Stahl Innovation In WB Wood Coating Applications 斯塔尔在⽔水性⽊木器中的创新应⽤用
斯塔尔精细涂料(苏州)有限公司 销售经理 蔡佳斌 2016年6月 上海
■ About Stahl.
有关斯塔尔。 ■ Application of OH-functional acrylic in 2K WB wood coating.
带羟基的自交联丙烯酸分散体在双组分水性木器上由低到面的应用。 ■ Transparent, mulityphase acrylic for wood coating.
高透,多相,自交联丙烯酸分散体在水性木器上从户内到户外的应用。 ■ Eco-crosslinker in WB wood coating.
环保型交联剂碳化二亚胺在水性木器中的应用。
Content 主要内容
斯塔尔是皮革化工领域全球领先的供应商。拥有超过30年的水性树脂的研发和生产经验。
About Stahl 有关斯塔尔
Worldwide coverage 全球化运营 ■ One headquarters ■ 9 R&D centers ■ 11 Manufacturing sites ■ 38 Application labs in 23 countries ■ 1800+ Employees
Stahl Business Services
业务支持
Stahl Campus®
Automotive Leather
Chemicals
PielColor Stahl Polymers
原材料树脂
Performance Coatings
高性能涂料
Central General Services
Stahl Management Team
斯塔尔管理层
Leather Finish
皮革涂饰
Wet-End 皮革鞣制
Stahl Business Units 斯塔尔的业务组成
▪ Application of OH-functional acrylic in 2K WB wood coating. 带羟基的自交联丙烯酸分散体在双组分水性木器上由低到面的应用。
▪ Transparent, mulityphase acrylic for wood coating. 高透、多相、自交联丙烯酸分散体���在水性木器上从户内到户外的应用。
▪ Eco-crosslinker in WB wood coating. 环保型交联剂碳化二亚胺在水性木器中的应用。
Contents 内容
▪ OH-functional self cross linker acrylic dispersion applied from primer to topcoat in W/B wood coatings. ——带羟基的自交联水性丙烯酸分散体在双组分水性木器上由低到面的应用。���
Picassian® AC-192
Picassian® AC-192 - Double cross linking 双重交联体系
1st C自交联
2nd cross linking with isocyanates 与固化剂交联反应
OH- functional,self-crosslinking two phase acrylic dispersion for high performance furniture coatings. 用于高性能双组分水性木器漆体系的自���交联丙烯酸分散体。 Physical product properties 基本参数:
▪ Solid content 固含量: 40 % ▪ Appearance 外观: translucent White 白色透明液体 ▪ pH-value PH值: 7.0 ▪ Viscosity 粘度: 50 - 300mPas ▪ MFFT 最低成膜温度: 39℃ ▪ Tg 玻璃化温度: 58 ℃ ▪ OH value 羟值: 60 / mgKOH/g, 1.82/%
Picassian® AC-192
Key benefits 主要特点: ▪ Very good chemical resistance 出色的耐化学品性能 ▪ Good scratch resistance and early hardness 优异的耐刮和早期硬度 ▪ Excellent transparency 优异的清透性 ▪ Easy and quick to sand(1k&2k) 极其出色的打磨性(1k&2K) ▪ Excellent anti-setting and widely operation able 很好的防尘性和施工宽泛性能 Applications filed应用领域:
▪ 1K and 2K furniture coatings 单组分和双组分水性木器漆 ▪ Wood floor primers 地板漆 ▪ Sanding and sanding sealers 封闭和打磨底漆 ▪ General wood coatings 常规的木器涂装
Picassian® AC-192
Picassian® AC-192 - MFFT value 成膜温度
4%
39
12 14 13 14
29 27
0
5
10
15
20
25
30
35
40
45
control DPnB DPnP BDG BG EDG DPM
/ ℃
MFFT value with different coalescent 在不同成膜助剂下的最低成膜温度
Picassian® AC-192 - Choice of curing agents 固化剂的选择
NCO/OH=1.2
- 10,00% 0
1
2
3
4
5
6
XD-803 Bayhydur 304 Bayhydur 305 Bayhydur 2655 Bayhydur 2487/1
Gloss/60º 光泽 Transparent 透明性
