Unifac en Excel

temperatura 325 UNO DOS

grupo subgrupo

Alcano

1 CH3 1 12 CH2 2 43 CH 24 C

Alqueno

5 CH2=CH6 CH=CH7 CH2=C8 CH=C9 C=C

Aromatico3

10 ACH11 AC

12 ACCH313 ACCH214 ACCH

Alcohol

5 15 OH 16 16 CH3OH7 17 H2O8 18 ACOH

Cetona9

19 CH3CO20 CH2CO

Aldehído 10 21 CHO

Ester 1122 CH3COO23 CH2COO

12 24 HCOO

Éter 13

25 CH3O26 CH2O27 CH-O28 FCH2O

Amino, 1st 1429 CH3NH230 CH2NH231 CHNH2

Amino, 2nd 1532 CH3NH33 CH2NH34 CHNH

Amino, 3rd 1635 CH3N36 CH2N

Anilina 17 37 ACNH2

Piridina 1838 C5H5N39 C5H4N40 C5H3N

Nitrilo 1941 CH3CN42 CH2CN

Acido 2043 COOH44 HCOOH

Chloride 2145 CH2Cl46 CHCl47 CCl

Dichloride 2248 CH2Cl249 CHCl250 CCl2

Other Chloride23

51 CHCl352 CCl3

24 53 CCl425 54 ACCl

Nitro26

55 CH3NO256 CH2NO257 CHNO2

27 58 ACNO2Disulfide 28 59 CS2

Thiol 2960 CH3SH61 CH2SH

Furfural 30 62 furfuralEthanediol 31 63 (CH2OH)2

iodo 32 64 Ibromo 33 65 Br

alkyne 3466 CH=-C67 C=-C

Dimetilsulfoxyde 35 68 DMSOAcrylonitrile 36 69 ACRY

Trichloroethylene 37 70 Cl-(C=C)Fluorobenzene 38 71 ACF

Formamide 3972 DMF-173 DMF-2

Fluorides 4074 CF375 CF2

Fluorides 4076 CF

Flexy Ester 41 77 COO

Silane 42

78 SiH379 SiH280 SiH81 Si

Siloxane 4382 SiH2O83 SiHO84 SiO

Methylpyrrolidone 44 85 NMP

Chlorofluorocarbons 45

86 CCl3F87 CCl2F88 HCCl2F89 HCClF90 CClF291 HCClF292 CClF393 CCl2F2

Amides 46

94 CONH295 CONHCH396 CONHCH297 CON(CH3)298 CONCH3CH299 CON(CH2)2

Glycol Ethers 47100 C2H5O2101 C2H4O2

Sulfides

48102 CH3S103 CH2S104 CHS

49 105 Morpholine

50106 C4H4S107 C4H3S108 C4H2S

0.34 2.144580.66 1.41552

Instrucciones

Marcell Maldonado

A la derecha de cada celda se coloca el dato correspondiente (celdas verdes). La temperatura se ingresa en grados Kelvin. Para fracción mol adimensional y para la especie UNO. Para los subgrupos las cantidades presentes en cada molécula. En la columna UNO para el compuesto 1, por igual a la columna DOS. La respuesta se localiza a la derecha de los coeficientes de actividad adimensionales.

