방열소재및방열접착 기술시장동향...
Transcript of 방열소재및방열접착 기술시장동향...
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Chapter 1 .5
Chapter 2 , .19
Chapter 3 29
Chapter 4 39
Chapter 5 49
Chapter 6 59
Chapter 7 71
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2013 5 30
2013 6 1
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| 051-831-0761
| 051-831-0762
ISBN | 978-89-294-0296-9 93500
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Chapter 1
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.
, , ,
.
.
.
.
(heat sink)
07
.
,
, , , .
,
,
.
LED
. LED
85%
LED .
10 2 .
high power LED ,
.
06
1 LED
-
,
. ,
.
Aron Kasei
.
.
, 500
. ,
. , Aron
Kasei 1,000
.
Aron Kasei
0.2
6 . , 2
.
. LED ,
.
09
.
.
0.5
6 ,
.
()
.
. ,
.
.
, Aron Kasei
,
.
.
.
.
08
-
. Eresabu ,
, , .
ES1000 Polyphenylene sulfide(PPS) ,
.
,
. EN6017 PA
, , , , ULV-0(2mmt)
.
, . EN6017
,
LED . , PPS
X1104 (
). EN6025 PA , ,
Eresabu
.
, .
EN6025 , ,
.
EN6025
, LED
.
/
.
,
/ .
,
.
011
LED(Light Emitting Diode)
. ,
, ,
,
.
(Heat sink) ,
, /
. Starlight Industrial
Co., Ltd.
Esubea (Compound technology)
Eresabu
.
,
(BN) (Filler) ,
.
,
, , ,
.
Starlight Industrial Co., Ltd. Eresabu
,
. ,
,
010
-
. phonon
. Phonon scattering
phonon-phonon scattering, boundary
scattering, defect or impurity scattering .
Boundary scattering
013
,
.
,
, ,
.
.
Starlight Industrial Co., Ltd.
,
.
(0.1~0.2W/m.K) 10 (2~3W/m.K)
, ( 0.8) . ,
(100~200W/mK) .
,
, .
2
.
LED ,
.
.
.
. Phonon ,
012
2
Material Thermal Conductivity (W/mK)
Beryllium oxide 260
Aluminium niride 320
Silicon carbide 270
Alumina 24-35
Air at 0C 0.025
Glass 0.8
Water 0.6
Ice 1.6
Grease Fiber-reinforced, Plastic 0.23-1.06
Diamond 2000
Polyethylene HD 0.5
Styroform 0.01
Thermal grease, Ag based 2~3
Aluminium 237
Gold 315
Gopper 386
Metal Lead 35
Steinless Steel 16.3
SS316 14-16
Silver 406, 418, 429
Steel 50.2
Pb-Sn 50
SolderSn-Ag-Gu 55
Sn-Zn-Al 66
Sn-Bi-Ag 21
Paste Clear paste(Silicone, epoxy) ~0.2
-
bimodal
wetting
.
.
Thermal Interface Materials(TIM)
.
.
.
1.27~1.5 .
TIM TIM
.
BLT kTIM A
. RC1, RC2 TIM .
, ,
.
015
scattering ,
acoustic mismatch, defect . Scattering
phonon .
.
scattering
phonon
.
phonon .
.
. ,
FCC
. ,
phonon scattering
.
0.1~0.3 W/m.K
.
.
.
.
.
014
-
.
,
.
.
.
. .
,
.
.
.
.
.
,
.
. 100 psi 6090 shore A
,
.
,
.
017
Reffecive .
TIM .
.
. TIM ,
, , .
TIM .
.
, ,
.
0.03W/mK ,
016
3
Material 1
Material 2
-
,
.
.
. ,
,
.
.
24 W/m.K .
50 5 psi
.
.
018
Chapter 2
-
.
.
Kumlutas PE Al
, Mamunya PVC epoxy Cu Ni
021
, .
. heat
sink 1~30W/mK
, ,
.
/
.
Al, Ag, Cu, Ni .
Paris Boudenne PP 2
Cu
(, ).
Cu 20% ()
, percolation threshold
, 20% ()
020
4 PP/Cu
5 PP/Cu
-
ZnO nano-pyramidal double
percolation
( 7(a)).