- 30,00%
- 50,00%
- 70,00%
- 90,00%
Picassian® AC-192 - Choice of curing agents 固化剂的选择
NCO/OH=1.2
0
1
2
3
4
5
6
XD-803 Bayhydur 304 Bayhydur 305 Bayhydur 2655 Bayhydur 2487/1
Coffee resistance, 1h 耐咖啡, 1h Vinegar resistance, 1h 耐醋, 1h Tea resistance, 1h 耐茶, 1h
Picassian® AC-192 - Choice of curing agents 固化剂的选择
NCO/OH=1.2
0
20
40
60
80
100
120
140
160
Initial 16h in R.T 2d in R.T 5d in R.T Final
XD803 Bayhydur 305 Bayhydur 2655 Bayhydur 2487/1
Hardness/s, on black glass摆杆硬度
Picassian® AC-192 - Sealing ability in primer applications 封闭性能
AC-192+Bayhydur 2655
AC-122
Competitors+Bayhydur2655
Control
AC-122
Control
Competitors+ Bayhydur2655
AC-192+Bayhydur 2655
Substrate: MDF Substrate: chicken wood
Picassian® AC-192 - Sanding ability in primer applications 打磨性
Dry condition: R.T×12h
AC-122
AC-192, 1K
competitors+Bayhydur2655
AC-192+Bayhydur 2655
Worst
Best
Picassian® AC-192 - Excellent anti-setting ability 出色的防尘效果
Vis=15s/2# cup, 30days in R.T
Matting agents 哑粉
Picassian® AC-192 - Semi gloss lacquer/chemical resistance
Raw material Amount Product
Picassian®AC-192 80.0 OH-acrylics
Tego Foamex810 0.1 Defoamer
Tego Airex902 0.2 Defoamer
BYK191 0.1 Dispering agent
Syliod 7000 1.5 Matting agent
DPnB 2.0 Coalescent
DPM 4.0 Coalescent
Water 10.4 Water
AMP95 0.1 PH adjustor
D-816 1.0 Wax paste
Rheolate 288 0.2 Rheological agents
BYK346 0.2 Wetting agents
BYK333 0.2 Levelling agents
NCO:OH=1.2,means 100.0 parts of the a. m. formulation require: 15.2 parts Bayhydur 305 (70.0% in PMA) , 11.6 parts Bayhydur 2655(70.0% in PMA), 12.0 parts Bayhydur 2487/1(70.0% in PMA).
Picassian® AC-192 - Semi gloss lacquer/chemical resistance
Test chemicals Test duration Test results/2k Test results/1k
50%Alcohol ⼄乙醇 1h 5 4
Acetone 丙酮 10s 5 4.5
Ammonia 氨水 2mins 5 5
NaHCO3 苏打水 1h 5 4.5
Water 水 24h 5 4
Ink 墨水 24h 5 5
Hot Coffe 咖啡 1h 5 5
Hand cream 24h 5 5
Vinegar 醋 1h 5 5
Tea茶 1h 5 5
Remark: cross kinged with Bayhydur 305 (70.0% in PMA)
Picassian® AC-192 - Semi gloss lacquer/chemical resistance. Pot-life test 活化期测试
Physics performance 物理性能: Gloss光泽 ▪ 60⁰: 45% with Bayhydur 305 ▪ 38% with Bayhydur 2655 ▪ 50% with Bayhydur 2487/1
Hardness 硬度: ▪ ≈⋲F
0
5
10
15
20
25
30
35
40
45
50
0,5h 1h 2h 3h 4h
Vis/2#cup Gloss/60⁰
/ ℃
- 60%
- 20%
- 25%
- 30%
- 35%
- 40%
- 45%
- 50%
- 55%
44% 44% 44% 45% 45%
Picassian® AC-192 - Pigment applications
Pos. Raw material Amount Product
1 Picassian®AC-192 60.0 Hydroxyl acrylics
2 Tego Foamex 810 0.1 Defoamer
3 Tego Airex 902 0.2 Defoamer
4 DPnB 2.0 Coalescent
5 DPM 4.0 Coalescent