temperarura 325

grupo subgrupo k

Alcano

CH3 1 0.9011 0.8480CH2 2 0.6744 0.5400CH 3 0.4469 0.2280C 4 0.2195 0.0000

Alqueno

CH2=CH 5 1.3454 1.1760CH=CH 6 1.1167 0.8670CH2=C 7 1.1173 0.9880CH=C 8 0.8886 0.6760C=C 7 0.6605 0.4850

Aromatico3

ACH 9 0.5313 0.4000AC 10 0.3652 0.1200

ACCH3 11 1.2663 0.9680ACCH2 12 1.0396 0.6600ACCH 13 0.8121 0.3480

Alcohol

5 OH 14 1.0000 1.20006 CH3OH 15 1.4311 1.43207 H2O 16 0.9200 1.40008 ACOH 17 0.8952 0.6800

Cetona 9CH3CO 18 1.6724 1.4880CH2CO 19 1.4457 1.1800

Aldehido 10 CHO 20 0.9980 0.9480

Ester 11CH3COO 21 1.9031 1.7280CH2COO 22 1.6764 1.4200

12 HCOO 23 1.2420 1.1880

Ether 13

CH3O 24 1.1450 1.0880CH2O 25 0.9183 0.7800CH-O 26 0.6908 0.4680

FCH2O 27 0.9183 1.1000

Amine, 1st 14CH3NH2 28 1.5959 1.5440CH2NH2 29 1.3692 1.2360CHNH2 30 1.1417 0.9240

Amine, 2nd 15CH3NH 31 1.4337 1.2440CH2NH 32 1.2070 0.9360CHNH 33 0.9795 0.6240

Amine, 3rd 16CH3N 34 1.1865 0.9400CH2N 35 0.9597 0.6320

Aniline 17 ACNH2 36 1.0600 0.8160

Pyridine 18C5H5N 37 2.9993 2.1130C5H4N 38 2.8332 1.8330

Pyridine 18C5H3N 39 2.6670 1.5530

Nitrile 19CH3CN 40 1.8701 1.7240CH2CN 41 1.6434 1.4160

Acid 20COOH 42 1.3013 1.2240

HCOOH 43 1.5280 1.5320

Chloride 21CH2Cl 44 1.4654 1.2640CHCl 45 1.2380 0.9520CCl 46 1.0060 0.7240

Dichloride 22CH2Cl2 47 2.2564 1.9880CHCl2 48 2.0606 1.6840CCl2 49 1.8016 1.4480

Other Chloride23

CHCl3 50 2.8700 2.4100CCl3 51 2.6401 2.1840

24 CCl4 52 3.3900 2.910025 ACCl 53 1.1562 0.8440

Nitro 26CH3NO2 54 2.0086 1.8680CH2NO2 55 1.7818 1.5600CHNO2 56 1.5544 1.2480

27 ACNO2 57 1.4199 1.1040Disulfide 28 CS2 58 2.5070 1.6500

Thiol 29CH3SH 59 1.8770 1.6760CH2SH 60 1.6510 1.3680

Furfural 30 furfural 61 3.1680 2.4810Ethanediol 31 (CH2OH)2 62 2.4088 2.2480

iodo 32 I 63 1.2640 0.9920bromo 33 Br 64 0.9492 0.8320

alkyne 34CH=-C 65 1.2929 1.0880C=-C 66 1.0613 0.7840

Dimetilsulfoxyde 35 DMSO 67 2.8266 2.4720Acrylonitrile 36 ACRY 68 2.3144 2.0520

Trichloroethylene 37 Cl-(C=C) 69 0.7910 0.7240Fluorobenzene 38 ACF 71 0.6948 0.5240

Formamide 39DMF-1 72 3.0856 2.7360DMF-2 73 2.6322 2.1200

Fluorides 40CF3 74 1.4060 1.3800CF2 75 1.0105 0.9200CF 76 0.6150 0.4600

Flexy Ester 41 COO 77 1.3800 1.2000

Silane 42

SiH3 78 1.6035 1.2630SiH2 79 1.4443 1.0060SiH 80 1.2851 0.7490Si 81 1.0470 0.4100

