방열소재및방열접착 기술시장동향...

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  • Chapter 1 .5

    Chapter 2 , .19

    Chapter 3 29

    Chapter 4 39

    Chapter 5 49

    Chapter 6 59

    Chapter 7 71

    80

    . / 81

    2013 5 30

    2013 6 1

    |

    |

    |

    | () 66

    | () 245

    | 051-831-0761

    | 051-831-0762

    ISBN | 978-89-294-0296-9 93500

    ,

    .

    , .

  • .

    Chapter 1

  • .

    , , ,

    .

    .

    .

    .

    (heat sink)

    07

    .

    ,

    , , , .

    ,

    ,

    .

    LED

    . LED

    85%

    LED .

    10 2 .

    high power LED ,

    .

    06

    1 LED

  • ,

    . ,

    .

    Aron Kasei

    .

    .

    , 500

    . ,

    . , Aron

    Kasei 1,000

    .

    Aron Kasei

    0.2

    6 . , 2

    .

    . LED ,

    .

    09

    .

    .

    0.5

    6 ,

    .

    ()

    .

    . ,

    .

    .

    , Aron Kasei

    ,

    .

    .

    .

    .

    08

  • . Eresabu ,

    , , .

    ES1000 Polyphenylene sulfide(PPS) ,

    .

    ,

    . EN6017 PA

    , , , , ULV-0(2mmt)

    .

    , . EN6017

    ,

    LED . , PPS

    X1104 (

    ). EN6025 PA , ,

    Eresabu

    .

    , .

    EN6025 , ,

    .

    EN6025

    , LED

    .

    /

    .

    ,

    / .

    ,

    .

    011

    LED(Light Emitting Diode)

    . ,

    , ,

    ,

    .

    (Heat sink) ,

    , /

    . Starlight Industrial

    Co., Ltd.

    Esubea (Compound technology)

    Eresabu

    .

    ,

    (BN) (Filler) ,

    .

    ,

    , , ,

    .

    Starlight Industrial Co., Ltd. Eresabu

    ,

    . ,

    ,

    010

  • . phonon

    . Phonon scattering

    phonon-phonon scattering, boundary

    scattering, defect or impurity scattering .

    Boundary scattering

    013

    ,

    .

    ,

    , ,

    .

    .

    Starlight Industrial Co., Ltd.

    ,

    .

    (0.1~0.2W/m.K) 10 (2~3W/m.K)

    , ( 0.8) . ,

    (100~200W/mK) .

    ,

    , .

    2

    .

    LED ,

    .

    .

    .

    . Phonon ,

    012

    2

    Material Thermal Conductivity (W/mK)

    Beryllium oxide 260

    Aluminium niride 320

    Silicon carbide 270

    Alumina 24-35

    Air at 0C 0.025

    Glass 0.8

    Water 0.6

    Ice 1.6

    Grease Fiber-reinforced, Plastic 0.23-1.06

    Diamond 2000

    Polyethylene HD 0.5

    Styroform 0.01

    Thermal grease, Ag based 2~3

    Aluminium 237

    Gold 315

    Gopper 386

    Metal Lead 35

    Steinless Steel 16.3

    SS316 14-16

    Silver 406, 418, 429

    Steel 50.2

    Pb-Sn 50

    SolderSn-Ag-Gu 55

    Sn-Zn-Al 66

    Sn-Bi-Ag 21

    Paste Clear paste(Silicone, epoxy) ~0.2

  • bimodal

    wetting

    .

    .

    Thermal Interface Materials(TIM)

    .

    .

    .

    1.27~1.5 .

    TIM TIM

    .

    BLT kTIM A

    . RC1, RC2 TIM .

    , ,

    .

    015

    scattering ,

    acoustic mismatch, defect . Scattering

    phonon .

    .

    scattering

    phonon

    .

    phonon .

    .

    . ,

    FCC

    . ,

    phonon scattering

    .

    0.1~0.3 W/m.K

    .

    .

    .

    .

    .

    014

  • .

    ,

    .

    .

    .

    . .

    ,

    .

    .

    .

    .

    .

    ,

    .

    . 100 psi 6090 shore A

    ,

    .

    ,

    .

    017

    Reffecive .

    TIM .

    .

    . TIM ,

    , , .

    TIM .

    .

    , ,

    .

    0.03W/mK ,

    016

    3

    Material 1

    Material 2

  • ,

    .

    .

    . ,

    ,

    .

    .

    24 W/m.K .

    50 5 psi

    .

