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Hazard Communication& Chemical Safety
Based on OSHAStandard
1910.1200
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Hazard Communication
OSHA Hazard Communication Standard 29CFR 1910.1200 !Ri"ht to #no$% $ent intoeect in 'o(em)er 19*+. Often referred to a,
!Hazcom.% OSHA ha, re(i,ed the Hazard Communication
Standard to )e more in line $ith "lo)al,y,tem,. -he ne$ lo)ally Harmonized
Sy,tem /HS ,tandardize, ,afety data ,heet,and u,e, icto"ram, that can )e under,toodre"ardle,, of a er,on, nati(e lan"ua"e.
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Hazard Communication
-he uro,e of Hazcom i, to en,ure thatinformation concernin" hazard, a,,ociated$ith the $or3lace i, tran,mitted to
emloyee,.
4ou5 a, an emloyee5 ha(e a Ri"ht to #no$a)out the hazard, in your $or3 areaand
the otential eect, of the,e hazard, uonyour health and ,afety.
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Hazard Communication
6t may ,eem ea,y enou"h to e7ect chemical,and hy,ical hazard, to )e in la),5 ,ho,5 andmaintenance area,5 ho$e(er hazard, can al,o)e found in o8ce,5 cla,,room,5 and other $or3area,.
-he,e may include
Coier:rinter toner, ;ry era,e cleaner,
Cleanin" chemical, ,ray,
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=e u,e many chemical, Hazardou, material, /chemical roduct, and
hy,ical a"ent, /radiation5 la,er,5 (i)ration5etc. can )e found any$here.6t ha, )eene,timated that o(er a half million chemical
roduct, are u,ed )y )u,ine,, and indu,trye(ery year. Some of the,e hazard, o,e littledan"er to you5 $hile other, may )e deadly.
>odern manufacturin" $ould not )e o,,i)le$ithout chemical, and roce,,e,. Ho$e(er5 li3emachinery or electrical e?uiment5 you mu,t3no$ ho$ to u,e chemical, ,afely.
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=e u,e many chemical,
-he @r,t ,te in u,in" chemical, androce,,e, ,afely i, to reco"nize tho,e
material, and roce,,e, that may )ehazardou, to your health or hy,ical,afety.
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=e u,e many chemical,
=e $ant you to 3no$ ho$ to u,e them ,afely
4ou $ill learn a)out
The Hazards of Chemicals Our Written Proram
Ho! Chemicals are "a#eled Safe $se of Chemicals
%aterial Safet& 'ata Sheets Basic Procedures for S(ills
Who &ou can as) for more information
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Hazard, of Chemical,
-here are 2 )a,ic tye, of chemicalhazard,
hy,ical Hazard, Health Hazard,
-he @r,t rule of Chemical ,afety i,
B#no$ $hat you are $or3in" $ithand ho$ to rotect your,elf andother,!
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hy,ical Hazard,
Chemical, are cla,,i@ed a, ha(in"Ph&sical Hazardsif they are
*+(losi,e
Com(ressed -as
Com#usti#le "iuids
/lamma#le
$nsta#le
Water eacti,e
O+idizers
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hy,ical Hazard,
Some chemicals ma& #e safe #&
themsel,es #ut #ecomedanerous !hen in contact!ith other su#stances.
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Chemicals !ith Ph&sicalHazards
$sed onl& #& trainedem(lo&ees
Stored in a safe manner3e,er mi+ed !ith other
chemicals unless #& an
a((ro,ed (rocedure
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Health Hazard,
Chemical, are cla,,i@ed a, )ein" ahealth hazard if they
Can cau,e cancer Are oi,onou, /to7ic Cau,e harm to your ,3in5 internal
or"an,5 or ner(ou, ,y,tem
Are corro,i(e ,uch a, acid, Cau,e aller"ic reaction, after reeated
e7o,ure
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Chemicals can enter the #od&
throuh4&our lunsif you )reath
fume,5 mi,t, or du,t
&our s)inif li?uid or du,t
touche, or ,ill, on youor ,la,he, in your eye,
&our mouthif you eatafter handlin" chemical,
accidental s!allo!inof a chemical
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Health Dect,
Some chemicalsa5ect s(eci6c
orans such as&our )idne&sli,er
re(roducti,e orner,ous s&stem.
