第 1 章 エネルギー量子とスペクトル...
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Transcript of 第 1 章 エネルギー量子とスペクトル...
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1 Newton110-10 m5. *
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11 microscopicmacroscopic
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112 p.7825 c(2.998108 m s-1) c
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5a. hh c / (16) h6.62610-34 J sPlanckc2.998108 m s-1
h *
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O2O=O497 kJ mol-18.25310-19 J(16) hc/(6.62610-34 J s)(2.998108 m s-1) 8.25310-19 J 2.4110-7 m241 nm !()*
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p.691385b. E h Eh (17)
E()E
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DNA250300 nm(5b) DNA DNA(A)(G)(C)(T)42ATGC15*
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113
p.810.192-1
p.69138(5) *
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(5)
p.69138p.8101
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5c.
13p.810.114p.101719211c
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3Lambert-Beer-
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12 121 (5)E(5b)*
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a CoCl2CoCl26H2OCoBr219 23Cu(NH3)42+, Cu(H2O)42+
()d*
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b ()
3HC-CH3 2HC=CH2 CHCH 1.54 1.34 1.20 kJ mol-1 368 720 962
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C=C
1.3991.3341.50
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150.5 kJ mol-1223
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I21000 25 2000 *
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PH4.4 580590 nm PH3.1 650750 nm)
3
EBT1*
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122 11-cis-
11-cis-*
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13 131 (5)()
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5c. 132
133 Fraunhofer(5b)
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134 1868
(5)
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135 a 1000 1960861983
b 19671339,192,631,7701*
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14 141 5. a 02b 3 3 2 3n63n5 2H2O3CO24 p.10341646CO2
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343-14
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c (5)(5b)
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(5)(5b)
CO2
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143 q2r1r2 p q(r1r2) q p q l l|r1r2| q l
O-H(OH)OH () *
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144 cm-1 1 cm-11.98610-23 Jcm-1hc 1 cm-1h c cm-1 (6.62610-34 J s)(2.998108 m s-1)(102 m-1) 1.98610-23 J
E5003500 cm-1p.10 1719
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p.101719-NH3N-H-NH3-NH3HClHClH-Cl
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T 1 EK (3/2)kBT < > kBBoltzmann kBR / NA1.3806610-23 J K-1 (18)
PVnRTnRTnVP
KBoltzmannkBK 1 KkB K(1.3806610-23 J K-1)(K)1.3806610-23 J
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O2O=O8.25310-19 J1124K E *
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5.
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5a. hh c / (16) h6.62610-34 J sPlanckc2.998108 m s-1
5b. E h Eh (17)
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5c.
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