Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The...

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Chemistry Letters No. 12 December, 2001 CMTAG ISSN 0366-7022 Copyright © 2001 The Chemical Society of Japan 1204 Synthesis, Structure, and Reactions of the First Stable Aromatic S -Nitrosothiol Bearing a Novel Dendrimer-Type Steric Protection Group Kei Goto, Yoko Hino, Yusuke Takahashi, Takayuki Kawashima, Gaku Yamamoto, Nozomi Takagi, and Shigeru Nagase 1206 The First Stable Aromatic S-Nitrosothiol: Synthesis, Structure and Reactivity Maiko Itoh, Keiko Takenaka, Renji Okazaki, Nobuhiro Takeda, and Norihiro Tokitoh 1208 Dynamics of Silylenes in Polysilylenes with Structural Defects by Excimer Laser Flash Photolysis Shu Seki, Shou Tsuji, Yoshinori Matsui, and Seiichi Tagawa 1210 Rhodium(I)-Catalyzed Acylation of Alkyne with Acylsilane: Transformation of 5- or 6-Alkynoylsilane to α-Alkylidene- cycloalkanone Motoki Yamane, Takuma Amemiya, and Koichi Narasaka

Transcript of Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The...

Page 1: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

Chemistry LettersNo. 12December, 2001

CMTAGISSN 0366-7022

Copyright © 2001 The Chemical Society of Japan

1204 Synthesis, Structure, and Reactions of theFirst Stable Aromatic S-NitrosothiolBearing a Novel Dendrimer-Type StericProtection Group

Kei Goto, Yoko Hino, Yusuke Takahashi,Takayuki Kawashima, Gaku Yamamoto,Nozomi Takagi, and Shigeru Nagase

1206 The First Stable Aromatic S-Nitrosothiol:Synthesis, Structure and Reactivity

Maiko Itoh, Keiko Takenaka, Renji Okazaki,Nobuhiro Takeda, and Norihiro Tokitoh

1208 Dynamics of Silylenes in Polysilylenes withStructural Defects by Excimer Laser FlashPhotolysis

Shu Seki, Shou Tsuji, Yoshinori Matsui, andSeiichi Tagawa

1210 Rhodium(I)-Catalyzed Acylation ofAlkyne with Acylsilane: Transformationof 5- or 6-Alkynoylsilane to α-Alkylidene-cycloalkanone

Motoki Yamane, Takuma Amemiya, andKoichi Narasaka

Page 2: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

C-154 Chemistry Letters No. 12 2001

Copyright © 2001 The Chemical Society of Japan

1212 Selective Si–Si Bond Cleavage ofDecaisopropylbicyclo[2.2.0]hexasilanewith Hydrobromic Acid and HydrochloricAcid

Akira Meguro, Haruaki Sakurai, Kei Kato,Soichiro Kyushin, and Hideyuki Matsumoto

1214 Synthesis and Transfection Capability ofMulti-Functionalized Fullerene Polyamine

Hiroyuki Isobe, Naoki Tomita, Shigeki Jinno,Hiroto Okayama, and Eiichi Nakamura

1216 Boron–Metal Exchange Reaction ofSilylboranes with OrganometallicReagents: A New Route to ArylsilylAnions

Atsushi Kawachi, Takashi Minamimoto, andKohei Tamao

1218 A New Screw-Sense Switchable Polysilylenewith Quantized and Superposed Helicities

Michiya Fujiki, Masao Motonaga, Hong-ZhiTang, Keiichi Torimitsu, Zhong-Biao Zhang,Julian R. Koe, Junji Watanabe, Ken Terao,Takahiro Sato, and Akio Teramoto

1220 Novel Photocycloaddition of AromaticKetones to Cyclic Oligosilanes

Masahiro Kako, Mei Gu, Yohei Takenaka,Kentaro Takagi, Kazuhiro Kondo, YasuhiroNakadaira, Masanobu Wakasa, and HisaharuHayashi