Siloxane 43SiH2O 82 1.4838 1.0620

Siloxane 43 SiHO 83 1.3030 0.7640SiO 84 1.1044 0.4660

Methylpyrrolidone 44 NMP 85 3.9810 3.2000

Chlorofluorocarbons 45

CCl3F 86 3.0356 2.6440CCl2F 87 2.2287 1.9160

HCCl2F 88 2.4060 2.1160HCClF 89 1.6493 1.4160CClF2 90 1.8174 1.6480

HCClF2 91 1.9670 1.8280CClF3 92 2.1721 2.1000

CCl2F2 93 2.6243 2.3760

Amides 46

CONH2 94 1.4515 1.2480CONHCH3 95 2.1905 1.7960CONHCH2 96 1.9637 1.4880CON(CH3)2 97 2.8589 2.4280

CONCH3CH2 98 2.6322 2.1200CON(CH2)2 99 2.4054 1.8120

Glycol Ethers 47C2H5O2 100 2.1226 1.9040C2H4O2 101 1.8952 1.5920

Sulfides

48CH3S 102 1.6130 1.3680CH2S 103 1.3863 1.0600CHS 104 1.1589 0.7480

49 Morpholine 105 3.4740 2.7960

50C4H4S 106 2.8569 2.1400C4H3S 107 2.6908 1.8600C4H2S 108 2.5247 1.5800

cantidad 1 cantidad 21.0000 1.0000 0.9011 0.9011 0.848 0.848 0.27109972.0000 4.0000 1.3488 2.6976 1.08 2.16 0.34526850.0000 2.0000 0 0.8938 0 0.456 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 01.0000 0.0000 1 0 1.2 0 0.38363170.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 0

r1/parcial r2/parcial q1/parcial q2/parcial eki i=1

eki=vk( i)Q kqi

0.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 0

0.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 00.0000 0.0000 0 0 0 0 0

R1 R2 Q1 Q2 0.2448037 1 3.2499 4.4925 3.128 3.4640.6235566 1 J1 J2 L1 L20.1316397 1 0.798498089 1.103804 0.933798242 1.0341039

0 0 ln γc1 ln γc1 ln γr1 ln γr20 0 0.158459193 0.0326174 0.604483412 0.31487770 00 0 2.144577591

0 0 1.4155173270 00 00 00 00 00 00 10 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 0

eki i=2

ri=∑kvk(i )Rk q i=∑

(i )Qk

0 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 0

0 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 0

Alcano Alqueno Aromatico Alcohol

1 2 3 4 5 6

1 0.000 86.020 61.130 76.500 986.500 697.2002 -35.360 0.000 38.810 74.150 524.100 787.6003 -11.120 3.446 0.000 167.000 636.100 637.4004 -69.700 -113.600 -146.800 0.000 803.200 603.3005 156.400 457.000 89.600 25.820 0.000 -137.1006 16.510 -12.520 -50.000 -44.500 249.100 0.0007 300.000 496.100 362.300 377.600 -229.100 289.6008 275.800 217.500 24.340 244.200 -451.600 -265.2009 26.760 42.920 140.100 365.800 164.500 108.70010 505.700 56.300 23.390 106.000 529.000 -340.20011 114.800 132.100 85.840 170.000 245.400 249.60012 329.300 110.400 18.120 428.000 139.400 227.80013 83.360 26.510 52.130 65.690 237.700 238.40014 -30.480 1.163 -44.850 296.400 -242.800 -481.70015 65.330 -28.700 -22.310 223.000 -150.000 -370.30016 -83.980 -25.380 -223.900 109.900 28.600 -406.80017 1139.000 2000.000 247.500 762.800 -17.400 -118.10018 -101.600 -47.630 31.870 49.800 -132.300 -378.20019 24.820 -40.620 -22.970 -138.400 185.400 162.60020 315.300 1264.000 62.320 89.860 -151.000 339.80021 91.460 40.250 4.680 122.900 562.200 529.00022 34.010 -23.500 121.300 140.800 527.600 669.90023 36.700 51.060 288.500 69.900 742.100 649.10024 -78.450 160.900 -4.700 134.700 856.300 709.60025 106.800 70.320 -97.270 402.500 325.700 612.80026 -32.690 -1.996 10.380 -97.050 261.600 252.60027 5541.000 0.000 1824.000 -127.800 561.600 0.00028 -52.650 16.620 21.500 40.680 609.800 914.20029 -7.481 0.000 28.410 19.560 461.600 448.60030 -25.310 82.640 157.300 128.800 521.600 0.00031 139.900 0.000 221.400 150.600 267.600 240.80032 128.000 0.000 58.680 26.410 501.300 431.30033 -31.520 174.600 -154.200 1112.000 524.900 494.70034 -72.880 41.380 0.000 0.000 68.950 0.00035 50.490 64.070 2.504 -143.200 -25.870 695.00036 -165.900 573.000 -123.600 397.400 389.300 218.80037 47.410 124.200 395.800 419.100 738.900 528.00038 -5.132 -131.700 -237.200 -157.300 649.700 645.90039 -31.950 249.000 -133.900 -240.200 64.160 172.20040 147.300 62.400 140.600 0.000 0.000 0.00041 529.000 1397.000 317.600 615.800 88.630 171.000