    .

    018

    Chapter 2

  • .

    .

    Kumlutas PE Al

    , Mamunya PVC epoxy Cu Ni

    021

    , .

    . heat

    sink 1~30W/mK

    , ,

    .

    /

    .

    Al, Ag, Cu, Ni .

    Paris Boudenne PP 2

    Cu

    (, ).

    Cu 20% ()

    , percolation threshold

    , 20% ()

    020

    4 PP/Cu

    5 PP/Cu

  • ZnO nano-pyramidal double

    percolation

    ( 7(a)).

    Zhi

    , BN nanotube (BNNT) BN nanosphere (BNNS)

    . Golberg BN nanotube

    Poly(vinyl alcohol) (PVA)

    electrospinning , BNNT

    023

    .

    .

    . AlN, Al2O3,

    BN, SiC, BeO

    .

    ,

    , , .

    Ohashi

    flake AlN AlN

    . AlN 74 vol%

    8.2 W/m.K .

    AlN Al2O3

    .

    Zhou BN HDPE

    powder mixing melt mixing ,

    . powder mixing

    melt mixing

    .

    ,

    . Ando 2

    022

    6 (a) HDPE/BN , (b) Powder mixing HDPE/BN SEM (BN 35 vol%.), (c) Meltmixing HDPE/BN SEM (BN 35 vol%.).

  • melt < roll milled < solution < powder mixture

    .

    Examples of High Thermal Conductivity Polymer Composites

    025

    . ,

    Nishino PVA

    ()

    Tanaka

    , .

    , .

    .

    Coupling agent .

    .

    024

    7 (a) Polyimide blend/ZnO , (b) BNNT/BNNS ,(c) Electrospinning PVA/BNNT , (d) PVA/nano-diamond .

  • .

    . 0.35 nm

    100 2

    .

    ,

    .

    , .

    . National Tsing Hua Ma

    -stacking

    (). 4 phr

    10 , MWCNT

    5 .

    Balandin epoxy

    10 vol% 5.2 W/m.K

    .

    2 vol% 5.8 W/m.K 14

    W/m.K ().

    , , /

    .

    027

    (graphite), (carbon nanotube),

    (carbon fiber), (graphene)

    . ,

    , ,

    . Expanded graphite(EG)

    20~100 nm

    ,

    EG , ,

    . 3,000 W/m.K

    . TIM

    .

    Biercuk

    .

    1wt% 40 K 70%

    , 125%

    . Liu

    .

    ,

    3.8 wt% 65% .

    . CNT

    .

    026

  • .

    Chapter 3

    028

    8 (a) (b)

    9 , (1~10)

    GraphiteGraphite oxide

    Thermal reductionH2SO4/NHO3

    GraphenePy-PGMA-GrapheneThe reactive oxirane ring

    (a)

  • .

    .

    CEMEDINE

    SX720, SX1007 SX1010 SX1000,

    () , . SX720

    1.0W/mK , SX1000

    2W/mK .

    . SX1007

    UL94V-0 . SX720, SX1000

    -40~130. 150

    . SUPER X

    . -30 130

    1,000 .

    (sheet)/(grease)

    .

    .

    .

    . , ,

    .

    , .

    CEMEDINE FPD(plate panel

    display) PC

    (pick up) .

    UL94V-0 .

    031

    .

    PC

    /

    .

    ,

    .

    .

    CEMEDINE CO. SUPER X()

    . (siloxane)

    /

    . SUPER X

    3 .

    (materials) .

    .

    (body) .

    .

    . (air void)

    030

  • :

    .

    : .

    :

    .

    : , ( ; UL1950)

    .

    .

    IC

    .

    (, , ), ()

    .

    .

    .

    , ,

    .

    ,

    .

    .

    .

    033

    . 2

    .

    . ,

    .

    (, )

    () . ,

    (IC)

    IC

    . ()

    .

    .

    IC

    .

    , .

    . ,

    CPU

    . ( )

    4 .

    032

  • .

    .

    ,

    (Tg)

    .

    .

    .

    180

    Tg

    .

    .

    .

    , , ,

    .

    .

    .

    () .

    035

    () 270W/mK

    .

    ,

    .

    .

    :

    .

    ( ) .

    (tap density) .

    :

    .

    .

    .

    .

    (Mitsui Chemical)

    , ,

    .

    .

    034

  • .

    .

    .

    . ,

    .

    ,

    , , .

    ,

    .

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    .

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    ,

    .

    .

