海水环境化学实验
description
Transcript of 海水环境化学实验
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pH --
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pHpH
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pH
pHg
pH
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pHx pHpHs pHEx Es H 8.315F 96500T 273.16
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pHC6H4COOKCOOH25pH4.00325pH6.864Na2B4O7.10H2O25pH9.182
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pH1 C6H4COOKCOOH KH2PO4)11552 Na2HPO4)11522 Na2B4O7.10H2O 210-6S/cm 10
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2 10.12C6H4COOKCOOH10.05/ 3.388KH2PO43.530Na2HPO410.025/ 3.800Na2B4O7.10H2O11 pH 40KCl100
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10.01pHDelta3202060
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1. 30Progb2(b13)2. pH3. pHpH
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pH pHwpHmtmtwd500 pHw pHmtmtwpHwpHm pH tw tm d tm tw
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24pHpH2pH
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()I-
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1233%411560.0100/713
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1150 220303250.05425052506101750213
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1 10.000.511325034 0.0524
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2 1/2
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3 1.01.020244 11.0115
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5 5034200.05
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1
/
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2
/ V V1 f1 V2/V22V22
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3
O2 /1.429 / /1mg/L=1.429ml/L; 1ml/L=0.77mg/L
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NaS2O3 I-I2
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H2SI22HIS I2 2Na2S2O3Na2S4O62NaI H2S I2 2Na2S2O3 117 0.2/
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1. 0.0100/ 2.50Na2S2O3.5H2O1000.2Na2CO30.01/0.01/2. 3% 50 [C3H5(OH)3] 1.5 [(C6H10O5)n] 19013.11 HCl4. 0.01/ 2KI100.2542005. 0.0100/ KIO312020.356716. 13 50H2SO4d1.84150
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1100220303250.0542505250610075001000810055005500109101050111211111213100200500100014
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1 10.000.511325034 0.0524
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2. 1002110.2 100
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3. 50340.01/200.05
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4. 2~30.05
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V /V1V2
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/
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--
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543nm 0.02/
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116 50HCl30021% 5.0NH2SO2C6H4H2N35016500230.1% 0.50C10H7NHCH2.CH2.NH2.2HCl50014 a5.00/ 0.0345NaNO211010012b0.050/ 1.00100
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121005001000350500450510050062505001000750081915101151512. 100500100013
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125000.51.02.03.04.01.051.015543nm5AiAoAiAo/
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C123456789101112V000.50.51.01.02.02.03.03.04.04.0505050505050505050505050 AiAo
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50.01bdAw
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An AnAo An
CNO2N / An a b
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210255011+6At AnAwAoAt
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2
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0.03/
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40% 201001+1-0.1/ 2.8KBrO320.0KBr1 1.0-5031+155040%0.2% 1.0NH2SO2C6H4H2N5001+1, 0.1% 0.50,500, 10.0/ 0.05349NH4Cl100110010.050/ 0.5100
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121001000350100500 45051005006500750082915101011515212
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1 125000.501.00 2.505.008.00530551154543nm5AiAoAiAo/ab
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C123456789101112V000.500.501.001.002.502.505.005.008.008.00505050505050505050505050AiAo
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2 50.0 1bdAw
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/abk()
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1202
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882nm0.02/
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1+560H2SO4300, 3% 3.0 [(NH4)6Mo7O24.4H2O] 100 0.14KSbO.C4H4O6.1/2H2O100 4010020 5.40C6H8O6100418.00/ 0.1088KH2PO41101151210010.080
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12100100035010025050045051510617. 8
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00.250.501.001.502.0050504.01.01010882nmAiAoAiAo/ ab
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C123456789101112V000.250.250.500.501.001.001.501.502.002.00505050505050505050505050AiAo
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500.451bAw
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An
An
c( /An a b AnAo
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480.5/2S/154502.51+5At AnAwAoAt
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0.15/
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25% 25NaOH10013 1H2SO430.0100/ 0.3567KIO3120210.0100/0.01/ 2.5Na2S2O3.5H2O0.210.01/ 0.32KMnO45010173% 3 [C3H5(OH)3]100190
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12525312104250525061005007100500100081259G41011150140/1235251314300015. 16
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10.000.51.0132503~4 0.0524
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1002501 25%NaOH10.000.01/1051+30.450.01/3~40.05V1
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13V2
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1.
/
2.
/V2 V1 V COD /
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(Organoehlofine pesticidesOCPs)(HCH)(DDT)121OCPs10 104 HCHDDT OCPsOCPs
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OSPs-666-666-666-666PP-DDT, PP-DDD, PP-DDE
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()68-6958-59(6504 h)2%20g1000mL()99.9%8-666-666-666-666PP-DDT, PP-DDD, PP-DDE1mg/mL.0.05g/mL.
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Ni63SE-540.22cm,25cm,0.25 m100 mL1 L
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250 mL500 mL25 mL30 min(60-80min)500 mL10 g100 mL10 mL2.0 mL0.2 mL0.5 min2000 rmin15 min1.0 mL 1mL
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:150-270 ,16 min4min220 10 min290 290 2.0 mLmin50 mLmin1.0 L 0.2mV, 0.5mV/30min.
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OCPs
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Wi-OCPs10-9Ai iAk- iAb- iVi -mL)Vb- (L )Vj-(L )Ci-i(g/mL) W-(g)R-(%)
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7.1
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() () (): : (:mL/min): :
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23