UNIFAC: Parámetr

os aij

GRUPO PRINCIPAL

42 -34.260 0.000 787.900 0.000 1913.000 0.00043 110.200 0.000 234.400 0.000 0.000 0.00044 13.890 -16.110 -23.880 6.214 796.900 0.00045 30.740 0.000 167.900 0.000 794.400 762.70046 27.970 9.755 0.000 0.000 394.800 0.00047 -11.920 132.400 -86.880 -19.450 517.500 0.00048 39.930 543.600 0.000 0.000 0.000 420.00049 -23.610 161.100 142.900 274.100 -61.200 -89.24050 -8.479 0.000 23.930 2.845 682.500 597.800

Alcohol Cetona

Ester Ether

7 8 9 10 11 12 13

1318.000 1333.000 476.400 677.000 232.100 507.000 251.500270.600 526.100 182.600 448.800 37.850 333.500 214.500903.800 1329.000 25.770 347.300 5.994 287.100 32.1405695.000 884.900 -52.100 586.800 5688.000 197.800 213.100353.500 -259.700 84.000 -203.600 101.100 267.800 28.060-181.000 -101.700 23.390 306.400 -10.720 179.700 -128.6000.000 324.500 -195.400 -116.000 72.870 0.000 540.500

-601.800 0.000 -356.100 -271.100 -449.400 0.000 -162.900472.500 -133.100 0.000 -37.360 -213.700 -190.400 -103.600480.800 -155.600 128.000 0.000 -110.300 766.000 304.100200.800 -36.720 372.200 185.100 0.000 -241.800 -235.7000.000 0.000 385.400 -236.500 1167.000 0.000 -234.000

-314.700 -178.500 191.100 -7.838 461.300 457.300 0.000-330.400 0.000 0.000 0.000 0.000 0.000 222.100-448.200 0.000 394.600 0.000 136.000 0.000 -56.080-598.800 0.000 225.300 0.000 2889.000 0.000 -194.100-341.600 -253.100 -450.300 0.000 -294.800 0.000 0.000-332.900 -341.600 29.100 0.000 0.000 554.400 -156.100242.800 0.000 -287.500 0.000 -266.600 99.370 38.810-66.170 -11.000 297.800 -165.500 -256.300 193.900 -338.500698.200 0.000 286.300 -47.510 35.380 0.000 225.400708.700 0.000 82.860 190.600 -133.000 0.000 -197.700826.800 0.000 552.100 242.800 176.500 235.600 -20.9301201.000 10000.000 372.000 0.000 129.500 351.900 113.900-274.500 622.300 518.400 0.000 -171.100 383.300 -25.150417.900 0.000 -142.600 0.000 129.300 0.000 -94.490360.700 0.000 -101.500 0.000 0.000 0.000 0.0001081.000 1421.000 303.700 0.000 243.800 0.000 112.4000.000 0.000 160.600 0.000 0.000 201.500 63.71023.480 0.000 317.500 0.000 -146.300 0.000 -87.310-137.400 838.400 135.400 0.000 152.000 0.000 9.2070.000 0.000 138.000 245.900 21.920 0.000 476.6000.000 0.000 -142.600 0.000 24.370 0.000 736.4000.000 0.000 443.600 0.000 0.000 0.000 0.000