Page 3: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

Chemistry Letters No. 12 2001 C-155

Copyright © 2001 The Chemical Society of Japan

1222 Can Cp2Zr(C2H4) Easily React withHydrosilane? A Theoretical Study

Shigeyoshi Sakaki, Tatsunori Takayama, andManabu Sugimoto

1224 UV Absorption and FluorescenceProperties of Pyrene Derivatives HavingTrimethylsilyl, Trimethylgermyl, andTrimethylstannyl Groups

Hajime Maeda, Yohtaro Inoue, HidekiIshida, and Kazuhiko Mizuno

1226 Preparation of Organoytterbium Reagentfrom Ytterbium Trichloride and Organo-magnesium

Seijiro Matsubara, Takanori Ikeda, KoichiroOshima, and Kiitiro Utimoto

1228 Synthesis of Bromohydrosilanes:Reactions of Hydrosilanes with CuBr2 inthe Presence of CuI

Atsutaka Kunai, Takahiko Ochi, ArihiroIwata, and Joji Ohshita

1230 Copper(I) Chelate Complexes with Novelπ-Conjugated 1,2-Bis(2-pyridylethynyl)-benzene Ligands: Synthesis, Structure,and Reactivity

Tomikazu Kawano, Jun Kuwana, TatsujiShinomaru, Chong-Xu Du, and Ikuo Ueda

Page 4: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

C-156 Chemistry Letters No. 12 2001

Copyright © 2001 The Chemical Society of Japan

1232 Orientation of Rotational Isomers of 1,2-Bis(2-anthryl)ethene in Liquid Crystals

Takashi Karatsu, Yuuki Tanaka, MasanoriImakawa, Keijiro Fukui, and AkihideKitamura

1234 A Dimeric Mixed-Anions Lead(II)Complex: Synthesis and StructuralCharacterization of [Pb2(BTZ)4(NO3)-(H2O)](ClO4)3 {BTZ = 4,4'–Bithiazole}

Ali Reza Mahjoub and Ali Morsali

1236 Conformational Change Forced byCesium Ion Complexation in CrystalViolet Derivative Possessing Tris(mono-aza-15-crown-5) Structure

Ryoko M. Uda, Masatoshi Oue, and KeiichiKimura

1238 Resonance Raman SpectroscopicDetection of Pyridylazo Complex Formedat Liquid–Liquid Interface in CentrifugalLiquid Membrane System

Akira Ohashi and Hitoshi Watarai

1240 CD Investigation of Porphyrin–PorphyrinInteraction with Links to Acyclic β-SheetPeptide Self-Assembled in an AqueousMedia

Toru Arai, Makiko Inudo, TomomiIshimatsu, Tomikazu Sasaki, Tamaki Kato,and Norikazu Nishino

Page 5: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

Chemistry Letters No. 12 2001 C-157

Copyright © 2001 The Chemical Society of Japan

1242 General and Greener Route to Ketones byPalladium-Catalyzed Direct Conversion ofCarboxylic Acids with OrganoboronicAcids

Ryuki Kakino, Hirohisa Narahashi, IsaoShimizu, and Akio Yamamoto

1244 Synthesis of PPV-Based ConjugatedOligomer Containing Tropone in MainChain

Koji Takagi, Yukimi Nishikawa, HideoKunisada, and Yasuo Yuki

1246 Preparation of Fine Sr2CeO4 Particles fora Blue Phosphor

Takanobu Chiga, Toshiyuki Masui, NobuhitoImanaka, and Gin-ya Adachi

1248 Formation Mechanism of Peroxides inReactions of Cyclic Olefins with Ozone inAir

Shiro Hatakeyama, Subramanian Sivanesan,and Taichiro Urabe

1250 Dynamics of Water Molecules inMicropores of AlPO4-5 and SAPO-5Studied by 1H NMR

Kazuma Gotoh, Shin’ichi Ishimaru, andRyuichi Ikeda

Page 6: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

C-158 Chemistry Letters No. 12 2001

Copyright © 2001 The Chemical Society of Japan

1252 Enhanced Molecular-Shape Selectivity forPolyaromatic Hydrocarbons throughIsotropic-to-Crystalline Phase Transitionof Poly(octadecyl acrylate)