6 Water 10.8
7 Rheolate 288 0.2 Rheological agents
8 R706 slurry* 22.0 TiO2 slurry
9 BYK346 0.2 Wetting agents
10 BYK333 0.2 Levelling agents
Total 100.00
Tio2 paste*
1 Water 12.9 Water
2 Tego disper 735w 7.5 Dispersing agent
3 Tego Foamex 810 0.20 Deformer
4 R706 75.0 Tio2
5 water 4.2
6 BYK 420 0.2 Anti-setting agent
Total 100
Picassian® AC-192 - Pigment applications
Test chemicals Test duration Test results
50%Alcohol 1h 5
Acetone (10") 10s 5
Ammonia (2') 2mins 5
Alkali(NaHCO3) 1h 5
Water (24h) 24h 5
Ink 24h 5
Hot Coffe (1h) 1h 4.5
Hand cream 24h 5
vinegar 1h 4.5
Tea 1h 5
Remark: cross kinged with Bayhydur 2655(70.0% in PMA), NCO:OH=1.2,means 100.0 parts of the a. m. formulation require 8.7 parts Bayhydur 2655 (70.0% in PMA)
Picassian® AC-192 - Pigment applications. Pot-life test 活化期测试
Physics performance 物理性能: Gloss光泽 ▪ 60⁰: 80% with Bayhydur 305 ▪ 78% with Bayhydur 2655 ▪ 74% with Bayhydur 2487/1
Hardness 硬度: ▪ ≈⋲F
Remark: premix Bayhydur 305 (70.0% in PMA) with water at ratio of 1:1
0
200
400
600
800
1000
1200
1400
0,5h 1h 2h 3h 4h
Bayhydur 305 Bayhydur 2655 Bayhydur 2487/1
▪ Double cross linking, self cross linked and cross link isocyanate. 双重交联体系, 自交联和与异氰酸酯固化剂交联
▪ Superior sanding ability , efficiently matching with factory application. 出色的打磨性。适应于工厂快速流水化作业
▪ Very good stain and chemical resistance. 很好的耐沾污和耐化学品性能 ▪ Good scratch and fast hardness increasing speed. 硬度上升速度块 ▪ Excellent anti-setting ability. 对哑粉和粉料包裹好, 防沉性好, 白漆光泽高 ▪ Good blocking resistance. 好的抗粘连性 ▪ excellent transparency and gloss 清透性好, 光泽高 ▪ Very easy to formulate, from high gloss to the matted gloss, from 1k to 2k.
易于做配方, 好消光, 适合单双组分体系
Picassian® AC-192 - Features overview 总结
▪ Application of OH-functional acrylic in 2K WB wood coating. 带羟基的自交联丙烯酸分散体在双组分水性木器上由低到面的应用。
▪ Transparent, mulityphase acrylic for wood coating. 高透、多相、自交联丙烯酸分散体���在水性木器上从户内到户外的应用。
▪ Eco-crosslinker in WB wood coating. 环保型交联剂碳化二亚胺在水性木器中的应用。
Contents 内容
▪ Translucent self-crosslinking acrylic applied from indoor to outdoor in W/B wood coatings. ——清透型自交联多相丙烯酸分散体在水性木器从户内到户外的应用。���
Picassian® AC-122, AC-169, AC-290
Picassian® AC-122, AC-169, AC-290 - Translucent Family 清透型丙烯酸系列
Picassian® AC-194 Solid content: 45% MFFT: 43 ℃ Hardness (König, seconds):110
Picassian® AC-122 Picassian® AC-290
Picassian® AC-169
Solid content: 44% MFFT: ˂10 ℃ Hardness (König, seconds): 48
Solid content: 40% MFFT: 20 ℃ Hardness (König, seconds): 73
Solid content: 40% MFFT: 35 ℃ Hardness (König, seconds): 110
Improvement of SC and anti-scratch 固含量更高, 耐刮更好