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Our Written HazardCommunication Proram
(ro,ides=ritten information on hazard,
Ei,t, Chemical, $e u,e and their
hazard,Sy,tem for en,urin" chemical, are
la)eled
>ean, to en,ure $e ha(e an>aterial Safety ;ata Sheet />S;Sfor each chemical
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Our =ritten Hazard
Communication ro"ramEi,t, $ho i, re,on,i)le for the
ro"ram
ro(ide, chemical ,eci@c ,afetytrainin" method,
-ell, you $here to @nd chemical
,afety information7ou can see a the !ritten (roram
#& as)in &our su(er,isor
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Our =ritten Hazard
Communication ro"ramEi,t, $ho i, re,on,i)le for the
ro"ram
ro(ide, chemical ,eci@c ,afetytrainin" method,
-ell, you $here to @nd chemical
,afety information7ou can see a the !ritten (roram
#& as)in &our su(er,isor
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Ea)elin" of Chemical,Chemical Ea)el, ro(ide
information on 6dentity5Hazard, and Safe ,e
All chemical container, arela)eled)y themanufacturer
-he comany may laceadditional la)el,on thecontainer,
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Ea)elin" of Chemical, OSHA has u(dated the reuirements for la#elin of
hazardous chemicals under its Hazcom Standard8HCS.
As of :une 1 201; all la#els !ill #e reuired to ha,e4
G Pictorams
G Sinal !ords
G Hazard and (recautionar& statements
G Product identi6erG Su((lier identi6cation
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# li f Ch i l
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"a#elin of Chemicals
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Ea)elin" of Chemical,
6f chemical, are laced in anothercontainer5 thi, ne$ container mu,t
ha(e a a la)el laced on it.
All container, mu,t )e roerly
la)eled
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niform Ea)elin"
Sy,temOur Comany !niform Ea)el,% are
u,ed to en,ure $e ha(e one
la)elin" ,y,tem.
-he,e may )e laced on container,
$hen chemical, are deli(ered to u,or chemical, are tran,ferred toother container,
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2 a,ic !niform Ea)el,%
H%aterial 6denti@cationSy,tem
3/PA 'ational Fire rotection A,,ociation
Both t&(es must identif& the
chemical name and hazards
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niform Ea)el,
icture, may )e u,ed toidentify hazard, and
re?uired rotection
-hi, 6nformation may
al,o )e on the>anufacturer, la)el
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H>6S & 'FA la)el, are (ery
,imilaroth u,e colored )o7e, to identify
,eci@c hazard,
'um)er, or code, in the )o7e, tellyou the hazard (alue
hiher num#ers = hiher hazard
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'FA & H>6S Ea)el Color,
ed Fire Hazard
Blue Health Hazard
7ello!7ello! Reacti(ity Hazard e7lo,i(e5 un,ta)le
WhiteWhite Secial Hazard, corro,i(e5
radioacti(e5 $ater reacti(e5 acid
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H%
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'FA Ea)el..The (ur(ose of the 3/PA>0? la#elin s&stem is to(ro,ide a !a& of uic)l&identif&in the ,arious 6re
related hazardousassociated !ith a(articular material. The3/PA >0? @diamond@ iscommonl& found on #ul)storae containers #ut isalso !idel& used onchemical containers and%S'S sheets.
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'FA Flamma)ility Code,
?%aterials that !ill ra(idl& orcom(letel& ,a(orize at atmos(heric(ressure and normal am#ient
tem(erature or that are readil&dis(ersed in air and that !ill #urnreadil&. "iuids !ith a ash(oint#elo! >/ and a #oilin (oint
#elo! 100/.
http://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/maphttp://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/maphttp://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/map7/23/2019 HAZCOM & CHEMSAF
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'FA Flamma)ility Code,
"iuids and solid that can #einited under almost all am#ient
tem(erature conditions. "iuids!ith a ash(oint #elo! >/ and a#oilin (oint a#o,e 100/ or liuids!ith a ash(oint a#o,e >/ #ut
not e+ceedin 100/ and a #oilin(oint #elo! 100/.
http://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/maphttp://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/maphttp://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/map7/23/2019 HAZCOM & CHEMSAF
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'FA Flamma)ility Code,
2 %aterials that must #e moderatel&heated or e+(osed to relati,el&
hih am#ient tem(eratures #eforeinition can occur. "iuids !ithash(oint a#o,e 100/#ut note+ceedin 200/.