Zhi
, BN nanotube (BNNT) BN nanosphere (BNNS)
. Golberg BN nanotube
Poly(vinyl alcohol) (PVA)
electrospinning , BNNT
023
.
.
. AlN, Al2O3,
BN, SiC, BeO
.
,
, , .
Ohashi
flake AlN AlN
. AlN 74 vol%
8.2 W/m.K .
AlN Al2O3
.
Zhou BN HDPE
powder mixing melt mixing ,
. powder mixing
melt mixing
.
,
. Ando 2
022
6 (a) HDPE/BN , (b) Powder mixing HDPE/BN SEM (BN 35 vol%.), (c) Meltmixing HDPE/BN SEM (BN 35 vol%.).
-
melt < roll milled < solution < powder mixture
.
Examples of High Thermal Conductivity Polymer Composites
025
. ,
Nishino PVA
()
Tanaka
, .
, .
.
Coupling agent .
.
024
7 (a) Polyimide blend/ZnO , (b) BNNT/BNNS ,(c) Electrospinning PVA/BNNT , (d) PVA/nano-diamond .
-
.
. 0.35 nm
100 2
.
,
.
, .
. National Tsing Hua Ma
-stacking
(). 4 phr
10 , MWCNT
5 .
Balandin epoxy
10 vol% 5.2 W/m.K
.
2 vol% 5.8 W/m.K 14
W/m.K ().
, , /
.
027
(graphite), (carbon nanotube),
(carbon fiber), (graphene)
. ,
, ,
. Expanded graphite(EG)
20~100 nm
,
EG , ,
. 3,000 W/m.K
. TIM
.
Biercuk
.
1wt% 40 K 70%
, 125%
. Liu
.
,
3.8 wt% 65% .
. CNT
.
026
-
.
Chapter 3
028
8 (a) (b)
9 , (1~10)
GraphiteGraphite oxide
Thermal reductionH2SO4/NHO3
GraphenePy-PGMA-GrapheneThe reactive oxirane ring
(a)
-
.
.
CEMEDINE
SX720, SX1007 SX1010 SX1000,
() , . SX720
1.0W/mK , SX1000
2W/mK .
. SX1007
UL94V-0 . SX720, SX1000
-40~130. 150
. SUPER X
. -30 130
1,000 .
(sheet)/(grease)
.
.
.
. , ,
.
, .
CEMEDINE FPD(plate panel
display) PC
(pick up) .
UL94V-0 .
031
.
PC
/
.
,
.
.
CEMEDINE CO. SUPER X()
. (siloxane)
/
. SUPER X
3 .
(materials) .
.
(body) .
.
. (air void)
030
-
:
.
: .
:
.
: , ( ; UL1950)
.
.
IC
.
(, , ), ()
.
.
.
, ,
.
,
.
.
.
033
. 2
.
. ,
.
(, )
() . ,
(IC)
IC
. ()
.
.
IC
.
, .
. ,
CPU
. ( )
4 .
032
-
.
.
,
(Tg)
.
.
.
180
Tg
.
.
.
, , ,
.
.
.
() .
035
() 270W/mK
.
,
.
.
:
.
( ) .
(tap density) .
:
.
.
.
.
(Mitsui Chemical)
, ,
.
.
034
-
.
.
.
. ,
.
,
, , .
,
.
, , ,
.
.
, .
,
.
.
.
036
.
.
, .
.
, ,
.
, CPU
,
.
, .
.
.
,
.
(paint protection against
heat) .
.
037
-
(design)
.
() .
.
.
10 90%
. Haze 5% .
Alumite .
, . , ,
. ,
(160) .
.
(excited state) .
()
.
,
LED .
.
. LED
. ,
.
.
038
Chapter 4
-
.
LED .
,
, ,
. LED
. LED
.
LED
. LED
. LED
.
. LED ,
, , X-,
. LED
041
LED
. LED
. (LED)
SMD .
(mold) LED .
(Surface Mount Device) (PCB)
. SMD LED
.
LED
LED , , ,
. LED
p-n
040
10 SMD LED (a) LED (b)
-
.
55%
, 19%
. LED
. LED
. LED LED
.
043
.
, , , LED
.
LED . LED
LED
. LED
, , , TEC ,
heat sink slug .
heat sink .
LED
LED ,
.