-240.000 0.000 110.400 0.000 41.570 0.000 -93.510386.600 0.000 0.000 354.000 175.500 0.000 0.0000.000 0.000 -40.900 183.800 611.300 134.500 -217.9000.000 0.000 0.000 0.000 0.000 0.000 167.300

-287.100 0.000 97.040 13.890 -82.120 -116.700 -155.2000.000 0.000 0.000 0.000 0.000 0.000 0.000

284.400 -167.300 123.400 577.500 -234.900 145.400 -247.800

180.200 0.000 992.400 0.000 0.000 0.000 448.5000.000 0.000 0.000 0.000 0.000 0.000 0.000

832.200 -234.700 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.000

-509.300 0.000 0.000 0.000 0.000 0.000 0.000-205.700 0.000 156.400 0.000 -3.444 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.000

-384.300 0.000 0.000 0.000 0.000 0.000 0.0000.000 810.500 278.800 0.000 0.000 0.000 0.000

Amine, 1st Amine, 2nd Amine, 3rd

Pyridine Nitrile Acid

14 15 16 17 18 19 20

391.500 255.700 206.600 920.700 287.800 597.000 663.500240.900 163.900 61.110 749.300 280.500 336.900 318.900161.700 122.800 90.490 648.200 -4.449 212.500 537.40019.050 -49.290 23.500 664.200 52.800 6096.000 872.3008.642 42.700 -323.000 -52.390 170.000 6.712 199.000

359.300 -20.980 53.900 489.700 580.500 53.280 -202.00048.890 168.000 304.000 243.200 459.000 112.600 -14.0900.000 0.000 0.000 119.900 -305.500 0.000 408.9000.000 -174.200 -169.000 6201.000 7.341 481.700 669.4000.000 0.000 0.000 0.000 0.000 0.000 497.5000.000 -73.500 -196.700 475.500 0.000 494.600 660.2000.000 0.000 0.000 0.000 -233.400 -47.250 -268.100-78.360 251.500 5422.000 0.000 213.200 -18.510 664.6000.000 -107.200 -41.110 -200.700 0.000 358.900 0.000

127.400 0.000 -189.200 0.000 0.000 147.100 0.00038.890 865.900 0.000 0.000 0.000 0.000 0.000-15.070 0.000 0.000 0.000 89.700 -281.600 -396.0000.000 0.000 0.000 117.400 0.000 -169.700 -153.700

-157.300 -108.500 0.000 777.400 134.300 0.000 0.0000.000 0.000 0.000 493.800 -313.500 0.000 0.000

131.200 0.000 0.000 429.700 0.000 54.320 519.1000.000 0.000 -141.400 140.800 587.300 258.600 543.3000.000 0.000 -293.700 0.000 18.980 74.040 504.200

261.100 91.130 316.900 898.200 368.500 492.000 631.000108.500 102.200 2951.000 334.900 0.000 363.500 993.4000.000 0.000 0.000 0.000 0.000 0.283 0.0000.000 0.000 0.000 134.900 2475.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 335.700 0.000

106.700 0.000 0.000 0.000 0.000 161.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 570.6000.000 0.000 0.000 192.300 0.000 169.600 0.0000.000 0.000 0.000 0.000 0.000 0.000 616.6000.000 0.000 0.000 0.000 -42.710 136.900 5256.0000.000 0.000 0.000 0.000 0.000 329.100 0.0000.000 0.000 -257.200 0.000 0.000 0.000 180.2000.000 0.000 0.000 0.000 0.000 -42.310 0.0000.000 0.000 0.000 0.000 281.600 335.200 898.2000.000 -198.800 116.500 0.000 159.800 0.000 0.00049.700 0.000 -185.200 343.700 0.000 150.600 -97.7700.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 284.500 0.000 -22.100 0.000 -61.600 1179.000

961.800 1464.000 0.000 0.000 0.000 0.000 0.000-125.200 1604.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 -70.2500.000 0.000 0.000 0.000 0.000 119.200 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 221.400 0.000 0.000