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'FA Flamma)ility Code,
1>aterial, that mu,t )e reheated)efore i"nition can occur. Ei?uid, that
ha(e a Ia,hoint a)o(e 200JF.
0 >aterial, that $ill not )urn.
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'FA Health Hazard Code,
?%aterials that on ,er&short e+(osure couldcause death or maDorresidual inDur&.
%aterials that on short
e+(osure could causeserious tem(orar& orresidual inDur&.
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'FA Health Hazard Code,
2%aterials that onintense or continued
#ut not chronice+(osure could causeinca(acitation or(ossi#le residual inDur&.
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'FA Health Hazard Code,
1>aterial, that on e7o,ure$ould cau,e irritation )ut onlyminor re,idual inKury.
0>aterial, that on e7o,ureunder @re condition, $ould
oer no hazard )eyond that ofordinary com)u,ti)lematerial.
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'FA Reacti(ity Hazard
Code,?%aterials that in themsel,es are
readil& ca(a#le of detonation or of
e+(losi,e decom(osition orreaction at normal tem(eraturesand (ressures.
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'FA Reacti(ity Hazard
Code, %aterials that in themsel,es
are ca(a#le of detonation or
e+(losi,e decom(osition orreaction #ut reuire astron initiatin source or!hich must #e heated under
con6nement #eforeinitiation or !hich reacte+(losi,el& !ith !ater.
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'FA Reacti(ity Hazard
Code,2%aterials that readil& undero
,iolent chemical chane at ele,ated
tem(eratures and (ressures or!hich react ,iolentl& !ith !ater or!hich ma& form e+(losi,e mi+tures!ith !ater.
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'FA Reacti(ity Code,
1%aterials that in themsel,es arenormall& sta#le #ut !hich can
#ecome unsta#le at ele,atedtem(eratures and (ressures.
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'FA Reacti(ity Code,
0%aterials that in themsel,es arenormall& sta#le e,en under 6re
e+(osure conditions and !hich arenot reacti,e !ith !ater.
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'FA Secial Hazard
Code,AC6; L Acid roduct,AE# L Al3ali or a,e,
COR L Corro,i(e roduct,
OM L O7idizer
= LReact, $ith $ater
Radioacti(e
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=hat do 6 do
if there i, no la)el or 6 cannot readthe la)elN
STOP do not u,e the chemicalT*""your ,uer(i,or
*A'the >S;S and ha(e another
la)el ut on the container
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Chemical, can )e ,afely u,edif
you 3no$ the hazard, and ho$ torotect your,elf
they are u,ed only for aro(eduro,e,
they are ,tored roerly
you u,e the correct er,onalrotecti(e e?uiment
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Chemical, can )e ,afely u,edif
you do not eat in area, $herechemical, are u,ed
you $a,h immediately if you comein contact $ith chemical,
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Chemical ;i,o,al
Dach chemical and container mu,t)e di,o,ed of roerly
'o container i, truly BemtyBunle,, roerly cleaned
Follo$ >S;S re?uirement, for
container di,o,al
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Chemical ;i,o,al
Recycle unu,edchemical,
;o not lace hazardou,chemical, in normaltra,h recetacle,.