Hirotaka Ihara, Yoshihiro Goto, ToshihikoSakurai, Makoto Takafuji, Takashi Sagawa,and Shoji Nagaoka

1254 Thermal and Pressure Induced SpinCrossover of a Novel Iron(III) Complexwith a Tripodal Ligand Involving ThreeImidazole Groups

Yukinari Sunatsuki, Masafumi Sakata,Susumu Matsuzaki, Naohide Matsumoto, andMasaaki Kojima

1256 Electrochemical Studies for Interactionbetween [Cu(salen)] and La(III) Ion inN,N-Dimethylformamide

Kazuhiro Manseki, Yuko Shimizu, AkikoObata, Hiroshi Sakiyama, Kei Unoura,Masatomi Sakamoto, Yuzo Nishida,Yoshihiko Sadaoka, and Hisashi O

–kawa

1258 Synthesis, Structure, and Reactions of aNovel Triarylsilanol with a Bowl-TypeFramework: A Silanol ExtremelyResistant to Self-Condensation

Kei Goto, Tomoko Okumura, and TakayukiKawashima

1260 Estimation of the Emission of VolatileOrganic Compounds (VOCs) in Tokyofrom Their Observed Increments of theAtmospheric Averaged Concentrationsabove the Background Concentrations

Takao Miyoshi and Yoshihiro Makide

Page 7: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

Chemistry Letters No. 12 2001 C-159

Copyright © 2001 The Chemical Society of Japan

1262 Unique Fluorescent Properties of 1-Aryl-3,4-diphenylpyrido[1,2-a]benzimidazoles

Keisuke Hirano, Yoji Oderaotoshi, SatoshiMinakata, and Mitsuo Komatsu

1264 The First [5]Supercyclodextrin WhoseCyclopentameric Array Is Held Only by aMechanical Bond

Takahiro Kaneda, Takashi Yamada,Tatsuhiko Fujimoto, and Yoshiteru Sakata

1266 Porphyrin Polygons: A New SyntheticStrategy for Cyclic Porphyrin OligomersUtilizing a Porphyrin Double DeckerStructure

Masato Ikeda, Atsushi Sugasaki, YoheiKubo, Kazunori Sugiyasu, MasayukiTakeuchi, and Seiji Shinkai

1268 Alignment Behavior of Discotic Nematicand Rectangular Columnar Phases onSelf-Assembled Monolayers of Alkanethioland Asymmetrical Disulfide

Hirosato Monobe, Hiroaki Azehara, YoShimizu, and Masamichi Fujihira

1270 A 3-Volt Lithium-Ion Cell withLi[Ni1/2Mn3/2]O4 and Li[Li1/3Ti5/3]O4 : AMethod to Prepare Stable Positive-Electrode Material of Highly CrystallizedLi[Ni1/2Mn3/2]O4

Tsutomu Ohzuku, Kingo Ariyoshi, SatoshiYamamoto, and Yoshinari Makimura

Page 8: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

C-160 Chemistry Letters No. 12 2001

Copyright © 2001 The Chemical Society of Japan

1272 Origin of Microporosity of AmmoniumDodecatungstophosphate Unveiled bySingle Crystal Structure Analysis

Takeru Ito, Masato Hashimoto, SayakaUchida, and Noritaka Mizuno

1274 Spindle-Type EuO Nanocrystals and TheirMagnetic Properties

Supitcha Thongchant, Yasuchika Hasegawa,Yuji Wada, and Shozo Yanagida

1276 Reaction Propagation over a RingElectrode during Self-Sustained CurrentOscillations in the Fe/H2SO4 System

Yuka Shiomi, Antonis Karantonis, andSeiichiro Nakabayashi

1278 Synthesis, Characterization and CrystalStructure of the Water-Soluble, All-Inorganic Composition, A,β-Keggin Tri-niobium(V)-Substituted Polyoxotungstate

