University of Isfahan Faculty of Engineering Department of Mechanical Engineering Energy course
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University of Isfahan Faculty of Engineering Department of Mechanical Engineering Energy course Methanol Fuel Cell Prepared by: Hosein Farzaneh Email:[email protected]
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University of Isfahan Faculty of Engineering Department of Mechanical Engineering Energy course Methanol Fuel Cell Prepared by: Hosein Farzaneh Email:[email protected]. مقدمه. - PowerPoint PPT Presentation
Transcript of University of Isfahan Faculty of Engineering Department of Mechanical Engineering Energy course
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University of IsfahanFaculty of EngineeringDepartment of Mechanical Engineering
Energy courseMethanol Fuel Cell
Prepared by:Hosein Farzaneh
Email:[email protected]
.
(PAFC) (AFC) (MCFC) (SOFC) (DMFC) (PFC) - (ZAFC) (AAFC) (MAFC) (IAFC) (LAFC)- (CAFC) ( ): - - ( ): - - - - -
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. : . . ( ) . 200 ( 700 ) . . . .
CH3OH . . . . "" ( CO H2 ) . - . . - . CO H2 . ICI . - .
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CH3OH + H2O ==> CO2 + 6H+ + 6e- 3/2 O2 + 6 H+ + 6e- ==> 3 H2O CH3OH + 3/2 O2 ==> CO2 + 2 H2O : :
(IDMFC) 500 5 . . . .
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2) DMFC)) 1981 . SPE . :
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CO .
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pt-Ru pt-Sn . pt-Ru .
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(DMFC) (SPE) . . ( ) ( ) 1977 450 DMFC . linden,D.(1984), Handbook of batteries and fuel cells, mcGrow Hill, NY.Meyer, A.[. (1978). 1,5 KW methanol fuel cell power plant system design study, proceedings of 28th power sources symposium,electrochemical society, pennington, NJ., U.S.A.specific of purchase description for fuel cell power units U.S. Army mobility R&D command, ft. Belwoir VA 22060.General electric, Aircraft Equipment division, direct energy conversion programs, (1981) feasibility study of SPE fuel cell power plants for Automotive Application. Final study Report,Univ. of California, los Alamos national laboratory, los Alamos, new mexico.Blomen, L.J. M.J. and mugerwa, M.N. (eds)( 1993). Fuel cell systems, plenum press, NY.PP.68-69. Parsons, R., Noot, T.V.d. (1988), J.Electroanal. chem. Vol.257,P.9.Proceeding of 26th Symp. On Automotive tech. & automation, (13-17 sep. 1993), Aache, Germany.Leger,J. m., lemy,C. (1990), Ber. Bunsenges. Phys. Chem. Vol.94,p.1021.Kunimatsu, K.(1990), Ber. Bunsrenges. Phys, Chem. Vol.94,P.1025.Ross, P.N.m Gasteiger, H.A. (1995) methanol electrocatalysis by pt alloys and adatoms- modified Pt, proceedings of the ist int.symp. On new material for fuel cell systems, monteral, Quebec,Canada, June 9-13, P.286.Aramata, A.; toyoshima, I; Enyo, M.(1992). Electrochemica Acta,Vol. 37,P.1317.Kadirgan, f.; Beden, Leger, J-M., Lamy, C.(1982).J. Electroanal,chem. Vol. 142,p.171.Shibata, M.;motoo,S. (1987). J.Electronal. Chem, vol.229, P.385Hydrogen and fuel cell letter, special lssue, 15 April 1992.
Garcia BL, Sethuraman VA,Weidner JW,White RE. Mathematical model of a direct methanol fuel cell. J Fuel Cell Sci Technol 2004;1:438.Hang Guo, Chong-fang Ma. 2D analytical model of a direct methanol fuel cell. Electrochem Commun 2004;6:30612.Kulikovsky AA. Analytical model of the anode side of DMFC: the effect of non-Tafel kinetics on cell performance. Electrochem Commun 2003;5: 5308.Kulikovsky AA. A method for analysis of DMFC performance curves. Electrochem Commun 2003;5:10306.Scott K, Argyropoulos P. A one dimensional model of a methanol fuel cell anode. J Power Sources 2004;137:22838.Scott K, Taama W, Cruickshank J. Performance and modeling of a direct methanol solid polymer electrolyte fuel cell. J Power Sources 1997;65: 15971.L. Pisani, G. Murgia, M. Valentn, B. DAguanno, A new semiempirical approach to performance curves of polymer electrolyte fuel cells, J. Power Sources 108 (2002) 192203.Kulikovsky AA. The voltage-current curve of a direct methanol fuel cell: exact and fitting equations. Electrochem Commun 2002;4:93946.Wang ZH, Wang CY. Mathematical modeling of liquid-feed direct methanol fuel cell. J Electrochem Soc 2003;150(4):A50819.
