以生物處理技術處理含氮廢水之研究

2012.11.24

1.

2.TFT-LCD(DMSO((CH3)2SO)MEA(C2H5ONH2)(TMAH((CH3)4NOH))

3.

Fig.3 2-1 ()TMAH45L20L2.38mFig. UASB

Table. Operation parameter of UASB-UnitValueVolumeL65pH-7~ 8Temperature351ORPmV-440 ~ -550 HRTd1~3VLRkg N m-3 d-1InoculumTMAH

2-1 ()TMAH

TKN/COD:(0.05)COD/TOC:COD/TOC(4.0)CODTOCCOD

Table.TMAH UnitnRangeAverageStandard deviationTMAH%102.0-2.3%CODmg O L-192,346-3,4463,045482TOCmg C L-123,316-4,2083,762631TICmg C L-12461-1,430946685OrgNmg N L-1101,003-1,7751,219225NH4+-Nmg N L-1100-923pH-612.0-12.512.30.2TKN/COD--0.31-0.570.170.09COD/TOC--0.62-0.710.81 0.07

1. 22cm 19cm53cm 10L

2. 100L pH

3.

4.

Fig. 2-2 ()

2-2 () 8Table.

:

Table. 248 RUN 1~5:(Eff =Eff+AnammoxEff)

2-2 ()

2-3 () 1.5LUASB(SyntheticmediumS)(Ozone effluentO)

Operating parametersRun1Run2Run3HRT(day)0.1Influent flow rate(L day-1)15pH7.1~7.5Temperature()30~31DO(mg L-1)

2-3 ()95CODRun1~ Run3 Run11-25 (Run226-62) () (Run363-95)

Performance-O PhaseRun1Run2Run3Operation tim(day)1-2526-6263-95NH4+-N(mgN L-1)48 1333 695 36NO2--N(mgN L-1)58 855 5102 8NO3--N mgN L-1)2 25 222 35COD(mgO2 L-1 )112 14101 12149 25TKN(mgNL-1)47 2032 586 38

3-1 ()TMAHFig. Fig. 500UASBTMAH

3-1 ()TMAH Table. org-N92%

Unit123HRTday1.3-3TMAH:WW-TMAH:(1:6)TMAH:(1:6)MLVSSmg/L13,000~14,00013,000~14,00013,000~14,000VLRCODkg/m3-day0.82-0.96VLROrg-Nkg/m3-day0.22-0.063FCOD/MkgCOD/ kgVSS0.060-0.071Forg-N/Mkg org-N/ kgVSS0.016-0.005COD removal%33-82OrgN hydrolysis%92-66

3-1 ()TMAHFig. Fig. CODorg-NNH4+-Norg-NNH4+-Norg-N92%

3-1 ()TMAHFig. pH Fig. pH7.2~7.4after 12hrafter 12hr (suger)12org-N56%10%56%10%12

3-1 ()TMAHpH Biochemical Methane Potential , BMP TMAHpHpH7~8TMAH

TKN iniNH4+-N iniOrgN iniTOC iniCOD iniTMAH iniMinitialMfinalS0 (TMAH)/X0MPRS.MPRpHpHaverage5-1853 116 736 33161010 7002 15940189600.44 0.3 0.0002 5.5 5.5 5-2158400.3 0.0002 5.5 6-1628 118 510 32851010 5750 16360134000.35 9.9 0.0068 6.3 6.3 6-21476010.3 0.0070 6.3 7-1559 115 444 33101058 5323 16340149800.33 23.6 0.0162 6.8 6.8 7-21480025.1 0.0172 6.8 7.5-1603 116 486 31391058 5450 17540145400.31 25.4 0.0174 7.3 7.4 7.5-21360028.6 0.0196 7.5 8-1544 107 437 31751202 5303 16300142600.33 29.4 0.0202 8.1 8.0 8-21382029.0 0.0199 8.0 9-1663 108 554 32171490 5504 17080140200.32 19.1 0.0131 8.9 8.9 9-21406014.1 0.0097 9.0 10-1818 102 716 35772933 5270 16740150200.31 0.0 0.0000 9.8 9.8 10-2151800.0 0.0000 9.9

