COSHH Transaqua HT2.pdf

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    Material Safety Data Sheet

    . Product and company identification

    roduct name Transaqua HT2

    SDS # 462602

    roduct use Hydraulic fluid .For specific application advice see appropriate Technical Data Sheet or consult our companyrepresentative.

    ode 462602-US39

    upplier Castrol OffshoreDivision of BP Products North America200 Westlake Blvd.Houston, Texas 77079Tel: 800-339-7157

    MERGENCY HEALTH

    NFORMATION:

    1 (800) 447-8735

    Outside the US: +1 703-527-3887 (CHEMTREC)

    MERGENCY SPILLNFORMATION:

    1 (800) 424-9300 CHEMTREC (USA)

    THER PRODUCT

    NFORMATION

    1 (866) 4 BP - MSDS(866-427-6737 Toll Free - North America)email: [email protected]

    . Hazards identification

    hysical state

    olor Brown.

    mergency overview DANGER !

    HARMFUL OR FATAL IF SWALLOWEDINHALATION CAUSES HEADACHES, DIZZINESS, DROWSINESS AND NAUSEA AND MAYLEAD TO UNCONSCIOUSNESS.CAUSES EYE AND SKIN IRRITATION.MAY CAUSE RESPIRATORY TRACT IRRITATION.

    Harmful or fatal if swallowed. Do not breathe vapor or mist. Do not ingest. Avoid contact witheyes, skin and clothing. Use only with adequate ventilation. Keep container tightly closed andsealed until ready for use. Wash thoroughly after handling.

    Dermal contact. Eye contact. Inhalation.outes of entry

    otential health effects

    Eyes Causes eye irritation.

    Skin Causes skin irritation.

    Inhalation Over-exposure by inhalation may cause respiratory irritation. Inhalation causes headaches,dizziness, drowsiness and nausea and may lead to unconsciousness.

    Ingestion Harmful or fatal if swallowed. Ingestion may cause gastrointestinal irritation and diarrhea.Contains material which may cause damage to the following organs: Kidneys.

    ee toxicological information (Section 11)

    Liquid.

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    . Composition/information on ingredients

    ngredient name CAS # %

    thylene glycol 107-21-1 45 - 50riethanolamine 102-71-6 1 - 5

    thylene glycol; ethanediol . Proprietary performance additives.

    . First aid measures

    ye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Getmedical attention.

    kin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Washclothing before reuse. Clean shoes thoroughly before reuse. Get medical attention.

    nhalation If inhaled, remove to fresh air. If it is suspected that fumes are still present, the rescuer shouldwear an appropriate mask or self-contained breathing apparatus. If not breathing, give artificialrespiration. If breathing is difficult, give oxygen. Get medical attention immediately.

    ngestion Do not induce vomiting unless directed to do so by medical personnel. Never give anything bymouth to an unconscious person. Get medical attention immediately.

    otes to physician Treatment should in general be symptomatic and directed to relieving any effects.

    Note: High Pressure ApplicationsInjections through the skin resulting from contact with the product at high pressure constitute amajor medical emergency. Injuries may not appear serious at first but within a few hours tissuebecomes swollen, discolored and extremely painful with extensive subcutaneous necrosis.Surgical exploration should be undertaken without delay. Thorough and extensive debridement of

    the wound and underlying tissue is necessary to minimize tissue loss and prevent or limitpermanent damage. Note that high pressure may force the product considerable distances alongtissue planes.

    . Fire-fighting measures

    Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.No action shall be taken involving any personal risk or without suitable training.

    rotective clothing (fire) Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

    ire-fighting procedures

    azardous combustion

    roductsCombustion products may include the following:carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)nitrogen oxides (NO, NO etc.)

    In a fire or if heated, a pressure increase will occur and the container may burst.ire/explosion hazards

    lash point [Product does not sustain combustion.]

    Water content interferes with flash point determination.

    xtinguishing media

    Suitable Use an extinguishing agent suitable for the surrounding fire.