    .

    036

    .

    .

    , .

    .

    , ,

    .

    , CPU

    ,

    .

    , .

    .

    .

    ,

    .

    (paint protection against

    heat) .

    .

    037

  • (design)

    .

    () .

    .

    .

    10 90%

    . Haze 5% .

    Alumite .

    , . , ,

    . ,

    (160) .

    .

    (excited state) .

    ()

    .

    ,

    LED .

    .

    . LED

    . ,

    .

    .

    038

    Chapter 4

  • .

    LED .

    ,

    , ,

    . LED

    . LED

    .

    LED

    . LED

    . LED

    .

    . LED ,

    , , X-,

    . LED

    041

    LED

    . LED

    . (LED)

    SMD .

    (mold) LED .

    (Surface Mount Device) (PCB)

    . SMD LED

    .

    LED

    LED , , ,

    . LED

    p-n

    040

    10 SMD LED (a) LED (b)

  • .

    55%

    , 19%

    . LED

    . LED

    . LED LED

    .

    043

    .

    , , , LED

    .

    LED . LED

    LED

    . LED

    , , , TEC ,

    heat sink slug .

    heat sink .

    LED

    LED ,

    .

    042

    11 LED (Heat Sink)

    12

    13 LED

  • LED

    . epi-up (non-flip chip)

    epi-down (flip chip)

    Au

    . ()

    .

    .

    045

    ,

    LED

    .

    . .

    LED PCB

    . /

    .

    3D

    HDI-Via Thin insulator

    filler

    Package on Package .

    . chip

    delamination

    . / TIM(Thermal

    Interface Material) .

    LED LED

    . LED

    4 .

    044

    14

    Sheet casting Sheet casting Printing

    Coating Stacking Cutting

    Firing Breaking

  • .

    PPA 6

    LED .

    LED .

    LTCC(Low Temp. Cofired

    Ceramic)

    thermal via

    . PCB

    .

    .

    LED

    .

    , ,

    .

    LED .

    .

    .

    . LED

    .

    LED

    . LED ,

    ( , , ), .

    LED .

    047

    .

    (Ag paste)

    chip on board

    . .

    .

    .

    .

    PPA

    046

    15 LED ( )

    16 LED ()

  • LED(Light Emitting Diode, )

    LED LED

    . LED

    , , (),

    , ()

    , .

    LED LED , LED , LED

    , LED . LED

    LED /

    . LED LED

    1 .

    LED

    (Wafer) (Epitaxy) ,

    (Fabrication), LED

    , LED

    (Packaging) ,

    .

    LED LED

    049

    JEDEC 51-2 .

    LED

    .

    LED LED

    . LED

    DC . LED

    AC LED .

    AC LED LED

    LED .

    LED

    .

    LED .

    LED

    .

    .

    048

    17

    18 LED

  • Chapter 5

    .

    (Sapphire), GaN, SiC, GaAs

    SiC

    . (MOCVD)

    .

    LED LED

    . LED

    ,

    , ,

    . LED

    (lead) PCB .

    050

    19 LED

    [] [Wafer] [Epi-Wafer] [LED Chip] [Package] [Module]

    / MOCVD Reaction Slicing/Dicing Packaging

    Sapphire, GaN,SiC, SI, GaAs

    (In, Al) GaN(, , UV),InAlGap(, ), AlGaAs(,IR)

    Standard, S/V, H/OPKG, Array PKG

  • , Elastmer

    ,

    , (W/mK)

    . CoolPolymer LCP,

    PA46, PC, PPS

    , Teijin Rapeama

    , ,

    .

    ,

    5W

    . Elastomer

    .

    ,

    . , DAF(Die Attach Film)

    , 70% ,

    2 W/mK 50 um

    . LED

    ,

    2W/mK , 0.5 mm ~ 2.0 mm

    .

    ,

    , DAF

    , 1 W/mK

    . LED

    053

    ,

    , .

    , PCB

    Thermal Via

    .

    Thermagon, Denka TT Electronics

    , Laird Tech(), Berquist()

    2~5 W/mK

    .

    ,

    ,

    . 2 W/m.K CCL(Copper Clad

    Laminate)

    .

    052

  • ,

    ,

    . PCB

    .

    LED

    ,

    , LED

    LED

    , PCB

    .

    ,

    ,

    .

    .

    LCD, PDP, LED

    , PDA IT

    ,

    . MSM(Mobile

    Solution Module) , Full

    80 .

    Heat Sink

    (Hot spot)

    .

