ChemInform Abstract: Stereoselective Synthesis of (-)-Swainsonine (XI) and 1,2-Di-epi-Swainsonine...

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2000 alkaloids alkaloids U 0600 17 - 209 Stereoselective Synthesis of (-)-Swainsonine (XI) and 1,2-Di-epi- Swainsonine (IX) from γ-Hydroxy-α,β-unsaturated Sulfones. Interestingly, it is found that the stereoselectivity of the dihydroxylation of unsaturated indolizidines strongly depends on substitution at C-8. — (DE VICENTE, JAVIER; GOMEZ ARRAYAS, RAMON; CANADA, JAVIER; CARRETERO, JUAN CARLOS; Synlett (2000) 1, 53-56; Dep. Quim. Org., Fac. Cienc., Univ. Auton., Cantoblanco, E-28049 Madrid, Spain; EN) 1

Transcript of ChemInform Abstract: Stereoselective Synthesis of (-)-Swainsonine (XI) and 1,2-Di-epi-Swainsonine...

Page 1: ChemInform Abstract: Stereoselective Synthesis of (-)-Swainsonine (XI) and 1,2-Di-epi-Swainsonine (IX) from γ-Hydroxy-α,β-unsaturated Sulfones.

2000 alkaloids

alkaloidsU 0600

17 - 209Stereoselective Synthesis of (-)-Swainsonine (XI) and 1,2-Di-epi-Swainsonine (IX) from γ-Hydroxy-α,β-unsaturated Sulfones. —Interestingly, it is found that the stereoselectivity of the dihydroxylation ofunsaturated indolizidines strongly depends on substitution at C-8. — (DEVICENTE, JAVIER; GOMEZ ARRAYAS, RAMON; CANADA, JAVIER;CARRETERO, JUAN CARLOS; Synlett (2000) 1, 53-56; Dep. Quim. Org.,Fac. Cienc., Univ. Auton., Cantoblanco, E-28049 Madrid, Spain; EN)

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