Chloride Dichloride Other Chloride Nitro

21 22 23 24 25 26 27

35.930 53.760 24.900 104.300 11.440 661.500 543.000-36.870 58.550 -13.990 109.700 100.100 357.500 0.000-18.810 -144.400 -231.900 3.000 187.000 168.000 194.900-114.100 -111.000 -80.250 -141.300 -211.000 3629.000 4448.00075.620 65.280 -98.120 143.100 123.500 256.500 157.100-38.320 -102.500 -139.400 -44.760 -28.250 75.140 0.000325.400 370.400 353.700 497.500 133.900 220.600 399.5000.000 0.000 0.000 1827.000 6915.000 0.000 0.000

-191.700 -130.300 -354.600 -39.200 -119.800 137.500 548.500751.900 67.520 -483.700 0.000 0.000 0.000 0.000-34.740 108.900 -209.700 54.570 442.400 -81.130 0.0000.000 0.000 -126.200 179.700 24.280 0.000 0.000

301.100 137.800 -154.300 47.670 134.800 95.180 0.000-82.920 0.000 0.000 -99.810 30.050 0.000 0.0000.000 0.000 0.000 71.230 -18.930 0.000 0.0000.000 -73.850 -352.900 -262.000 -181.900 0.000 0.000

287.000 -111.000 0.000 882.000 617.500 0.000 -139.3000.000 -351.600 -114.700 -205.300 0.000 0.000 2845.0004.933 -152.700 -15.620 -54.860 -4.624 -0.515 0.00013.410 -44.700 39.630 183.400 -79.080 0.000 0.0000.000 108.300 249.600 62.420 153.000 32.730 86.200-84.530 0.000 0.000 56.330 223.100 108.900 0.000-157.100 0.000 0.000 -30.100 192.100 0.000 0.00011.800 17.970 51.900 0.000 -75.970 490.900 534.700-129.700 -8.309 -0.227 248.400 0.000 132.700 2213.000113.000 -9.639 0.000 -34.680 132.900 0.000 533.2001971.000 0.000 0.000 514.600 -123.100 -85.120 0.000-7309.000 0.000 -26.060 -60.710 0.000 277.800 0.000-27.940 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 48.480 -133.200 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 481.300 0.0000.000 -40.820 21.760 48.490 0.000 64.280 2448.000

-262.300 -174.500 0.000 77.550 -185.300 125.300 4288.0000.000 0.000 0.000 0.000 0.000 174.400 0.0000.000 -215.000 -343.600 -58.430 0.000 0.000 0.0000.000 0.000 0.000 -85.150 0.000 0.000 0.000

383.200 301.900 -149.800 -134.200 0.000 379.400 0.0000.000 0.000 0.000 -124.600 0.000 0.000 0.0000.000 0.000 0.000 -186.700 0.000 223.600 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.000

182.200 305.400 -193.000 335.700 956.100 0.000 0.000

0.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 70.810 0.000 0.000 0.0000.000 0.000 196.200 0.000 161.500 0.000 0.0000.000 0.000 0.000 0.000 0.000 844.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 -194.700 0.000 3.163 7.082 0.000 0.0000.000 0.000 -363.100 -11.300 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 -79.340 0.000 176.300 0.000

eThiol

alkyne

28 29 30 31 32 33 34

153.600 184.400 354.600 3025.000 335.800 479.500 298.90076.300 0.000 262.900 0.000 0.000 183.800 31.14052.070 -10.430 -64.690 210.700 113.300 261.300 0.000-9.451 393.600 48.490 4975.000 259.000 210.000 0.000488.900 147.500 -120.500 -318.900 313.500 202.100 727.800-31.090 17.500 0.000 119.200 212.100 106.300 0.000887.100 0.000 188.000 12.720 0.000 0.000 0.0008484.000 0.000 0.000 -687.100 0.000 0.000 -246.600216.100 -46.280 -163.700 71.460 53.590 245.200 0.0000.000 0.000 0.000 0.000 117.000 0.000 0.000

183.000 0.000 202.300 -101.700 148.300 18.880 0.0000.000 103.900 0.000 0.000 0.000 0.000 0.000