Improvement of early anti-blocking 更好的早期抗粘连
Flexible for outdoor 柔韧性更好,用于户外
Picassian® AC-122, AC-169, AC-290 – Multiple phase 多相结构
Benefit of multiple phase: ▪ Low MFFT combined with
high hardness 低的成膜温度兼顾高的漆膜硬度
▪ Less VOC demand in formulations 需要更少的成膜助剂少
▪ Fast drying 快干
▪ Very high blocking resistance 优异的抗粘连性
▪ Higher level of elasticity 更好的韧性
▪ Very fast sandability 非常快的打磨性
AFM characterization
Multiple phase 多相结构
Conventional single phase 传统单相结构
Picassian® AC-122, AC-169, AC-290 - Transparency 清透性
Water AC-122
AC-169 AC-290
Conventional Conventional
Picassian® AC-122, AC-169, AC-290 – “Anfeuerung” 暖木效果
Conventional Acrylics AC-122 AC-169 AC-290
Translucent, self crosslinking,multiple-phase dispersion for high performance indoor furniture coatings. 应用于室内高性能水性木器漆的清透型, 自交联, 多相的丙烯酸分散体。 Key benefits 优点:
▪ Superior transparency and leveling ability 极其出色的清透性和流平性
▪ Good blocking and chemical resistance 优异的耐化学品性和早期抗粘连
▪ Very good scratch resistance 耐刮性好
▪ Excellent clarity and gloss 漆膜优异的光泽和细腻感
▪ Easy and quick to sand 好的早期打磨性
Picassian® AC-122
Application filed 应用领域: ▪ General transparency wood coatings 常规的清漆 ▪ Sanding primer 打磨底漆 ▪ Brush able paints 用于涂刷 ▪ Pigment lacquers 实色漆
Picassian® AC-122
Picassian® AC-122 - Easy and quick sanding ability 优异的快速打磨性
Dry condition: 27~28 ℃, RH=85%
Worst
Best
Conventional
AC-122
Conventional
AC-122
4 hours 16 hours
Picassian® AC-122 - 30% gloss lacquer 三分光清漆参考配方及耐化学性
Pos. Raw material Amount Product
1 Picassian®AC-122 75.00 Acrylic dispersion
2 Tego Foamex825 0.60 Deformer
3 Tego Airex902 0.20 Deformer
4 BYK191 0.20 Dispersing agents
5 Syliod 7000 1.40 Matting agents
6 DPnB 2.00 Coalescent
7 DPM 5.00 Coalescent
8 Water 15.2
9 AMP95 0.20 PH adjustor
10 Rheolate 288 0.30 Rheological agents
11 Rheolate 299 0.10 Rheological agents
12 D-816 0.50 Wax dispersion
13 Tego 410 0.20 Levelling agents
14 BYK 346 0.20 Wetting agents
Total 100.00
Picassian® AC-122 - 30% gloss lacquer 三分光清漆参考配方及耐化学性
Test chemicals Test duration 测试时间 Test results 测试结果
50%Alcohol 醇 1h 4.5
Acetone 丙酮 10s 5
Ammonia 氨水 2mins 4.5
Alkali(NaHCO3) 苏打水 1h 4.5
Water 水 24h 5
Ink 墨水 24h 5
Hot Coffe 咖啡 1h 5
Translucent, self crosslinking,multiple-phase emulsion for high performance indoor and semi outdoor furniture coatings. 应用于户内和半户外的清透型, 自交联, 多相的丙烯酸分散体。 Key benefits 主要特点:
▪ Good chemical resistance 很好的 耐化学品性
▪ Outstanding early blocking resistance 极其出色的早期抗粘连
▪ Excellent clarity and gloss 透明性好光泽高
▪ Superior brush able and feeling 极佳的涂刷体验
▪ Flexible and good anti scratch ability 柔韧性好,耐刮