    ,

    .

    055

    LED

    . ,

    1~2 W/mK

    .

    ,

    , , ,

    .

    , , Microwave

    Ferromagnetic Resonance ,

    ABS,

    .

    ,

    ,

    .

    LED

    . , LED 85%

    (Junction) LED

    .

    High Power LED

    054

  • PCB

    .

    , ,

    .

    . 10 W/mK

    , ,

    2 W/mK ~5 W/mK ,

    .

    , , /

    .

    , ,

    . , 8 W/mK

    .

    CCL ,

    ,

    .

    ,

    057

    / 2014

    /

    .

    . ,

    ,

    .

    IC, ,

    .

    .

    LED TV

    ,

    .

    ,

    .

    ,

    .

    mzrp LED

    .

    .

    LED .

    056

  • Chapter 6

    .

    .

    .

    ,

    10% .

    LED PCB

    ,

    50% .

    .

    058

    / (%) ()

    CCL / 60 4

    Cool Polymer 20 3

    DAF 60 4

    LED 50 3

    LED 50 3

    40 3

    Dow Corning 60 4

  • LED

    2012 TV LCD(Liquid Crystal

    Display) , IT, LCD,

    LCD . TV LCD

    2

    . IT LCD IT LCD

    , , LED

    . LCD

    OLED ,

    ,

    , .

    LED LED

    LED

    .

    LED .

    LED

    LED LED

    .

    LED .

    .

    LED LED

    LED . LED

    2016 .

    061

    LED

    2012 LED 2,117, 1 3,466

    . LED LCD

    20% ,

    11.6 %

    . , 3/4

    LED ,

    0.9 % . 2020 LED

    2012 46.1% 3,092, 1.6% 1

    3,682 .

    LED .

    LED . LED

    TV

    .

    ,

    LED . ,

    .

    060

  • . 2014 162

    2015 153 . 2015

    .

    LED

    ( : )

    LED

    ( : )

    LED

    20%~40% .

    ,

    .

    LED

    .

    2010 34 ,

    2010 19 2015 14%

    . LED 2010 11

    2015 16 .

    063

    LED

    2012 LED 33.2%

    2,150 . SMD ( )

    LED ,

    . LED

    . 2012 28.9%

    58, 19.1% 393 .

    YAG(Yttrium Aluminum Garnet)

    . LED

    2012 4.2%

    500 , 3.2% 215

    . LCD TV

    .

    LED

    Strategies Unlimited(2011. 9) LED

    2009 53 2010 TV

    108% 112

    . LED 2010 112 ,

    2014 162 2015 153

    . LED 2010 2 3,937

    2015 9 2,000 .

    2011 LED LED ,

    , LED , LED

    9.8% 123

    062

    2008 2009 2010 2011 2014 2015CAGR

    (10~15)

    LED 50.8 54 112 123 162 153 6.44%

    : Strategies Unlimited(2011.9)

    2008 2010 2012 2015CAGR

    (10~15)

    LED 8,275 23,937 54,600 92,000 30.9%

    :(2011.8)

  • . LED

    .

    , LED TV

    .

    .

    , 2009

    700 ~ 800 2010 2,500 ~ 3,000 2

    . LED BLU(Back

    Light Unit), , , , TV

    LCD(Liquid Crystal Display) BLU,

    , .

    PCB(Printed Circuit Board)

    MCCL() Metal PCB, PCB

    (Heat sink),

    (Sheet) ,

    065

    PC ,

    LED 4.1% .

    LED

    2010 7.8% 11 .

    2011 5% 11.55 .

    LED

    10% .

    LED LED

    .

    2010 LED, LG

    , LED

    2009 4 2010 2 .

    LED 2010 2 3,937 2015 9

    2,000 .

    LED(Light Emitting Diode)

    . LED TV

    LED

    . , LED

    LED

    .

    , LED , , COB(Chip On Board)

    064

    20 LED

    : CMRI

  • PCB MCCL

    Metal PCB, PCB ,

    .

    LED , ,

    2011 38.3% 4,219,

    3.4 37 .

    , , ,

    (needs)

    . 2012

    .

    , ,

    22

    (elastomer) 2 , (filler) ,

    6

    067

    , Metal PCB ,

    .

    LED TV LED .

    2009 LED TV LED LED

    TV 2009 450 2010 1500

    100% .

    LED , , LED

    LED

    .

    , LED

    . LED

    .