    Do not use water jet.Not suitable

    . Accidental release measures

    No action shall be taken involving any personal risk or without suitable training. Keepunnecessary and unprotected personnel from entering. Do not touch or walk through spilledmaterial. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriaterespirator when ventilation is inadequate. Put on appropriate personal protective equipment (seeSection 8).

    nvironmental

    recautions

    Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.Inform the relevant authorities if the product has caused environmental pollution (sewers,waterways, soil or air).

    ersonal precautions

    ethods for cleaning up

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    Stop leak if without risk. Move containers from spill area. Approach release from upwind.Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into aneffluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container fordisposal according to local regulations (see Section 13). Dispose of via a licensed waste disposalcontractor. Contaminated absorbent material may pose the same hazard as the spilled product.Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

    Large spill

    Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in anappropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

    Small spill

    . Handling and storage

    andling Put on appropriate personal protective equipment (see Section 8). Workers should wash handsand face before eating, drinking and smoking. Do not breathe vapor or mist. Do not ingest.Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wear appropriaterespirator when ventilation is inadequate.

    torage Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefully resealed andkept upright to prevent leakage. Do not store in unlabeled containers. Use appropriatecontainment to avoid environmental contamination.

    DO NOT ADD NITRITES TO THIS FLUID.ther information

    . Exposure controls/personal protection

    ccupational exposure limits

    thylene glycol ACGIH TLV (United States).

    C: 100 mg/m Issued/Revised: 5/1995 Form: Aerosolriethanolamine ACGIH TLV (United States).

    TWA: 5 mg/m 8 hours. Issued/Revised: 9/1994

    ngredient name Occupational exposure limits

    ome states may enforce more stringent exposure limits.

    While specific OELs for certain components may be shown in this section, other components may be present in any mist, vapor orust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided for guidance only.

    ontrol Measures Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or otherengineering controls to keep worker exposure to airborne contaminants below any recommendedor statutory limits.

    ygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating,smoking and using the lavatory and at the end of the working period. Appropriate techniquesshould be used to remove potentially contaminated clothing. Wash contaminated clothing beforereusing.

    ersonal protection

    Eyes Avoid contact with eyes. Safety glasses with side shields or chemical goggles.

    Skin and body Do not get on skin or clothing. Wear suitable protective clothing.

    Respiratory Use adequate ventilation. Do not breathe vapor or mist.

    Hands The correct choice of protective gloves depends upon the chemicals being handled, the conditionsof work and use, and the condition of the gloves (even the best chemically resistant glove willbreak down after repeated chemical exposures). Most gloves provide only a short time ofprotection before they must be discarded and replaced. Because specific work environments and

    material handling practices vary, safety procedures should be developed for each intendedapplication. Gloves should therefore be chosen in consultation with the supplier/manufacturer andwith a full assessment of the working conditions.

    Consult your supervisor or Standard Operating Procedure (S.O.P) for special handling instructions.

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    Physical and chemical properties.

    hysical state Liquid.

    olor Brown.

    pecific gravity 1.075

    H 8.7

    iscosity Kinematic: 2.1 to 2.5 mm2/s (2.1 to 2.5 cSt) at 40C

    lash point [Product does not sustain combustion.]

    Water content interferes with flash point determination.

    olubility Soluble in water.

    0. Stability and reactivity

    The product is stable.

    Reactive or incompatible with the following materials: oxidizing materials.

    Under normal conditions of storage and use, hazardous decomposition products should not beproduced.

    Not available.

    tability and reactivity

    onditions to avoid

    ncompatibility with

    arious substances

    azardous decompositionroducts

    Under normal conditions of storage and use, hazardous polymerization will not occur.azardous polymerization

    ossibility of hazardous

    eactions

    Under normal conditions of storage and use, hazardous reactions will not occur.

    1. Toxicological information

    lassification

    riethanolamine 3 - -

    roduct/ingredient name NTPIARC OSHA

    Ethylene glycol: Ingestion of ethylene glycol can cause metabolic acidosis, kidney damage,central nervous system depression, convulsions and death. The estimated human lethal dose isapproximately 1 ml/kg (about 1/2 cup for an adult). Vapor from hot operations or an aerosol cancause eye and respiratory irritation. Birth defects were reported in laboratory animals fed ethyleneglycol repeatedly in large amounts. Based on these studies, there may be a potential for birthdefects following ingestion of ethylene glycol by pregnant women.

    Contains material that may cause target organ damage, based on animal data. Target Organs:liver and Kidneys.

    ther Toxicity Data

    otential chronic health effects

    Carcinogenicity No known significant effects or critical hazards.

    Alkanolamine: This product contains an alkanolamine. In all metalworking fluids containingamines, there is a potential for forming nitrosamines which are animal carcinogens. Therefore, nonitrites or related nitrosating agents should be added to such compositions.

    ther information

    ARC :- Not classifiable as a human carcinogen.