▪ Low VOC demand for filming 很少的成膜助剂
Picassian® AC-169
Application filed 应用领域: ▪ General transparency wood coatings
常规的清漆体系 ▪ Pigment furniture coatings
实色漆 ▪ Brush able paints or low VOC DIY markets
涂刷或VOC要求很高的DIY市场 ▪ Semi outdoor applications
半户外应用 ▪ Industrial furniture coatings with fast line speed
and high demand of early blocking resistance 对叠压要求很高的工厂流水线快速涂装
Picassian® AC-169
Picassian® AC-169 - Low coalescent demand and superior early blocking ability. 需要较低的成膜助剂和出色的早期抗粘连
▪ Drying condition干燥时间: R.T × 4h ▪ Test duration测试时间: 16h (after night) ▪ DFT = 45u ▪ Coalescent: 0.5% DPnB + 3.5% DPM
0
1
2
3
4
5
6
AC-194 glossy lacquer AC-122 glossy lacquer AC-169 glossy lacquer Competiors
500kg/ m2 800kg/ m2 1400kg/ m2
AC-169 亮光清漆
Picassian® AC-169 - Low coalescent demand and superior early blocking ability 需要较低的成膜助剂和出色的早期抗粘连
0
5
10
15
20
25
Control DPnB DPnP DPM BDG EDG BG
4% 2% 1,50%
< 5 ℃
Picassian® AC-169 - Superior brush able and feeling 优异的涂刷体验
AC-169 AC-169
Conventional Conventional
Picassian® AC-169 - Glossy lacquer
Pos. Raw material Amount Product
1 Picassian®AC-169 80.00 Acrylic dispersion
2 Tego Foamex 825 0.60 Deformer
3 Tego Airex902 0.20 Deformer
4 DPnB 1.50 Coalescent
5 water 16.40
6 AMP95 0.10 PH adjustor
7 Rheolate 288 0.40 Rheological agents
8 Rheolate 299 0.10 Rheological agents
10 BYK346 0.50 Wetting agents
11 BYK333 0.20 Levelling agents
Total 100.00
Test chemicals Test duration 测试时间
Test results 测试结果
50%Alcohol 醇 1h 5
Acetone 丙酮 10s 5
Ammonia 氨水 2mins 5
Alkali(NaHCO3) 苏打水 1h 5
Water 水 24h 5
Ink 墨水 24h 5
Hot Coffe 咖啡 1h 5
Hand cream 护手霜 24h 5
Vinegar 醋 1h 5
Tea 茶 1h 5
Translucent, self crosslinking, multiple-phase emulsion for high performance outdoor coatings. 应用于户内和白户外的清透清透型, 自交联, 多相的丙烯酸分散体。 Key benefits 主要特点: ▪ Good transparency and flexibility
很好的清透性和柔韧性 ▪ Superior early water resistance
出色的早期耐水性 ▪ Excellent weathering resistance
优异的耐候性能 ▪ Good blocking resistance, Low MFFT
很好的初期抗粘连和抗叠压 ▪ Good adhesion to various kinds of substrate
附着于各种基材
Picassian® AC-290
Application filed 应用领域: ▪ Universal transparent outdoor wood coating ▪ Decking systems 户外木地板 ▪ Joinery systems 户外家具 ▪ Pigment or clear brush able paints
户外刷涂色漆
Picassian® AC-290
Picassian® AC-290 - Weather resistance and durability 耐候性
Picassian® AC-290 Competitor
▪ Test Method: ISO 1419 (Method C) ▪ Preparation/application: apply 2 x 150 dµ (by brush) over wood panel, dry @RT for 48h ▪ Operative conditions: 95% RH, 70ºC ▪ Evaluation: 1 week = 1 year outdoor exposure approx.
