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Transcript of IHEMQ?GB?IHEBF?JGUOFBDJHKN?JBBKKE?>H
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«ИИИ» ИИИИИИИИИИИИ қ0ҚИИ . ИИИИИ қҚқ.қ3қ.40
- : Қ99004 - , . ., .4Қ/43, .
. . , ., 7/9.
www.spbu.ru.
« » қ0ҚИИ .
, Су Н а Г а
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3
: ,
. қ0 , ,
, , , ,
. , ( )
, , , , .
, – ,
, , ,
( , , ).
, , ,
- - .
. , -
- ,
.
;
.
: - ( ) -
;
- NКCХ
- ; -
, , ; - ,
;
- ;
- .
: -
, ,
; , ;
-
4
- , : (V2) « » ( ), (τ /τ )
(k/b), (W2) (φ ) - (r3 );
τ /τ , . - - -
( - , - ) ;
- , ,
:
,
. , , .
, : - ( (Uef),
(ζSm ζW) ) 0.Қ9 – 1.02 (3.0 – 9.0)
NКCХ (0.001 – 0.Қ5 / ). , ζW ,
; -
, , - - -
( ). , - .
- ,
; - , -
, ; ,
;
- .
;
- , ( ) ( = 0.55 = 0.4қ ; = 0.қ3
= 0.Қ9 ) , . . ;
- , , , . ,
, , – . - .
-
5
: :
« », , қ6-қ8 қ0Ққ .; 8- -
. Ққ-Қ5 , - , қ0Ққ .; III « » " і" қ0Ққ;
– I : Қ7- - ( , қҚ – қ6 қ0Қ3 .); III
« – », -, қ5-қ6 қ0Қ3 ; IV IЧЭОrЧКЭТШЧКХ МШЧПОrОЧМО ШЧ МШХХШТНКХ МСОmТsЭrв КЧН
physicochemical mechanics. Moscow, 30 June – 05 July, 2013; 9th Saint-Petersburg Young Scientists Conference. November 11-14, 2013 Saint- PОЭОrsЛЮrР; IV
« – », - , Қ4-Қ5 қ0Қ4; – I : Қ8-
- ( ,қ0Қ4 .); V ё « » 6-Қ0 қ0Қ4; Қ0ЭС SКТЧЭ-Petersburg Young Scientists
Conference. November 10-14, 2014 Saint- PОЭОrsЛЮrР; II - « », - , Қ7
қ0Қ4 ; « -қ0Қ5» , қ0Қ5; V
« – », - , қ0-қҚ ; – I : Қ9- - ( , қ0 – қ4 қ0Қ5 .); IV « -қ0Қ5», . 3 – қ0Қ5 ; III
- , . - қ9 – Қ қ0Қ5 ; MШНОrЧ prШЛХОm of polymer Science. 11th International Saint-Petersburg Conference of Young Scientists. November 9-
12, 2015 Saint- PОЭОrsЛЮrР; III - « ». - , Қ0-ҚҚ қ0Қ5 .
: 36 , 3 – ,
, Қ – , , 32 , - .
: , ( ,
, ), , (қҚ3 ), Қ9қ , 7Қ , Қ5 қ
. :
, , .
– . . . . . . . . . . . , ; . . . . . ; . . . . .
, , . . . . .
. :
, , .
-
6
« » ;
; -
. « »
, .
, .
, N- , ( . [9-14]).
, – ( . Қ).
.Қ. = 0.55 ( ), = 0.4қ ( ).
SОЯОЧMЮХЭТ MОЭХОrTШХОНШ
( ). Қ .
.1. .
№
, ,
, 2/
,
μ / 2 1 0.23
-
-COOH
23.9 1.18
2 0.55 10.0 1.0
3 1.02 5.4 2.68
4 0.19
-NH2
29.0 0.85
5 0.42 13.1 0.78
6 0.45
12.2 0.34
7 0.50 11.0 -
( 7%),
, MКХЯОrЧГОЭКsТгОrNКЧШ-ZS. ( > 0.4 )
( қ0%), ( ~ 0.қ ) ( қ0%). « »
. .
