solvent extraction of deasphalted oil

from asphaltene rich feedstockKBR: ROSE Unit (Residuum Oil Superextraction)

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Plant

Petrochemical ProcessNo. Process Description Major Licensor

1 Ethylene Naphtha/Gas Oil Cracking Kellog, ABB Lummus,Stone & Webster, Linde

2 BTX Aromatics Benzene, Toluene, Xylene UOP, IFP

3 Tatoray BTX Aromatics UOP

4 Sulfolane BTX Aromatics UOP, Shell

5 Parex Selective adsorption of paraxylene UOP

6 Isomar Xylene Isomerization UOP

7 Butadiene Extraction Distillationn-Butene Dehydrigenation

BASF, Exxon, ShellAir Products, Nippon Zeon

8 Benzene Benzene Recovery Krup Koppers

9 EB/SM Ethyl Benzene, Stylene Monomer Mobil, Monsanto, Basf, UOP

10 PO/SM Propylene Oxide, Stylene Monomer ABB Lummus, Union Carbide,BASF, Mitsui Toatsu

11 EO/EG Ethylene Oxide, Ethylene Glycol Snamprogetti, Union Carbide

12 TPA/DMT Terephthalic Acid/Dimethylterephthalate

Amoco, Toray Industries,Maruzen Oil

13 Caprolactam Caprolactam BASF, Toray Industries, Zimmer

14 Methanol Methyl Alcohol ICI, Snamprogetti, Lurgi, Kellog,Haldor Topsoe, BASF

15 Ethylamine DEA,MEA,MDEA,TEA

16 Ammonia Ammonia Kellog, Lurgi, Haldor Topsoe,Snamprogetti, ICI, Uhde

, -3


Plant

Polymer & Synthetic RubberNo. Process Description Major Licensor

1. PE Poly-Ethylene BASF, Sumimoto, Uhde, Mitsui,Solvay

2. PP Poly-Propylene BASF, Sumimoto, Uhde, Mitsui,Solvay

3. HDPE High Density Poly-Ethylene BP Chemical, Asahi Chemical,Solvay, Mitsubishi Chemicals

4. LDPE Low Density Poly-Ethylene BASF, Dow Chemical, ICI,Snamprogetti, Sumimoto

5. LLDPE Linear Low Density Poly-Ethylene BP Chemical, BASF

6. PET PolyEthylene Terephthalate Eastman Chemical

7. ABS Acrylonitrile-Butadiene-Stylene resins Monsanto, Toray Industries,Dow Chemicals

8. PS Poly-Stylene

9. EPS Elastic Poly-Stylene

10. PVC Poly-Vinyl Chloride ATOCHEM, BASF, Mitsui Toatsu,Solvay/ICI

1. BR Butadiene Rubber BASF, Mitsui

2. SBR Styrene Buradiene Rubber Japan Syhthetic Rubber

3. EPR

4. EPDM

5. URETHANE

6. MNB

7. ANILINE

8. MDI

9. PUR

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Plant

Molecular sieve Dehydration;

Dehydration ()


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Plant

LNG; GTL;


Plant

1)

FEED GAS

LNG

C3Pre-cooling

MR

1. C3-MR (C3 Pre-cooled Mixed Refrigerant process)- APCI

License

* C3 = propane(C3H8)

C3

MR; mixed refrigerant


Plant

2)

C3

GT=Gas TurbineM=MoterC1=(C1H4)C2=(C2H6)

=


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2. OPRC (Optimised Pure Refrigerant Cascade )- Conoco Phillips


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LNG

3. MFCP (The Mixed Fluid Cascade Process)- The Statoil-Linde

+++++

Coolingwater


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4. DMRP (Dual Mixed Refrigerant Process)- Axens/IFP

ST; steam turbine


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5. SMRP (Single Mixed Refrigerant Process)-Black & Veatch PRICO


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Plant

(Petroleum Refining) : ,

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: LPG

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Plant


Plant

LPGLPG

LPG

B-A

LRFOB-C


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CDU

iC4

LCOTo Diesel HDS

VDUAR

Fuel Oil

(Refinery) :Residue Upgrading : VDU - VGO FCC + Delayed Coker or VRDS or Visbreaker

GasolineSweetening

LCN(FCC Gasoline)