042
11 LED (Heat Sink)
12
13 LED
-
LED
. epi-up (non-flip chip)
epi-down (flip chip)
Au
. ()
.
.
045
,
LED
.
. .
LED PCB
. /
.
3D
HDI-Via Thin insulator
filler
Package on Package .
. chip
delamination
. / TIM(Thermal
Interface Material) .
LED LED
. LED
4 .
044
14
Sheet casting Sheet casting Printing
Coating Stacking Cutting
Firing Breaking
-
.
PPA 6
LED .
LED .
LTCC(Low Temp. Cofired
Ceramic)
thermal via
. PCB
.
.
LED
.
, ,
.
LED .
.
.
. LED
.
LED
. LED ,
( , , ), .
LED .
047
.
(Ag paste)
chip on board
. .
.
.
.
PPA
046
15 LED ( )
16 LED ()
-
LED(Light Emitting Diode, )
LED LED
. LED
, , (),
, ()
, .
LED LED , LED , LED
, LED . LED
LED /
. LED LED
1 .
LED
(Wafer) (Epitaxy) ,
(Fabrication), LED
, LED
(Packaging) ,
.
LED LED
049
JEDEC 51-2 .
LED
.
LED LED
. LED
DC . LED
AC LED .
AC LED LED
LED .
LED
.
LED .
LED
.
.
048
17
18 LED
-
Chapter 5
.
(Sapphire), GaN, SiC, GaAs
SiC
. (MOCVD)
.
LED LED
. LED
,
, ,
. LED
(lead) PCB .
050
19 LED
[] [Wafer] [Epi-Wafer] [LED Chip] [Package] [Module]
/ MOCVD Reaction Slicing/Dicing Packaging
Sapphire, GaN,SiC, SI, GaAs
(In, Al) GaN(, , UV),InAlGap(, ), AlGaAs(,IR)
Standard, S/V, H/OPKG, Array PKG
-
, Elastmer
,
, (W/mK)
. CoolPolymer LCP,
PA46, PC, PPS
, Teijin Rapeama
, ,
.
,
5W
. Elastomer
.
,
. , DAF(Die Attach Film)
, 70% ,
2 W/mK 50 um
. LED
,
2W/mK , 0.5 mm ~ 2.0 mm
.
,
, DAF
, 1 W/mK
. LED
053
,
, .
, PCB
Thermal Via
.
Thermagon, Denka TT Electronics
, Laird Tech(), Berquist()
2~5 W/mK
.
,
,
. 2 W/m.K CCL(Copper Clad
Laminate)
.
052
-
,
,
. PCB
.
LED
,
, LED
LED
, PCB
.
,
,
.
.
LCD, PDP, LED
, PDA IT
,
. MSM(Mobile
Solution Module) , Full
80 .
Heat Sink
(Hot spot)
.
,
.
055
LED
. ,
1~2 W/mK
.
,
, , ,
.
, , Microwave
Ferromagnetic Resonance ,
ABS,
.
,
,
.
LED
. , LED 85%
(Junction) LED
.
High Power LED
054
-
PCB
.
, ,
.
. 10 W/mK
, ,
2 W/mK ~5 W/mK ,
.
, , /
.
, ,
. , 8 W/mK
.
CCL ,
,
.
,
057
/ 2014
/
.
. ,
,
.
IC, ,
.
.
LED TV
,
.
,
.
,
.
mzrp LED
.
.
LED .
056
-
Chapter 6
.
.
.
,
10% .
LED PCB
,
50% .
.
058
/ (%) ()
CCL / 60 4
Cool Polymer 20 3
DAF 60 4
LED 50 3
LED 50 3
40 3
Dow Corning 60 4
-
LED
2012 TV LCD(Liquid Crystal
Display) , IT, LCD,
LCD . TV LCD
2
. IT LCD IT LCD
, , LED
. LCD
OLED ,
,
, .
LED LED
LED
.
LED .
LED
LED LED
.
LED .
.
LED LED
LED . LED
2016 .
061
LED
2012 LED 2,117, 1 3,466
. LED LCD
20% ,
11.6 %
. , 3/4
LED ,
0.9 % . 2020 LED
2012 46.1% 3,092, 1.6% 1
3,682 .
LED .