Kenji Nomiya, Takeshi Hasegawa, RyusukeNoguchi, Kei-ichi Nomura, MizutoTakahashi, and Hironari Yokoyama

1280 Microporous Structure of Titanium OxidePrepared by a Salt Catalytic Sol–GelProcess

Kazuhiko Tanaka, Yasushi Murakami,Tomohito Imai, Taki Matsumoto, ShinsukeFuruno, Wataru Sugimoto, and YoshioTakasu

Page 9: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

Chemistry Letters No. 12 2001 C-161

Copyright © 2001 The Chemical Society of Japan

1282 Selective Synthesis of Methanol fromCO+H2 over Pd Sulfide in the Presence ofH2S

Naoto Koizumi, Akihiro Miyazawa, TakuroFurukawa, and Muneyoshi Yamada

1284 Preferential Bond Activation of sp3 C–Hover sp2 C–H in α ,β-UnsaturatedCarboxylic Acids by Ruthenium Complex

Susumu Kanaya, Nobuyuki Komine,Masafumi Hirano, and Sanshiro Komiya

1286 Regioselective Photohydroxylation ofQuinolinium Ions in Smectite ClayInterlayers

Hisanao Usami, Yoshiaki Shimizu, HitoshiFujimatsu, and Takashi Iijima

1288 Palladium-Catalyzed ReductiveDimerizations of Highly FunctionalizedAllenes

Chang Ho Oh, Hee Sang Yoo, and SeungHyun Jung

1290 Palladium-Catalyzed Cyclizations of 1,6-Dienes in the Presence of Lewis Acids

Chang Ho Oh, Jung Duk Kim, and Je WookHan

Page 10: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

C-162 Chemistry Letters No. 12 2001

Copyright © 2001 The Chemical Society of Japan

1292 Thermal Stability of Alumina ModifiedSilica Fiber

Akira Hasegawa

1294 Hydrothermal Synthesis andCharacterization of SnS2 Nanocrystals

Chunrui Wang, Kaibin Tang, Qing Yang,Yitai Qian, and Cunyi Xu

1296 Structure of the First Tetranuclear Ni(II)Complex Derived from N-(2-hydroxy-benzylidene)-4,6-O-ethylidene-β-D-gluco-pyranosylamine

Ajay K. Sah, Chebrolu P. Rao, Pauli K.Saarenketo, and Kari Rissanen

1298 Potentiometric SCN– Selectivity of PolymerMembranes with Fixed OrganotinCompounds

Takayo Moriuchi-Kawakami, Hiroshi Aoto,Keiichi Fujimori, and Yasuhiko Shibutani

1300 White Light Optical Waveguide Detectionof Transient Absorption Spectra inUltrathin Organic Films upon PulsedLaser Excitation

Hideki Kawai, Kazuhiro Nakano, andToshihiko Nagamura

Page 11: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

Chemistry Letters No. 12 2001 C-163

Copyright © 2001 The Chemical Society of Japan

1302 High Sensitive and Prompt Discriminationof Luminescent Europium ß-DiketonatesUsing Electrospray Ionization MassSpectrometry

Shoji Kurata and Masatoshi Nagai

1304 Production of Acetic Acid Directly fromMethane and Carbon Dioxide UsingDielectric-Barrier Discharges

Chang-jun Liu, Yang Li, Yue-ping Zhang,Yu Wang, Jijun Zou, Baldur Eliasson, andBingzhang Xue

1306 Preparation of “Confetti” Particles byDipersion Copolymerization of Acrylo-nitrile/Styrene with Poly(ethylene glycol)Macromonomer