-
7
III.1 NaCl
NКCХ . , ( = 0.55 , = Қ.0қ
= 0.4қ ) . - .
( = 0.23 = 0.Қ9 ) MКХЯОrЧГОЭКsТгОrNКЧШ-ZS. = 0.55
, , Uef
( .2 қ) , ( .қ Қ).
.2. ζ- ( = 0.55 ) ,
MКХЯОrЧГОЭКsТгОrNКЧШ-ZS (Қ) (қ),
NaCl = 0.0Қ / .
ζ- ; 9.0 ,
(7%). ζ- . ζ- ( АТОrsОmК) :
ζ- = 0.55 = 1.02 . = 0.23 ққ%,
. ζ-
, ( = 0.19 ) 34%, ,
( = 0.42 ) NaCl қ0%. ζ- ( .3, , ) .
.3. ζ- ( = 0.42 ) ( = 0.55 ) CNaCl = 0.001 (1,4); 0.01 (2,5); 0.1 (6); 0.15(3) / .
.3. ζ- ( = 0.19 )(1);( = 0.42 )(қ) ( = 0.23 )(3); ( = 0.55 )(4); ( = 1.02 )(5)
CNaCl = 0.0Қ / .
3 4 5 6 7 8 9
10
20
30
40
50
60
70
80
2
1
В
pH
(1)
(2)
3 4 5 6 7 8 9
-60
-40
-20
0
20
40
60
5
4
3
2
(3) а=0.23 (4) а=0.55 (5) а=1.02
CNaCl=0.01 /
(1) а=0.19 (2) а=0.42
,
pH
1
3 4 5 6 7 8 9
-60
-40
-20
0
20
40
60
а=0.55 (4) CNaCl=0.001 /
(5) CNaCl=0.01 /
(6) CNaCl=0.1 /6
4
5
3
2
,
pH
а=0.42 (1) CNaCl=0.001 /
(2) CNaCl=0.01 /
(3) CNaCl=0.15 /1
-
8
ζ( ) ( .3. , Қ-3) ζ- ,
. ζ- , .
. ζ-
( .3. ) , ζ-
( Қ,қ). , ζ- , .
III.2.
(3.0 - 9.0) 0.00Қ – 0.Қ5 / .
, - . ,
, m, (n0) (nt): m = n0/nt.
.4. ( = 0.23 ) 3.0 CNaCl = 0.0Қ / ,
(Қ) (n0 = 1.1×107 / 3) (2)
(n0 = 3.6×1011
/ 3)
( = 0.23 ) ( .4), m(t) , (
) . , , ,
.
.
( = 0.55 ) ( .5) ( ).
( = 0.55 ) NКCХ (0.00Қ, 0.0Қ 0.Қ / ) .6. .
. ( = 0.55 )
(Vmax
-
9
. ( .6. - ).
.5
.6 .5. ( = 0.55 ) 3.0 ( ), 4.0 ( ), ( ), 9.0 ( ) NКCХ:
0.00Қ (Қ), 0.0Қ (қ), 0.Қ (3) / (n0 = 3.2×106 / 3) .6.
( = 0.55 ) 3.0 ( ), 4.0 ( ), ( ), 9.0 ( ) NaCl: 0.001 (1), 0.01 (2), 0.1 (3) / .
( = 0.55 ) ,
V(h), NКCХ 2.
(W1) (W2).
20 40 60 80
-10
-5
0
5
10
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.1 /
3
2 1
h,
V/kT
20 40 60 80
-10
-5
0
5
10
3
2 1V/kT
h,
(1) CNaCl=0.001 /
(2) CNaCl=0.01 / (3) CNaCl=0.1 /
20 40 60 80
-10
-5
0
5
10
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.1 /
3 2 1
V/kT
h,
V/kT
20 40 60 80
-10
-5
0
5
10
3 2 1
h,
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.1 /
50 100 150 200 250 3000
1
2
3
4
2
3
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.1 /
m
t,
1
50 100 150 200 250 3000
1
2
3
4
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.1 /
m
t,
50 100 150 200 250 3000
1
2
3
4
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.1 /
m
t,
50 100 150 200 250 3000
1
2
3
4
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.1 /
m
t,
6
-
10
қ. ( = 0.55 ) , NКCХ 3.0 – 9.0,
, .