LED . LED
TV
.
,
LED . ,
.
060
-
. 2014 162
2015 153 . 2015
.
LED
( : )
LED
( : )
LED
20%~40% .
,
.
LED
.
2010 34 ,
2010 19 2015 14%
. LED 2010 11
2015 16 .
063
LED
2012 LED 33.2%
2,150 . SMD ( )
LED ,
. LED
. 2012 28.9%
58, 19.1% 393 .
YAG(Yttrium Aluminum Garnet)
. LED
2012 4.2%
500 , 3.2% 215
. LCD TV
.
LED
Strategies Unlimited(2011. 9) LED
2009 53 2010 TV
108% 112
. LED 2010 112 ,
2014 162 2015 153
. LED 2010 2 3,937
2015 9 2,000 .
2011 LED LED ,
, LED , LED
9.8% 123
062
2008 2009 2010 2011 2014 2015CAGR
(10~15)
LED 50.8 54 112 123 162 153 6.44%
: Strategies Unlimited(2011.9)
2008 2010 2012 2015CAGR
(10~15)
LED 8,275 23,937 54,600 92,000 30.9%
:(2011.8)
-
. LED
.
, LED TV
.
.
, 2009
700 ~ 800 2010 2,500 ~ 3,000 2
. LED BLU(Back
Light Unit), , , , TV
LCD(Liquid Crystal Display) BLU,
, .
PCB(Printed Circuit Board)
MCCL() Metal PCB, PCB
(Heat sink),
(Sheet) ,
065
PC ,
LED 4.1% .
LED
2010 7.8% 11 .
2011 5% 11.55 .
LED
10% .
LED LED
.
2010 LED, LG
, LED
2009 4 2010 2 .
LED 2010 2 3,937 2015 9
2,000 .
LED(Light Emitting Diode)
. LED TV
LED
. , LED
LED
.
, LED , , COB(Chip On Board)
064
20 LED
: CMRI
-
PCB MCCL
Metal PCB, PCB ,
.
LED , ,
2011 38.3% 4,219,
3.4 37 .
, , ,
(needs)
. 2012
.
, ,
22
(elastomer) 2 , (filler) ,
6
067
, Metal PCB ,
.
LED TV LED .
2009 LED TV LED LED
TV 2009 450 2010 1500
100% .
LED , , LED
LED
.
, LED
. LED
.
LED TV
. ,
. LED
, LED
066
21 LED
22 LED
: LED
:
-
2011 , 2010 8.0%
284 . 80%
. , , ,
. ,
, .
.
.
.
. ,
.
. .
()
. 2011 2010 5.0%
167. CPU , LED,
. , 1
. ,
, .
. ,
.
069
. , , (6
) (4 ) .
2011 2010 7.5% 3,051
. , . 2017
2011 38.3% 4,219 .
, ,
. , LED
(die bond)
.
,
,
. 2011
2010 37.5% 11. 2017
2011 3.4 37 .
2009 , 2011
LED 50% . LED
,
. 2011
, 2012 ,
.
(siloxane) ,
.
068
-
Chapter 7
()
. 2011 2010 11.4% 117
.
.
,
,
,
.
()
.
,
. 2011 2010 37.5% 11
. LED
. LED LED
.
,
, . ,
.
070
-
2012~2013
.
: 2012~2013
LED LED
.
60W
,
.
073
2013 LED
2013 LED
. LED
, , LED
.
2012 3 LED
24% , LED
Lighting Science Group
, 2012 3 40.4%
. Hubbell Acuity Brands
LED 16% 12% ,
Top tier Zumtobel LED
20% .
LED
LED .
072
2009 2010 2011 2012 2013 2014 2015 2016
100W
75W
40W 60W
100W
EU65W
60W
40W, 25W
, ,
100W ,
60W ,
15W,
CFL LED(USD) LEDvs LEDvs.CFL
(USD) (USD) Average Low High () ()
0.7 5.2 21 15 25 27.7 4.1
1.6 9.0 23 12 36 14.2 2.6
- 7.9 35 29 42 N/V 4.4
0.9 3.4 17 15 19 19.1 4.9
`1.2 4.7 16 10 23 13.3 3.3
1.1 5.3 22 10 42 20.0 4.2
: , KTB
: KTB
-
Zhaga
, 2014
. 2011
, 1 2012
.
