8/18/2019 011abr

1/7

 

MATERIAL SAFETY DATA SHEET

SECTION 1 -- PRODUCT AND COMPANY IDENTIFICATION

CUSTOMER: ABRO INDUSTRIES, INC.

PRODUCT NUMBER: SP-011

PRODUCT NAME: ABRO Spray Paint, Gloss Black

ISSUE DATE: Sept. 14, 2007

PREPARED BY: SKSMANUFACTURER: ABRO INDUSTRIES, INC.

3580 Blackthorn Court

South Bend, IN 46628

EMERGENCY TELEPHONE NUMBER: 800-424-9300 (24 Hours)* *for medical, spill, leak, fire or transport accident emergencies

SECTION 2 -- COMPOSITION/INFORMATION ON INGREDIENTS

% by WT

CAS No. INGREDIENT UNITS VAPOR PRESSURE

18  74-98-6  Propane ACGIH TLVOSHA PEL

2500ppm1000ppm 

760 mm 

17  106-97-8  Butane ACGIH TLVOSHA PEL

800ppm800ppm  760 mm 

4  64742-89-8 

Lt. AliphaticHydrocarbonSolvent ACGIH TLVOSHA PEL

100ppm100 ppm 

53 mm 

6  64742-89-8 

 V.M.&P. Naphtha ACGIH TLVOSHA PELOSHA PEL

300ppm300ppm400ppm STEL 

12 mm 

14  108-88-3  Toluene

 ACGIH TLVOSHA PELOSHA PEL

20ppm

100ppm(Skin)150ppm(Skin)STEL 

22 mm

8/18/2019 011abr

2/7

 

1  95-63-6  1,2,4-Trimethylbenzene ACGIH TLVOSHA PEL

25 ppm25 ppm 

2.03 mm 

29  67-64-1  Acetone ACGIH TLV ACGIH TLVOSHA PEL

500 ppm750 ppm STEL1000 ppm 

180 mm 

0.6  1333-86-4  Carbon Black ACGIH TLVOSHA PEL

3.5 mg/m33.5 mg/m3 

SECTION 3 -- HAZARDS IDENTIFICATION

ROUTES OF EXPOSUREINHALATION  of vapor or spray mist.EYE or SKIN  contact with the product, vapor or spray mist.

EFFECTS OF OVEREXPOSUREEYES: Irritation.SKIN: Prolonged or repeated exposure may cause irritation.INHALATION: Irritation of the upper respiratory system.May cause nervous system depression. Extreme overexposure mayresult in unconsciousness and possibly death. Prolongedoverexposure to solvent ingredients in Section 2 may causeadverse effects to the liver, urinary, cardiovascular and

reproductive systems.SIGNS AND SYMPTOMS OF OVEREXPOSURE

Headache, dizziness, nausea, and loss of coordination areindications of excessive exposure to vapors or spray mists.Redness and itching or burning sensation may indicate eye orexcessive skin exposure.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURENone generally recognized.

CANCER INFORMATIONFor complete discussion of toxicology data refer to Section 11.

SECTION 4 -- FIRST AID MEASURES

EYES: Flush eyes with large amounts of water for 15 minutes.Get medical attention.SKIN: Wash affected area thoroughly with soap and water.Remove contaminated clothing and launder before re-use.

8/18/2019 011abr

3/7

 

INHALATION: If affected, remove from exposure. Restore breathing.Keep warm and quiet.INGESTION: Do not induce vomiting. Get medical attentionimmediately.

SECTION 5 -- FIRE FIGHTING MEASURES

FLASH POINT  LEL UELPropellant < 0 F 0.9 12.8

EXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, FoamUNUSUAL FIRE AND EXPLOSION HAZARDSContainers may explode when exposed to extreme heat.

 Application to hot surfaces requires special precautions.During emergency conditions overexposure to decompositionproducts may cause a health hazard. Symptoms may not beimmediately apparent. Obtain medical attention.SPECIAL FIRE FIGHTING PROCEDURESFull protective equipment including self-contained breathingapparatus should be used. Water spray may be ineffective. Ifwater is used, fog nozzles are preferable. Water may be used tocool closed containers to prevent pressure build-up and possibleauto ignition or explosion when exposed to extreme heat.

SECTION 6 -- ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDRemove all sources of ignition. Ventilate the area.Remove with inert absorbent.

SECTION 7 -- HANDLING AND STORAGE

STORAGE CATEGORY: Not AvailablePRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEKeep away from heat, sparks, and open flame. Vapors willaccumulate readily and may ignite explosively.During use and until all vapors are gone: Keep area ventilated -Do not smoke - Extinguish all flames, pilot lights, and heaters -Turn off stoves,electric tools and appliances, and any othersources of ignition. Consult NFPA Code. Use approved Bonding andGrounding procedures. Contents under pressure. Do not puncture,incinerate, or expose to temperature above 120F. Heat fromsunlight, radiators, stoves, hot water,and other heat sourcescould cause container to burst. Do not take internally. Keep outof the reach of children.