2 , NaCl -
, - .
, , m.
.7 mt=300
3.0 - 9.0.
.7. ( = 0.55 )
300
3.0 - 9.0
, - . ,
= 0.55 .
pH CNaCl,
/ Vmа ,
kT
hmax,
-V2,
kT
hmin,
W1 W2 П а а а а у я
3.0
0.001 41.6 2.3 0.03 63.1 >1010
29.3
0.01 8.3 2.4 0.4 16.8 280 3.2
0.1 1.7 1.2 4.0 3.7 1.3 1.0 ( - )
4.0
0.001 287.5 0.9 0.01 112.0 >1010
84.8
0.01 80.3 1.1 0.2 24.5 >1010
5.4
0.1 31.8 0.6 2.7 4.9 >1010
1.0
5.8-
6.2
0.001 644.9 1.0 0.01 126.8 >1010
106.1
0.01 596.8 0.3 0.1 31.3 >1010
7.69
0.1 345.1 0.3 1.8 7.1 >1010
1.2
9.0
0.001 686.9 1.0 0.01 127.5 >1010
106.9
0.01 596.8 0.3 0.1 31.3 >1010
7.7
0.1 345.1 0.3 1.8 7.1 >1010
1.2
-
11
. , = 0.55
. .
= 0.4қ .8; .
, , 3.0.
( = 0.4қ ) , V(h), NКCХ (0.00Қ, 0.0Қ 0.Қ5 / ) .9.
.8
.9
.8. ( = 0.4қ ) 3.0 ( ), 4.0 ( ), ( ), 9.0 ( ) NКCХ: 0.001 (1), 0.01
(қ), 0.Қ5 (3) / (n0 = 2.9×106 / 3) .9.
( = 0.42 ) 3.0 ( ), 4.0 ( ), ( ), 9.0 ( ) NaCl: 0.001 (1), 0.0Қ (қ), 0.Қ5 (3) / .
0 50 100 150 200 250 300
1
2
3
t,
1
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.15 /
m
2
3
0 50 100 150 200 250 300
1
2
3 (1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.15 /
t,
m
1
2
3
0 50 100 150 200 250 300
1
2
3
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.15 /
t,
1
m
2
3
0 50 100 150 200 250 300
1
2
3
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.15 / 3
2
1
t,
m
20 40 60
-10
0
10
20
30
40
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.15 /
V/kT
h,
1
2
3
20 40 60
-10
0
10
20
30
40
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.15 /
V/kT
h,
12
3
20 40 60
-10
-5
0
5
10
(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.15 /
h,
1
2
3
V/kT
-
12
. , ,
4.0 0.Қ5 / ( .9. , , 3). 9.0 ,
NaCl = 0.0Қ 0.15 / . , , .
= 0.23 , = 0.55 =1.02 .
, .
, .
, . V(h)
.10. (>30 kT) .
.10.
= 0.қ3 (Қ), = 0.55 (қ), = Қ.0қ (3)
.
,
, , , – , -.
- . ,
, « » .11. 1 0.2 – 1.8
( .ҚҚ, Қ), 0.7 ( .ҚҚ, қ).
= 0.Қ9 > 1.2 ( .Қ2). ,
, .
(τ ) (τ ), , , .
, τ /τ 0.05 0.55
1 , x = ( +С)/a, С - .
10 20 30
-5
0
5
(1) a = 0.23 (2) a= 0.55 (3) a= .02
h,
V/kT
1
2
3
10 200
50
100
150
200
250
300
350
V/kT
h,
-
13
, τ /τ Қ.3қ Қ.7 .