▪ Application of OH-functional acrylic in 2K WB wood coating. 带羟基的自交联丙烯酸分散体在双组分水性木器上由低到面的应用。
▪ Transparent, mulityphase acrylic for wood coating. 高透、多相、自交联丙烯酸分散体���在水性木器上从户内到户外的应用。
▪ Eco-crosslinker in WB wood coating. 环保型交联剂碳化二亚胺在水性木器中的应用。
Contents 内容
▪ Environmentally friendly multifunctional polycarbodiimide cross-linker for W/B wood applications. ——环保型交联剂碳化二亚胺在水性木器体系中的应用。���
Picassian® XL-702, XL-732
React mechanism of Polycarbodiimides 聚碳化二亚胺的交联反应机理
Polycarbodiimides for W/B wood applications. XL702 & XL 732. ⽤用于⽔水性⽊木器漆体系的聚碳化⼆二亚胺 XL702,XL 732
Picassian® XL-702 Picassian® XL-732 Picassian® XL-701
Picassian® XL-725
Yellow clear liquid, sc= 100% 黄色透明液体, 100% 固含量
Yellow translucent water soluble liquid, sc= 40%
黄色透明水溶型, 40% 固含量
White emulsion, sc= 40% 白色乳液, 40% 固含量
Solution in MPA, sc= 50% 白色乳液, 40% 固含量
Polycarbodiimides of improvement in W/B wood coating 碳化二亚胺在水性木器中对耐性的提高
Dosage of polycarbodiimides= 2% 碳化二亚胺添加量= 2%
0
1
2
3
4
5
6
Control XL702, Initial XL702, 15d XL732, Initial XL732, 15d
Water, 24h 耐水, 24h 50% Alcohol, 1h 50%酒精, 24h Wet cup, 40min 耐湿热杯, 40mins
Stahl products in W/B wood applications 用于水性木器的斯塔尔产品⼀一览
Coating process 涂装工序
Products 推荐产品
Benefits 特点
Seal primer 封闭底漆
AC-192 (2k) 2k systems for superior film densification. 双组分, 比单组分更好的漆膜致密 性。
AC-280 Densified and hydrophobic film. 漆膜致密和疏水性。
AC-146 Cationic. 阳离子性型。
Filler 腻子 AC-126, AC-280 Excellent containment to pigment and filler. 对 颜填料很好的包裹性能,适合高PVC。
Wiping stains 擦色 AC-222 Alkali soluble acrylic, excellent permeability. 碱溶性丙烯酸, 很好的渗透性
Sanding primer 打磨底漆
AC-122 Drying fast for sanding, superior transparency ability and leveling. 快干易打磨,清透,流平好
AC-192(1k &2k) Drying fast, good sanding ability both 1k and 2k. 快干好打磨(1k&2k)
White primer ⽩白底 AC-126,AC-280 Superior compatibility to the high PVC. 对⾼高PVC很好的包裹性能。
Shading stains 修色 PU-488, AC-122 Good compatibility with alcohol与⼄乙醇相容性好。
Topcoat 面漆
AC-122 Excellent transparency, levelling, chemical resistance, easy to formulate. 出色的清透和流平性, 耐性好, 好消光。
AC-169 Superior early blocking, levelling, brushing feeling and chemical resistance, suitable for low voc requirement. 出色的早期抗粘连和流平性, 好涂刷, 耐性好, 低VOC。
PU-488 Good abrasion resistance and chemical resistance. 耐刮性好,耐性出色。
PU-476 Alkyd modified aliphatic urethane, good levelling, superior gloss, fullness and final hardness. 醇酸改性聚氨酯, ���流平好, 光泽和丰满度高, 后期硬度高。
AC-192(1k&2k) Fast to dry and final hardness because of double crosslinking, long pot-life and good compatibility to various kinds of curing agents. 双重交联, 快干, 硬度上升块, 与各种固化剂相容性好, 活化期长, 好施工。
Cross linker 交联剂
XL- 706 Aziridine. 氮丙啶。
XL-702, XL-732 Polycarbodiimide. 聚碳化二亚胺。
We imagine a future where we create endless opportunities through partnership
If it can be imagined, it can be created
谢谢大家!
Thank you
Top Related