LED . 2011
LED 6.8%, LED 0.6%
2015 LED
075
LED (Replacement Lamp)
LED (Luminaires) .
, , (Fixture)
LED , LED
LED . LED
LED
, Connectivity (Smart)
.
LED
. Zhaga
. Zhaga Osram, Philips
/LED ,
LED . 2010 2
, 2(Book 1, Book 2)
, Zhaga LED
.
LED
. LED ,
,
.
.
074
: KTB
Osram, Philips, Cree, 284 LED (Light Engine) LED
,
20102, , LED 9Zhaga "Book", Book1Book88Book2Book3
(Book) Book 1 - (Common definitions and generic interfaces.)Book 2 - - (65mm )
(A socketable light engine with integrated control gear - mainly used in downlight applications (65mmbase))
Book 3 - - (A round engine with separate control gear - used in spot lighting and other applications that need a pointlight source)
Book 4 - (A flat emitter streetlinght engine with separate control gear)
Book 5 - (A socketable light engine with separate electronic control gear)
Book 6 - (A compact socketable LED light engine with integrated electronic control gear)
Book 7 - (Several indoor light engines with separate electronic control gear)
Book 8 - - (85mm)(A socketable light engine with intearated control gear - mainly used in downlight applications ( 85mmbase))
Light Engine LED , , LED, ,
-
2012 4.9%, 2013 8.1% ,
2020 54.5%
.
, LED 2001~2005 ,
2009~2011 LCD TV IT LED
. IT
IT
,
.
LED
LED LED,
, , , , ,
LED 80%
. 2010 28%
077
35.9%, 7.3% . /
LED
.
2013 LED 7% 78
LED (Fixture ) ,
53% , 2020 LED 46%,
LED 237 2012~2020
21.2% .
,
LED 2012 12.1%, 2013 20.3%
, 2020 67% .
LEd 2012 1.2%
, LED 2013 2.3%
.
LED
076
23 LED ( + )
24 LED :
: , KTB
-
.
LED
LED, LG, , . LED
LED
. LED, LG
. 2010 LED
MOCVD(Metal Organic Chemical Vapor Deposition)
LED 150, LG 145, 100
. LCD TV LED BLU
. ,
LED 5% .
LED LED
.
1993 LED , 1995
LED . LED
. , ,
, LED
.
,
.
079
10% ,
LED TV LED
LG . ,
LED .
Strategies Unlimited(2011.7) , 2010 LED
Nichia
LED 21.3% 1
LED 11.5% 2, Osram 8.7% 3
, 7.5% 4 .
, , ,
.
, , , ,
.
, , ,
, .
, , , ,
078
25 LED :
: Strategies Unlimited(2011. 7)
-
081
080
1. 3, , ,
2012.
2. , , , ReSEAT, 2012.
3. , , , ReSEAT, 2012.
4. , , , ReSEAT, 2012.
5. , LED , , 2008.
6. , _ , 2010.
7. 1, 2013 LED !, ktb , 2013.
8. , LED , KISTI KARKET REPORT, 2013.
9. , LED , KISTI KMR, 2012.
10. Business Information Research, , , 2011.
11. mirian.kisti.re.kr()
12. mirian.kisti.re.kr()
13. www.reseat.re.kr
14. www.chemlocus.co.kr
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17. J. Park, M.W. Shin, and C.C. Lee, Optics Letters 29, No.22 (2004).
18. Lan Kim and Moo Whan Shin, IEEE Trans. Component and Packaging
Technology 30, No. 4 (2007).
19. Lan Kim, Jong Hwa Choi, Sun Ho Jang, and Moo Whan Shin,
Thermochimica Acta. 455, 21 (2007).
20. Lianqiao Yang, Jianzheng Hu, Lan Kim and Moo Whan Shin, Phys.
Stat. Sol. (c) 3, 2187 (2006).
21. Lianqiao Yang, Jianzheng Hu, and Moo Whan Shin, Solid State
Phenomena 124-126, 483-486 (2007).
22. Lianqiao Yang, Jianzheng Hu and Moo Whan Shin, IEEE Electron
Device Letters 29, No.8 (2008).
/
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R&D
IPC (US Patent ) R&D
082