NКCХ (φ , φ ), –
(0.8 – 4.3)·10-7; - (r3 ) – (5 – 50)·10-15 3, . ,
φ , 9·10-6. (k) (b)
k/b = 2.8·10-16 – 3.9·10-13 3/ .
, Қ:Қ.
.
, ζ- . .13-14 m(t) = 0.55
= 0.42 , = 0.22 = 0.Қ9 . .
.Қ3. ( = 0.55 ) ( = 0.4қ ) . NaCl = 0.00Қ / , (ζ- : -6Қ.8 +қ0.3 ) (1); 4.0 (ζ- : -4Қ.қ + 40.5 ) (2).
.Қ4. ( = 0.23 ) ( = 0.19 ) . NaCl = 0.001 / , (ζ- : -54.0 + 53.3 ) (1); 4.0 (ζ- : -қҚ.7 +54.0 ) (2)
.ҚҚ (Қ)
(2) , 300 , « » . .Ққ ( = 0.Қ9 ) ,
300 , « » .
0 50 100 150 200 250 300
1
2
3
(1) pH (2) pH4.0
m
t, 0 50 100 150 200 250 300
5
10
15
(1) pH (2) pH4.0
m
t,
-
14
III.4. И И Ц .
, 1-(4- ) , : ζ-
+4қ , -3қ .
, ,
« » . = 0.45 .
( .Қ5), ( NaCl = 0.00Қ / )
.
.15.
(Қ,3)
(4,5) (Қ,4) , (3,5); қ –
.
, , . , ,
(-9 ), .
, - .
III.5. И - .
-
: , ( , .)
. .16 ζ- - .
, ζ- .
.Қ6. ζ- ( = 0.Қ9 )
( Қ,3) ( = 0.қ3 ) ( қ,4)
50 100 150 200 250 3000
1
2
54
3
2
2
1
m
t,
(1) ы, ы ы ФИ Ц (2) ы (3) ы, ы ы ФИ Ц ф . (4) ы, ы ы ФИ Ц (5) ы, ы ы ФИ Ц ф .
0 15 20 25 30
-60
-40
-20
0
20
40
60
4
3
2
1
% .
(1) - а=0.19 (2) - а=0.23 (3) - а=0.19 (4) - а=0.23
-
15
. ζ- , ,
. ( , ) қ5% .
. .17
( = 0.қ3 ) ( .Қ7. ) ( = 0.Қ9 ) ( .Қ7. ) - : ( Қ-3),
NaCl = 0.001 / . ( 4 .Қ7, , ).
.17. ( = 0.қ3 ) ( ) ( = 0.Қ9 ) ( ) -
( Қ-3) NaCl = 0.00Қ / . 4 .
w = Ққ% . . ,
; .
- , (Uef), (ζSm ζW)
, 0.19 – Қ.0қ (3.0 – 9.0) NКCХ (0.001 – 0.Қ5 / ).
, ζW ,
; -
- - -
( ). , - .
-
, ; - , -
ó , . ,
50 100 150 200 250 300
0
1
2
3
4
4
1
2
m
t,
(1) 12 % . (2) 21 % . (3) 32 % . (4) я 3
50 100 150 200 250 300
0
1
2
3
4
4
1
2
3
m
t,
(1) 12 % . (2) 21 % . (3) 32 % . (4) я
-
16
;
- ( ) –
(V2), « » ( ), ( / ) (k11/b11); ,
-
.
;
- , ( ) ( = 0.55 = 0.4қ ; = 0.қ3
= 0.Қ9 ) , . . ;
- , . ,
, , – ; - , ( Қ0% . 30% .)
, ; -
. - қ5% . .
, Ққ% .
, , К: 1. К .И., Ш И. , . .// Physicochemical properties of water–alcohol
mixtures. Glass physics and chemistry vol. 38 no. 5 2012, p 460-465.
2. Ш И. ., К .И., . ., Ш . ., . .// . Қ.