140.900 -8.538 170.100 -20.110 -149.500 -202.300 0.0000.000 -70.140 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.100 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 -60.780 0.000

230.900 0.460 0.000 177.500 0.000 -62.170 -203.0000.000 0.000 -208.900 0.000 228.400 -95.000 0.000

450.100 59.020 0.000 0.000 0.000 344.400 0.0000.000 0.000 0.000 0.000 177.600 315.900 0.000

116.600 0.000 -64.380 0.000 86.400 0.000 0.000132.200 0.000 546.700 0.000 247.800 146.600 0.0000.000 0.000 0.000 0.000 0.000 593.400 0.000

320.200 0.000 0.000 139.800 304.300 10.170 -27.7000.000 0.000 0.000 0.000 2990.000 -124.000 0.0000.000 0.000 0.000 0.000 292.700 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.000-27.450 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 85.700 0.000 535.800 0.000 -111.200 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.000

167.900 0.000 0.000 0.000 0.000 0.000 631.5000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 -71.000 0.000 -191.700 0.000 0.000 6.6990.000 0.000 0.000 0.000 0.000 0.000 0.000

885.500 0.000 -64.280 -264.300 288.100 627.700 0.000

0.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 -274.100 0.000 262.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 515.800 0.000 0.000 0.0000.000 6.971 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.000

itrile

Fluorides

35 36 37 38 39 40 41

526.500 689.000 -4.189 125.800 485.300 -2.859 387.100179.000 -52.870 -66.460 359.300 -70.450 449.400 48.330169.900 383.900 -259.100 389.300 245.600 22.670 103.5004284.000 -119.200 -282.500 101.400 5629.000 0.000 69.260-202.100 74.270 225.800 44.780 -143.900 0.000 190.300-399.300 -5.224 33.470 -48.250 -172.400 0.000 165.700-139.000 160.800 0.000 0.000 319.000 0.000 -197.5000.000 0.000 0.000 0.000 0.000 0.000 -494.200-44.580 0.000 -34.570 0.000 -61.700 0.000 -18.8000.000 -339.200 172.400 0.000 -268.800 0.000 -275.50052.080 -28.610 -275.200 0.000 85.330 0.000 560.2000.000 0.000 11.400 0.000 308.900 0.000 -122.300

128.800 0.000 240.200 -274.000 254.800 0.000 417.0000.000 0.000 0.000 0.000 -164.000 0.000 0.0000.000 0.000 0.000 570.900 0.000 0.000 -38.770

243.100 0.000 0.000 -196.300 22.050 0.000 0.0000.000 0.000 0.000 0.000 -334.400 0.000 -89.4200.000 0.000 160.700 -158.800 0.000 0.000 0.0000.000 81.570 -55.770 0.000 -151.500 0.000 120.300

-463.600 0.000 -11.160 0.000 -228.000 0.000 -337.0000.000 0.000 -168.200 0.000 0.000 0.000 63.670

215.000 0.000 -91.800 0.000 0.000 0.000 -96.870363.700 0.000 111.200 0.000 0.000 0.000 255.800337.700 369.500 1187.100 215.200 498.600 0.000 256.5000.000 0.000 0.000 0.000 0.000 0.000 -71.1800.000 0.000 10.760 0.000 -223.100 0.000 248.4000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 -47.370 0.000 0.000 0.000 469.80031.660 0.000 0.000 0.000 78.920 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 43.370

-417.200 0.000 0.000 0.000 302.200 0.000 347.8000.000 0.000 0.000 0.000 0.000 0.000 68.55032.900 0.000 0.000 0.000 0.000 0.000 195.1000.000 0.000 2073.000 0.000 -119.800 0.000 0.0000.000 0.000 0.000 0.000 -97.710 0.000 153.7000.000 0.000 -208.800 0.000 -8.804 0.000 423.4000.000 837.200 0.000 0.000 255.000 0.000 730.8000.000 0.000 0.000 0.000 0.000 -117.200 0.000