    LED TV

    . ,

    . LED

    , LED

    066

    21 LED

    22 LED

    : LED

    :

  • 2011 , 2010 8.0%

    284 . 80%

    . , , ,

    . ,

    , .

    .

    .

    .

    . ,

    .

    . .

    ()

    . 2011 2010 5.0%

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    . , 1

    . ,

    , .

    . ,

    .

    069

    . , , (6

    ) (4 ) .

    2011 2010 7.5% 3,051

    . , . 2017

    2011 38.3% 4,219 .

    , ,

    . , LED

    (die bond)

    .

    ,

    ,

    . 2011

    2010 37.5% 11. 2017

    2011 3.4 37 .

    2009 , 2011

    LED 50% . LED

    ,

    . 2011

    , 2012 ,

    .

    (siloxane) ,

    .

    068

  • Chapter 7

    ()

    . 2011 2010 11.4% 117

    .

    .

    ,

    ,

    ,

    .

    ()

    .

    ,

    . 2011 2010 37.5% 11

    . LED

    . LED LED

    .

    ,

    , . ,

    .

    070

  • 2012~2013

    .

    : 2012~2013

    LED LED

    .

    60W

    ,

    .

    073

    2013 LED

    2013 LED

    . LED

    , , LED

    .

    2012 3 LED

    24% , LED

    Lighting Science Group

    , 2012 3 40.4%

    . Hubbell Acuity Brands

    LED 16% 12% ,

    Top tier Zumtobel LED

    20% .

    LED

    LED .

    072

    2009 2010 2011 2012 2013 2014 2015 2016

    100W

    75W

    40W 60W

    100W

    EU65W

    60W

    40W, 25W

    , ,

    100W ,

    60W ,

    15W,

    CFL LED(USD) LEDvs LEDvs.CFL

    (USD) (USD) Average Low High () ()

    0.7 5.2 21 15 25 27.7 4.1

    1.6 9.0 23 12 36 14.2 2.6

    - 7.9 35 29 42 N/V 4.4

    0.9 3.4 17 15 19 19.1 4.9

    `1.2 4.7 16 10 23 13.3 3.3

    1.1 5.3 22 10 42 20.0 4.2

    : , KTB

    : KTB

  • Zhaga

    , 2014

    . 2011

    , 1 2012

    .

    LED . 2011

    LED 6.8%, LED 0.6%

    2015 LED

    075

    LED (Replacement Lamp)

    LED (Luminaires) .

    , , (Fixture)

    LED , LED

    LED . LED

    LED

    , Connectivity (Smart)

    .

    LED

    . Zhaga

    . Zhaga Osram, Philips

    /LED ,

    LED . 2010 2

    , 2(Book 1, Book 2)

    , Zhaga LED

    .

    LED

    . LED ,

    ,

    .

    .

    074

    : KTB

    Osram, Philips, Cree, 284 LED (Light Engine) LED

    ,

    20102, , LED 9Zhaga "Book", Book1Book88Book2Book3

    (Book) Book 1 - (Common definitions and generic interfaces.)Book 2 - - (65mm )

    (A socketable light engine with integrated control gear - mainly used in downlight applications (65mmbase))

    Book 3 - - (A round engine with separate control gear - used in spot lighting and other applications that need a pointlight source)

    Book 4 - (A flat emitter streetlinght engine with separate control gear)

    Book 5 - (A socketable light engine with separate electronic control gear)

    Book 6 - (A compact socketable LED light engine with integrated electronic control gear)

    Book 7 - (Several indoor light engines with separate electronic control gear)

    Book 8 - - (85mm)(A socketable light engine with intearated control gear - mainly used in downlight applications ( 85mmbase))

    Light Engine LED , , LED, ,

  • 2012 4.9%, 2013 8.1% ,

    2020 54.5%

    .

    , LED 2001~2005 ,

    2009~2011 LCD TV IT LED

    . IT

    IT

    ,

    .

    LED

    LED LED,

    , , , , ,

    LED 80%

    . 2010 28%

    077

    35.9%, 7.3% . /

    LED

    .

    2013 LED 7% 78

    LED (Fixture ) ,

    53% , 2020 LED 46%,

    LED 237 2012~2020

    21.2% .

    ,

    LED 2012 12.1%, 2013 20.3%

    , 2020 67% .

    LEd 2012 1.2%

    , LED 2013 2.3%

    .

    LED

    076

    23 LED ( + )

    24 LED :

    : , KTB

  • .

    LED

    LED, LG, , . LED

    LED

    . LED, LG

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