'o not (our
chemicals into sin)sonto the round orin storm drains
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Safe Stora"e
Store incomati)le chemical, in,earate area,
Eimit the amount of Iamma)lematerial to the minimum needed
Store Iamma)le li?uid, in
aro(ed Iamma)le ,tora"eloc3er,
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Safe Stora"e
Store acid, in ,earate Iamma)le,tora"e loc3er,
;o not ,tore chemical, in arefri"erator u,ed for food ,tora"e
;o not ,tore food in refri"erator,
u,ed for chemical ,tora"e
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6n ca,e of an emer"ency
6mlement the roer Dmer"encyAction lan
D(acuate eole from the area6,olate the area 3ee other from
enterin"
-urn o i"nition and heat ,ource,Only trained emloyee, areermitted to clean u ,ill,
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>aterial Safety ;ata Sheet,
/>S;SSho$ chemical ,afety information
Dach chemical ha, a ,earate >S;S
>S;S i, $ritten )y the chemicalmanufacturer
>S;S are 3et in the $or3lace foryour u,e
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>aterial Safety ;ata Sheet,
are (ro,ided #& the chemical manufacturerto (ro,ide additional informationconcernin safe use of the (roduct.
%aterial Safet& 'ata Sheets 8%S'S
Current /ormat
F
Safet& 'ata Sheets 8S'S
3e! format reuired #& :une 1 201;
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Dach >S;S tell, you
1. Common 'ame and Chemical'ame of the material
2. 'ame5 addre,, and hone num)erof the manufacturer
. Dmer"ency hone num)er, for
immediate hazard informationP. ;ate the >S;S $a, $ritten
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>S;S
+. Hazardou, in"redient,
. hy,ical & Health Hazard, of the
chemical,. 6denti@cation of chemical and
hy,ical roertie,
*. Fir,t Aid : Dmer"ency 6nformation9. Safe handlin" and u,e information
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>S;S
ha(e ,eci@c hazard information on Fire & D7lo,ion
Chemical Reaction, Control >ea,ure,
Health Hazard,
Sill & Eea3 rocedure,
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>S;S /ire F *+(losionaterial Fla,h oint5 autoi"nition temerature anduer:lo$er Iamma)ility
limit,Fire e7tin"ui,hin" a"ent,
to )e u,ed
Fire @"htin" techni?ue,
Any unu,ual @re ore7lo,i(e hazard,
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>S;S eaction
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>S;S Control %easures
Dn"ineerin" Control, re?uired for,afe roduct u,e
er,onal rotecti(e e?uimentre?uired for u,e of roduct
Safe ,tora"e re?uirement, and
"uideline,Safe handlin" rocedure,
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>S;S Health Hazards
Permissi#le *+(osure andThreshold "imits 8P*" F T"G
S&m(toms of e+(osureoutes of entr& into the #od&
%edical conditions that can #emade !orse #& e+(osure
Cancer causin (ro(erties
*merenc& F /irst Aid Procedures
S S
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>S;S S(ill F "ea)Procedures
Clean u techni?ue,
er,onal rotecti(e D?uiment to
)e u,ed durin" cleanu;i,o,al of $a,te & cleanu
material
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rotectin" 4our,elf
er,onal rotecti(eD?uiment /D may )eneeded to rotect your,elf
from chemical hazard,,e the D our Comany
ha, re?uired for eachchemical
Chec3 the D )efore u,e toma3e ,ure it i, notdama"ed
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rotectin" 4our,elf
,e face ,hield and o""le, ifthere i, a ,la,h hazard
,e the roer re,irator for du,t,5mi,t, and fume,
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rotectin" 4our,elf
,e the ri"ht "lo(e, $hen handlin"chemical,
roerly clean and ,tore your Dafter u,e
;onTt ta3e D home $hy ri,3
e7o,in" your familyN
St f h i
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Stay ,afe $hen u,in"chemical,
#no$ $hat you are $or3in" $ith
#no$ $here >S;S are located and
ho$ to u,e themA,3 your ,uer(i,or if you ha(e
?ue,tion,
Only trained emloyee, may u,echemical,
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Stay Safe
>a3e ,ure all container,are roerly la)eled
,e the roer rotecti(ee?uiment
Store chemical, only inaro(ed area,
6mmediately reort lea3,and ,ill,
;i,o,eof u,ed chemical,and container, roerly
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THA3 7O$
A3'
-O' B"*SS..
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