Ming-Qing Chen, Tatsuo Kaneko, Chun-HaoChen, and Mitsuru Akashi

1308 Synthesis of New PhotoresponsivePolymers Containing Trifluoromethyl-Substituted Norbornadiene Moieties

Takabumi Nagai, Miwa Shimada, andTadatomi Nishikubo

1310 Synthesis and Properties of Tetrathia-fulvalene-Substituted Ferrocenes

Masahiko Iyoda, Takahiro Takano, NaokiOtani, Kohei Ugawa, Masato Yoshida, HaruoMatsuyama, and Yoshiyuki Kuwatani

Page 12: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

C-164 Chemistry Letters No. 12 2001

Copyright © 2001 The Chemical Society of Japan

1312 Development of a Two-DimensionalEvaluation Method for Thin Layers UsingSurface Plasmon Resonance

Soichi Otsuki, Kensuke Murai, and SusumuYoshikawa

1314 Hydrogen Generation from Water withNonthermal Plasma

Hajime Kabashima, Hisahiro Einaga, andShigeru Futamura

1316 Tautomeric Equilibrium of Fluorescein inSolution: Ab Initio Calculations

Yun Hee Jang, Sungu Hwang, and Doo SooChung

1318 Synthesis of Carthamin Acetate, the RedPigment in Safflower Petals

Shingo Sato, Toshihiro Kumazawa, HiroyukiWatanabe, Koji Takayanagi, ShigeruMatsuba, Jun-ichi Onodera, Heitaro Obara,and Kimio Furuhata

1320 Electrochemical Behavior of Graphite-Lithium Intercalation Electrode in AlCl3-EMIC-LiCl-SOCl2 Room-TemperatureMolten Salt

Nobuyuki Koura, Keiko Etoh, YasushiIdemoto, and Futoshi Matsumoto

Surface profile of protein spots with various thickness on a silver film

Page 13: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

Chemistry Letters No. 12 2001 C-165

Copyright © 2001 The Chemical Society of Japan

1322 Preparation of Li4/3Ti5/3O4 Thin FilmAnode with High ElectrochemicalResponse for Rechargeable LithiumBatteries by Sol–Gel Method

Young Ho Rho, Kiyoshi Kanamura, andTakao Umegaki

1324 Enantioselective Radical Cross-CouplingReactions of Silyl Enol Ethers UsingChiral Oxovanadium

Masaaki Kurihara, Taeko Hayashi, andNaoki Miyata

1326 Synthesis and Crystal Structure of aChloro-Bridged Dinuclear Germanium(IV)Heterocoordinate Complex with 5,14-Dihydro-6,8,15,17-tetramethyldibenzo[b,i]-[1,4,8,11]tetraazacyclotetradecine

Xuan Shen, Kazunori Sakata, and MamoruHashimoto

1328 Synthesis of Binuclear Ligands PossessingTwo Discrete Multidentate N-HeterocyclicPodand Coordination Sites and TheirBimetallic Nickel(II) Complexes

Toshiyuki Moriuchi, Isao Nakayama,Kouichirou Nishimura, Masahito Nishiyama,Eiko Mochizuki, Yasushi Kai, and ToshikazuHirao

1330 Chiral Recognition by Multicenter SingleProton Hydrogen Bonding of Trifluoro-lactates

Toshimasa Katagiri and Kenji Uneyama

Page 14: Chemistry Letters · 2013-02-05 · C-154 Chemistry Letters No. 12 2001 Copyright © 2001 The Chemical Society of Japan 1212 Selective Si–Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane

C-166 Chemistry Letters No. 12 2001

Copyright © 2001 The Chemical Society of Japan

1332 Preparation of High Activity Catalyst forAmmonia Synthesis by Supporting Well-Defined Ru Nanoparticles on γ-Al2O3

Akane Miyazaki, Ioan Balint, Ken-ichi Aika,and Yoshio Nakano

1334 An Efficient Method for the Preparation ofVicinal Tertiary Diamines by ReductiveCoupling of Aminoacetals Mediated byLow Valent Titanium Iodide Species

Naritoshi Yoshimura and Teruaki Mukaiyama