. . қ0Қ4. .37. №қ. .қ9-38.
3. Ш И. ., . ., Ш И. ., К . И., . ., Ш . ., . .// қ.
. . қ0Қ4. .39. №қ9. .98-106.
: 1. Ш . ., Ш И. , . . К .И.// -
- , Қ3-қ3 қ0Қ0 . -
, - қ0ҚҚ,, . Қ8-19 2. К .И., Ш И. , . .// - -
, - , 65- . I, - , қ0Қ0, . 109 – 112
3. Ш И. , Ш . ., К .И.// - - , Қ4
- . Қ, қ0Қ0, . 7Қ
http://butlerov.com/stat/users/details.asp?lang=ru&id=2843http://butlerov.com/stat/users/details.asp?lang=ru&id=2868http://butlerov.com/reg/step1/index.asp?type=2&name9=%C1%E5%EB%FF%E5%E2%20%C0%EB%E5%EA%F1%E5%E9%20%CF%E5%F2%F0%EE%E2%E8%F7http://butlerov.com/stat/users/details.asp?lang=ru&id=2873http://butlerov.com/stat/users/details.asp?lang=ru&id=2874
-
17
4. Ш И. , . . К .И.// , «
– » қ0-қҚ қ0ҚҚ . - , - , қ0ҚҚ, . ҚҚ3-114 5. Ш И. , К .И.//
, Қ5 - . Қ, қ0ҚҚ, 394
6. Ш И. , К .И.// ,
, 300- . . Қ50- . . . қ9
қ0ҚҚ . - , - , қ0ҚҚ, . 74-75 7. К .И., Ш И. , . .// -
- , , 300- . . Қ50-
. . . қ9 қ0ҚҚ . - , - , қ0ҚҚ, . 57-58
8. Ш И. , . . К .И.// - . - , II
« – » . . . Қ4 қ0ҚҚ . - , қ0ҚҚ ., . қ3-24
9. Ш И. ., . . .И. К , . . . И Ш . .// , II
« – » Қ8-Қ9 қ0Ққ . II, - қ0Ққ . .55-56
10. Ш И. ., . ., . ., Ш . ., К .И.// : ,
Қ6 - . қ0Ққ, . қ4қ
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. III . . қ9
-Қ қ0Ққ, . 6қ9-630 12. Ш И. ., К .И., . ., . ., Ш . .//
( - - ): .
. . , қ6-қ8 қ0Ққ ., . 3ққ
13. Ш И. ., . ., . ., К .И., Ш . .// ( - - ):
. 8- - . 12-15 , - , қ0Ққ ., . 112
14. Ш И. ., К .И., . ., . ., Ш . .//
. III « » " і" 2012, № 3 (65), . Қ76-180
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М . – I : Қ7- -
-
18
( , қҚ – қ6 қ0Қ3 .). . , . , қҚ – қ6 қ0Қ3 ., .Қ66
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V « – », - , 20-қҚ қ0Қ5 . –
- , - , қ0Қ5, . 538-540. 21. Ш И. ., . ., К . И., . ., Ш . .//
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. IV « -қ0Қ5», . 3 – қ0Қ5 . .87.
23. Ш И. ., . ., К .И., . ., . ., Ш . .//
. қ0Қ5. III - , . - қ9 – Қ қ0Қ5
. .50-51. 24. Shirokova I.Yu., Kuchuk V.I, Belyaev A.P., Pankova G.A., Shevchenko N.N., Baigildin
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СпециальностьАВТОРЕФЕРАТУченый секретарьIII.1 Электрокинетическое поведение латексов полистирола в растворах NaClIII.2. Агрегативная устойчивость латексов полистирола с поверхностными функциональными группамиIII.4. Исследование электроповерхностных свойств и агарегативной устойчивости частиц ММА с модифицированной ФИТЦ поверхностью.III.5. Исследование электроповерхностных характеристик и агрегативной устойчивости латексов в водно-спиртовой дисперсионной среде.