植物油加氢脱氧制燃料——概述

报告人：杨昱涵 指导老师：张香文

Vegetable Oil Based Jet FuelsOverview

Theory Basis

Introduction

Products & Analysis

Problems& Planning

Vegetable Oil Biofuel history Research in the world Domestic Research

Contents

Triglyceride

Vegetable Oil

O

O O R2=R1

=

R3=

O O

O

C 76-78%

H 11.5-12.5%

O 9-11%

Emergency Fuel

1940s 1980s 1990s 2000s

• Transesterification

• Alcoholysis

• Hydroprocessing

• Deoxygenation

• Micro Algae

• Cellulose

Biofuel History

Biodiesel1st Generation

Green Diesel2nd Generation

3rd Generation

• Vegetable Oil

Research in the world

CormaSpain

LimaBrazil

Murzin Finland

SahooIndia

TaufiqurrahmiMalaysia

Bezergianni Greece

LambUSA

SavageUSA

UOPUSA

IdemCanada

TobaJapan

SolazymeUSA

KubickaCzech

Decarboxylation Murzin Kubicka Lamb Hancsok Savage* Ko*Decarbonylation Lamb HancsokDeoxygenation Kubicka PKU XTU Choudhary

Cracking LimaBezergianni ZJU

Raw MaterialSolvent T P

Reactor H2/Oil LHSV Catalyst X Products By-pro.s Remarks

Murzin SA 360 1 FPd/C （ mes,5wt% ） 15 C17+CO+CO2

5v （ H2/Ar ）

SA0.06M+PA0.04M C12

260-300 1.75 F/B

15ml/(min*g) Pd/C （ mes ） 5v

SA/OA/LA 300 Pd/C （ mes ） C17 1v

SA/OA/LA C12 300 0.6 SB Pd/C （ mes ） C17+CO+CO2

Ar-C17 Dimer Trimer 1v

Lauric Acid F 100

Corma VO/VO+HVO HVO300-450 5 F 1600 4.97 Sd NiMo/Al2O3

C15-C18 71%VO/87%VO+HVO

H2S/H2 9v% 450ml/min

Bezergianni

Waste Cooking Oil 370

8.27-9.65 F

500nm3

H2/Oilm3 1 Sd NiMo 90

WCO330-398 8.27 1800 1 Sd NiMo DMDS

Lamb SA/OA/LA C12 300 1.5 SB 4.57Pd/C （ mac,5wt% ） 98 C17

Kubicka Triglyceride

250-350

0.7-7 F 100 1.5

CoMo/Al2O3 （ mes ）

Triglyceride300-320 2-11 F 50 1—4 CoMo/MCM-41 （ mes ） DMDS

浙大Umich Savage ； Hydrothermal M ；

Domestic Research

上海交大F ； CaO ； Catalytic Cracking ； quasi-CO/CO2 intermediates; CaCO3北大Phenolic Bio-Oil; Pd/C; Hydroxygenation; Alkanes

湘潭大学Phenol/ benzaldehyde/ acetophenone; Amorphous Co-Mo-B; Hydrodeoxygenation; Bronsted

1

2

3

4

郑大Transesterification; KF/ZnO5

Introduction

Theory Basis

Products & Analysis

Problems& Planning

Feasibility Analysis Raw Material Selection About Mechanism

Contents

Heat of Combustion

Pour Point

Flash Point

Specific Gravity

sulfurCarbon Residue

Kinematic Viscosity

Acidity

Water Soybean OilBiodiesel

Properties Comparison

Srivastava, A.; Prasad, R., Triglycerides-based diesel fuels. Renewable & Sustainable Energy Reviews 2000, 4, (2), 111-133.Dr. James D. Kinder ; Timothy Rahmes, Evaluation of bio-derived synthetic parraffinic kerosene.

30%

40%

50%

60%

70%

80%

20%

C10 C12 C14 C16 C18 C20

Vegetable Oil

Fatty Acid

Carbon Number

Blakey, S.; Rye, L.; Wilson, C. W., Aviation gas turbine alternative fuels: A review. Proceedings of the Combustion Institute 2011, 33, (2), 2863-2885.

Jet Fuel

Parrafin

Fatty Acid Composition (wt%)

Palmitic16:0C16H32O2

Stearic18:0C18H36O2

Arachidic20:0C20H40O2

Oleic18:1C18H34O2

Linoleic18:2C18H32O2

Linolenic18:3C18H30O2

Ricinoleic C18H34O3

Soybean

Sunflower

Corn

Peanut

Jatropha

Rubber seed

Olive

Cotton seed

Rapeseed

Castor

12 3 0 23 55 0 0

6 03 67417 0

3 01 82264 0

12 Tr2 Tr625 0

13 14 13543 0

16 06 0.83413 0

10 08 163924 0

1 01 053 88

26 05 05821 0

5 084 0021 0

Taufiqurrahmi, N.; Bhatia, S., Catalytic cracking of edible and non-edible oils for the production of biofuels. Energy & Environmental Science 2011√, 4, (4), 1087-1112.

Huber, G. W.; Iborra, S.; Corma, A., Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering. Chemical Reviews 2006, 106, (9), 4044-4098.

Mechanism

H2 CO

C17

CO2

C17Decarboxylation

H2OH2

C18

Decarbonylation

Cracking

H2

Hydrodeoxygenation

C12-16

+H2O

Stearic Acid

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