    Ecological information2.

    cotoxicity

    obility Spillages may penetrate the soil causing ground water contamination.

    This product is not expected to bioaccumulate through food chains in the environment.ioaccumulative potential

    ersistence/degradability Biodegradable

    o testing has been performed by the manufacturer.

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    ther ecological

    nformation

    Miscible in water. Spills on water will disperse throughout the water phase. Unlikely to be harmfulto aquatic organisms unless glycol concentration is high.

    3. Disposal considerations

    Waste information The generation of waste should be avoided or minimized wherever possible. Disposal of thisproduct, solutions and any by-products should at all times comply with the requirements ofenvironmental protection and waste disposal legislation and any regional local authorityrequirements. Dispose of surplus and non-recyclable products via a licensed waste disposalcontractor. Waste should not be disposed of untreated to the sewer unless fully compliant withthe requirements of all authorities with jurisdiction. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material andits container must be disposed of in a safe way. Care should be taken when handling emptied

    containers that have not been cleaned or rinsed out. Empty containers or liners may retain someproduct residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways,drains and sewers.

    OTE: The generator of waste has the responsibility for proper waste identification (based on characteristic(s) or listing),

    ansportation and disposal

    4. Transport information

    ot classified as hazardous for transport (DOT, TDG, IMO/IMDG, IATA/ICAO)

    5. Regulatory information

    All components are listed or exempted.

    . Federal Regulations

    SARA 302/304: No products were found.SARA 311/312 Hazards identification: Immediate (acute) health hazard, Delayed (chronic)

    health hazard

    State regulations

    Ethylene glycol 107-21-1 45.776 - 46.005

    Ethylene glycol 107-21-1 45.776 - 46.005

    SARA 313

    Form R - Reporting

    requirements

    Supplier notification

    ConcentrationCAS numberProduct name

    CERCLA: Hazardous substances.: Ethylene glycol: 5000 lbs. (2270 kg); Phosphoric acid: 5000 lbs.(2270 kg); sodium hydroxide: 1000 lbs. (454 kg);

    CERCLA Sections

    102a/103 Hazardous

    Substances (40 CFR

    Part 302.4):

    Massachusetts

    Substances

    The following components are listed: ETHYLENE GLYCOL; TRIETHANOLAMINE

    New Jersey Hazardous

    Substances

    The following components are listed: ETHYLENE GLYCOL; 1,2-ETHANEDIOL;TRIETHANOLAMINE; ETHANOL, 2,2',2"-NITRILOTRIS-

    Pennsylvania RTK

    Hazardous Substances

    The following components are listed: 1,2-ETHANEDIOL; ETHANOL, 2,2',2"-NITRILOTRIS-

    California Prop 65: No products were foundCalifornia Prop. 65

    All components are listed or exempted.

    At least one component is not listed.

    At least one component is not listed.

    At least one component is not listed.

    Canada inventory

    China inventory (IECSC)

    Japan inventory (ENCS)

    Australia inventory (AICS)

    United States inventory

    (TSCA 8b)

    Other regulations

    REACH Status For the REACH status of this product please consult your company contact, as identified inSection 1.

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    At least one component is not listed.

    At least one component is not listed.

    Korea inventory (KECI)

    Philippines inventory

    (PICCS)

    6. Other information

    abel requirements DANGER !

    HARMFUL OR FATAL IF SWALLOWEDINHALATION CAUSES HEADACHES, DIZZINESS, DROWSINESS AND NAUSEA AND MAYLEAD TO UNCONSCIOUSNESS.CAUSES EYE AND SKIN IRRITATION.

    MAY CAUSE RESPIRATORY TRACT IRRITATION.

    National Fire

    Protection

    Association (U.S.A.) Health 0

    1

    2Fire hazard

    Instability

    Specific hazard

    istory

    ate of previous issue

    repared by Product Stewardship

    otice to reader

    ll reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental informationontained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to theccuracy or completeness of the data and information in this data sheet.

    he data and advice given apply when the product is sold for the stated application or applications. You should not use the productther than for the stated application or applications without seeking advice from BP Group.

    is the users obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BProup shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, fromny failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product forupply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using theroduct is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected ofny hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that thisocument is the most current available. Alteration of this document is strictly prohibited.

    MIS Rating :

    Physical

    Hazard

    Flammability

    Health * 2

    1

    0

    XPersonal

    protection

    03/14/2013.

    12/21/2010.

    ate of issue

    Indicates information that has changed from previously issued version.

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