Deisobutanizer N-Butane

NC4 C4Isomerization

AlkylateAlkylation

MTBE MTBE

LPGRecovery Propylene

PropyleneRecovery

PropaneLPG

Sweetening

FCC

NaphthaHDS

Fuel Oil

VGO

GO HDS

DelayedCoker

VRDS

Visbreaker

Naphtha

Gas Oil

Naphtha

VisbreakerResidue

ReformerFeed

C3sC4s


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CDU

H/SCrude

LPG Sweetening

LPG Sweetening

Propane

Butane

LSR Naphtha Sweetening

LSR

Naphtha

* ARU SRP

Diesel HDS

H2 *Diesel

Diesel

Sulfur

Kerosene Sweetening

KeroseneJet Fuel

Kerosene HDS

H2 *

Kerosene

H2 PlantLPG,NGNaphtha H2

Low Sulfur Fuel Oil

ARDS

H2

AR

VDU

Asphalt Blowing

VR

VGO

Asphalt

(Refinery) : Hydroskimming

Naphtha HDS

H2 *

Reformer

H2

GasolinePool

ReformateNaphtha Gasoline


Plant

(Refinery) : Residue Upgrading ; ARDS+RFCC

CDU

Deisobutanizer

Alkylate

N-Butane

LPGSweetening

iC4

MTBE MTBE

LPGRecovery Propylene

RFCC LCOTo Diesel HDS

ARDS

H2

AR

Fuel Oil

Alkylation

NC4

GasolineSweetening

PropyleneRecovery

C4Isomerization

Propane

LCN(FCC Gasoline)


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Plant

LPG

STRIPPER

Stripper;


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Plant

EJECTOR

1

2

3

4


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Plant

( )

:

- Coil type : (480~500C) - Soaker type : (430~460C)

Soaker type Coil type 15~30 %

(Visbreaking)


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Plant

Visbreaking (510~590C)

: , ,

Delayed Coking


Plant


Plant

350C () :

: - riser - - stripping - - riser

Cacking;

(Catalytic Cracking)


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: - - - :

- CO CO

-

: , -, -,

: -

: 30~60 %, - 5~10 %,- 5~10 %, 5~10 %


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Plant

:

(reforming) :

45 kg/cm2 ( 500C) 3~4 - , : LPG : ( ) : , : ,


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:

-

- , , ,

: Unicracker, H/C Unibon, Isocracker, H-Oil, LC-Fining, Hycon, Canmet, SOC

(Hydrocracking)


Plant


Plant

NAPHTHA CRACKING Furnace


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NAPHTHA CRACKING -1


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NAPHTHA CRACKING -2


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GTL .

1) (Syngas) 2) FT (1920 Franz Fischer

Hans Tropsch ) (Syncrude)

3) Hydrocracking , ,

--(CO H2 ) (partial oxidation) : ,

, , CO2 . (CH4 + 1/2O2 CO + 2H2)

(steam reforming): (H2O) 870oC . , . (CH4 + H2O CO + 3H2)

Autothermal : , . Start/Stop , Syntroleum


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-- :

FT ; (CO +2H2 -CH2- + H2O)

* -CH2- . C1C4 : C5 : (: C10C20) C20 :

----FT-GTL , , 20 . .


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Plant

GTL


Plant

GeneratorMain air CompressorSteam

Turbine

Steam Turbine

Booster air Compressor

SyngasCompressor

SyngasReactor Hydrocarbon Synthesis

Reactor

Air Separation Unit

Gas Turbine

Air

Dry Air

Natural Gas

Steam

Oxygen

Syngas

Tail gas

Synthetic crude

GTL


Plant

GTL

-Chevron- UOP- Axens

- / . Sasol SPD. Shell SMDS. Exxon AGC-21. Syntrolum. Rentech

- . PDVSA/Intevep. Willams/EI. BP. Axens. Statoil/Mossgas. Conoco

- Steam Reforming. Lurgi. Haldor Topsoe. Uhde. Kinetics Technology

- Partial Oxidation. Texaco. Royal Dutch/Shell

- Autothermal Reforming. Uhede. Lurgi. Haldor Topse

HydrocrackingGTL(FT Conversion)Syngas


Plant

Thank you!Thank you!

석유화학Plant.pdf

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