136.600 5.150 137.700 0.000 0.000 -5.579 72.3100.000 0.000 0.000 185.600 55.800 0.000 0.000-29.340 -53.910 -198.000 0.000 -28.650 0.000 0.000

0.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 -66.310 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 -32.170 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 101.2000.000 0.000 148.900 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.000

Silane Siloxane

Chlorofluorocarbons Amides

Sulfides

42 43 44 45 46 47 48

-450.400 252.700 220.300 -5.869 390.900 553.300 187.0000.000 0.000 86.460 0.000 200.200 268.100 -617.000

-432.300 238.900 30.040 -88.110 0.000 333.300 0.0000.000 0.000 46.380 0.000 0.000 421.900 0.000

-817.700 0.000 -504.200 72.960 -382.700 -248.300 0.0000.000 0.000 0.000 -52.100 0.000 0.000 37.630

-363.800 0.000 -452.200 0.000 835.600 139.600 0.0000.000 0.000 -659.000 0.000 0.000 0.000 0.000

-588.900 0.000 0.000 0.000 0.000 37.540 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 151.800 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.000

1338.000 0.000 0.000 0.000 0.000 0.000 0.000-664.400 275.900 0.000 0.000 0.000 0.000 0.000448.100 -1327.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 16.230 0.0000.000 0.000 0.000 0.000 -322.300 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 361.100 0.0000.000 0.000 -35.680 0.000 0.000 0.000 565.9000.000 233.100 0.000 0.000 0.000 423.100 63.9500.000 0.000 -209.700 0.000 0.000 434.100 0.0000.000 0.000 0.000 -218.900 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 1004.000 0.000 0.000 0.000 -18.2700.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 -262.000 0.000 0.000 -353.500 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 26.350 0.000 0.000 0.000 2429.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 111.800 0.000 122.400 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.000

0.000 -2166.000 0.000 0.000 0.000 0.000 0.000745.300 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.0000.000 0.000 0.000 0.000 0.000 0.000 0.000

Sulfides

216.100 92.99062.560 0.000-59.580 -39.160-203.600 184.900104.700 57.650-59.400 -46.010407.900 0.0000.000 1005.0000.000 -162.6000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 -136.6000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 108.5000.000 0.0000.000 -4.5650.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.000

0.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.0000.000 0.000

amk 1 2m/k 1 2 3 0 0 0 0 0 0

1 1 0 0 0 0 0 0 0 0 02 0 0 0 0 0 0 0 0 03 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

30 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

5 14 156.4 156.4 156.4 0 0 0 0 0 06 0 0 0 0 0 0 0 0 0 07 0 0 0 0 0 0 0 0 0 08 0 0 0 0 0 0 0 0 0 0

90 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

10 0 0 0 0 0 0 0 0 0 0

110 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

12 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

140 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

150 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

160 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

17 0 0 0 0 0 0 0 0 0 0

180 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

190 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

200 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

210 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

220 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

230 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

24 0 0 0 0 0 0 0 0 0 025 0 0 0 0 0 0 0 0 0 0

260 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

27 0 0 0 0 0 0 0 0 0 028 0 0 0 0 0 0 0 0 0 0

290 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

30 0 0 0 0 0 0 0 0 0 031 0 0 0 0 0 0 0 0 0 032 0 0 0 0 0 0 0 0 0 033 0 0 0 0 0 0 0 0 0 0

340 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

35 0 0 0 0 0 0 0 0 0 036 0 0 0 0 0 0 0 0 0 037 0 0 0 0 0 0 0 0 0 038 0 0 0 0 0 0 0 0 0 0

390 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

400 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

41 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

430 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

44 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

470 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

480 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

49 0 0 0 0 0 0 0 0 0 0

500 0 0 0 0 0 0 0 0 0

50 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0

3 4 5 6 7 8 9 10 110 0 0 0 0 14 0 0 0 0 0 0 00 0 0 0 0 986.5 0 0 0 0 0 0 00 0 0 0 0 986.5 0 0 0 0 0 0 00 0 0 0 0 986.5 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0

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