8/18/2019 011abr

4/7

 

SECTION 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USEUse only with adequate ventilation.

 Avoid contact with skin and eyes. Avoid breathing vapor and spray

mist. Wash hands after using. This coating may contain materialsclassified as nuisance particulates (listed "as Dust" in Section2) which may be present at hazardous levels only during sandingor abrading of the dried film. If no specific dusts are listed inSection 2, the applicable limits for nuisance dusts are ACGIH TLV10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of oldpaint by sanding, scraping or other means may generate dust orfumes that contain lead. Exposure to lead dust or fumes may causebrain damage or other adverse health effects, especially inchildren or pregnant women. Controlling exposure to lead or otherhazardous substances requires the use of proper protectiveequipment, such as a properly fitted respirator (NIOSH approved)and proper containment and cleanup. For more information, callthe National Lead Information Center at 1-800-424-LEAD (in US) orcontact your local health authority.

 VENTILATION

Local exhaust preferable. General exhaust acceptable if theexposure to materials in Section 2 is maintained below applicableexposure limits. Refer to OSHA Standards 1910.94, 1910.107,1910.108.

RESPIRATORY PROTECTIONIf personal exposure cannot be controlled below applicable limitsby ventilation, wear a properly fitted organic vapor/particulate

respirator approved by NIOSH/MSHA for protection againstmaterials in Section 2. When sanding or abrading the dried film,wear a dust/mist respiratorapproved by NIOSH/MSHA for dust which may be generated from thisproduct, underlying paint, or the abrasive.

PROTECTIVE GLOVESNone required for normal application of aerosol products whereminimal skin contact is expected. For long or repeated contact,wear chemical resistant gloves.

EYE PROTECTIONWear safety spectacles with unperforated sideshields.

OTHER PRECAUTIONS

Intentional misuse by deliberately concentrating and inhaling thecontents can be harmful or fatal.

8/18/2019 011abr

5/7

 

SECTION 9 -- PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT

SPECIFICGRAVITY

BOILINGPOINT

MELTINGPOINT

 VOLATILE VOLUME

EVAPORATIONRATE

5.80lb/gal694 g/l

0.70

8/18/2019 011abr

6/7

 TOXICOLOGY DATA

SECTION 12 -- ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATIONNo data available.

SECTION 13 -- DISPOSAL CONSIDERATIONS

 WASTE DISPOSAL METHOD

CAS No. Ingredient Name

74-98-6 PropaneLC50 RAT 4HR Not AvailableLD50 RAT Not Available

106-97-8 ButaneLC50 RAT 4HR Not AvailableLD50 RAT Not Available

64742-89-8 Lt. Aliphatic HydrocarbonSolventLC50 RAT 4HR Not AvailableLD50 RAT Not Available

64742-89-8  V. M. & P. NaphthaLC50 RAT 4HR Not AvailableLD50 RAT Not Available

108-88-3 TolueneLC50 RAT 4HR 4000 ppmLD50 RAT 5000 mg/kg

95-63-6 1,2,4-TrimethylbenzeneLC50 RAT 4HR Not AvailableLD50 RAT Not Available

67-64-1 AcetoneLC50 RAT 4HR Not Available

LD50 RAT 5800 mg/kg

1333-86-4 Carbon BlackLC50 RAT 4HR Not AvailableLD50 RAT Not Available

8/18/2019 011abr

7/7

 

Waste from this product may be hazardous as defined under theResource Conservation and Recovery Act (RCRA) 40 CFR 261.

Waste must be tested for ignitability to determine the applicableEPA hazardous waste numbers. Do not incinerate. Depressurizecontainer. Dispose of in accordance with Federal,State/Provincial, and Local regulations regarding pollution.

SECTION 14 -- TRANSPORT INFORMATION

US Ground (DOT)May be classed as Consumer Commodity, ORM-DUN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)Canada (TDG) May be classed as Consumer Commodity, ORM-DUN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2,LIMITED QUANTITY, EmS F-D, S-U Section 15 -- REGULATORYINFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATIONCAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 1495-63-6 1,2,4-Trimethylbenzene 1CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State ofCalifornia to cause cancer and birth defects or otherreproductive harm.TSCA CERTIFICATION

 All chemicals in this product are listed, or are exempt fromlisting, on the TSCA Inventory.

SECTION 16 -- OTHER INFORMATION

This product has been classified in accordance with the hazardcriteria of the Canadian Controlled Products Regulations (CPR)and the MSDS contains all of the information required by the CPR.The above information pertains to this product as currentlyformulated,and is based on the information available at thistime. Addition of reducers or other additives to this product maysubstantially alter the composition and hazards of the product.Since conditions of use are outside our control, we make nowarranties, express or implied, and assume no liability inconnection with any use of this information.