Chart1

0.00021963230.0000221782

0.00019904180.0000408839

0.00678141010.0000736102

0.00703509730.0001293983

0.01618415560.0002219651

0.0172136820.0003712409

0.01742645080.0006047061

0.01960218340.0009578143

0.02017185470.0014723738

0.01987672370.0021915762

0.01313675730.0031509123

0.0096844120.0043660217

00.0058213328

00.0074653386

0.0092168983

0.01098156

0.0126711762

0.0142187701

0.0155844023

0.0167529371

0.0177274229

0.0185216905

0.0191542537

0.0196441344

0.0200083962

0.0202608891

0.0204117234

0.0204671156

0.0204293794

0.0202969368

0.0200643099

0.0197221191

0.0192571962

0.0186530166

0.0178907836

0.0169516252

0.0158204154

0.0144915222

0.0129760725

0.0113089571

0.0095522091

0.0077908665

0.0061196476

0.0046236768

0.0033609019

0.0023536207

0.0015913378

0.0010413356

0.0006610585

0.0004079346

0.0002451017

S. MPR

Model

pH

S. MPR (mg CH4-C (mg VSS)-1 d-1)

Biogas

5-1CH4

Sampling timeAccumulation Time (hr)Biogass (ml)Accumulation Biogass (ml)Injet (ul)AreaValue (ul)%CH4 (ml)CH4 (ml)CH4 (ml)

11/22/11 17:0000050327492.3950.001.910.00

11/22/11 19:0025.45.450812125.92120.644.733.46

11/22/11 21:0041.87.2501051047.65150.286.125.13

11/23/11 2:59102.69.85014184610.33210.548.267.80

11/23/11 10:59181.811.65014822910.79220.398.638.56

11/23/11 23:00302.414301170028.52280.6811.3611.97

11/24/11 23:00544.818.85023511417.12341.6413.6915.95

5-2CH4


11/22/11 17:0000050329402.4050.001.920.00

11/22/11 19:0025.75.750794565.79120.664.633.37

11/22/11 21:0041.26.950993747.24140.175.794.70

11/23/11 2:59102.59.450887196.46130.325.174.40

11/23/11 10:59181.410.85016780612.22240.349.779.35

11/23/11 23:00302.213301057157.70260.5610.2710.41

11/24/11 23:00543.616.65021958715.99321.1512.7914.08

6-1CH4


11/22/11 17:0000050784105.71110.004.570.00

11/22/11 19:00221.821.85026203019.07388.3215.2619.01

11/22/11 21:00425.847.65038592628.095614.4922.4740.71

11/22/11 22:59624.672.23029130821.207117.3928.2763.90

11/23/11 0:59824.496.63029990021.837317.7529.1182.49

11/23/11 2:591024.8121.43031712123.087719.0830.78103.24

11/23/11 4:591221142.43034100924.828317.3733.09122.93

11/23/11 6:591420.61633035001725.488517.4933.97141.30

11/23/11 9:001620.4183.43034026224.778316.8433.02157.19

11/23/11 10:591821.4204.83035334725.728618.3534.29176.81

11/23/11 15:002232.8237.63031067622.617524.7230.15197.39

11/23/11 19:002636.2273.83030026021.867326.3729.14222.76

11/23/11 23:003033.23073028546720.786923.0027.71244.32

11/24/11 7:003838.2345.23026919919.606524.9526.13267.69

11/24/11 15:004630.2375.43025293218.416118.5324.55284.65

11/24/11 23:005425.4400.83034553925.158421.2933.53314.92

6-2CH4


11/22/11 17:0000050733035.34110.004.270.00

11/22/11 19:00222.6235027491420.01409.0516.0120.78

11/22/11 21:00426.9503024845818.096016.2224.1145.10

11/22/11 22:59627773029464021.457119.3028.6068.89

11/23/11 0:59824.81013030664622.327418.4529.7688.50

11/23/11 2:591025.61273032219323.457820.0131.27110.02

11/23/11 4:5912231503034613925.198419.3233.59131.66

11/23/11 6:591422.41723034814525.348418.9233.79150.78

11/23/11 9:0016221943033529324.408117.9032.54167.43

11/23/11 10:591820.82153034605925.198417.4633.58185.94

11/23/11 15:002236.82523029681621.607226.5028.81207.66

11/23/11 19:002635.22873031051622.607526.5230.14235.51

11/23/11 23:003030.83183031699523.077723.6930.76259.83

11/24/11 7:0038373553033364024.288129.9532.38291.39

11/24/11 15:0046293843035239725.658524.7934.20318.01

11/24/11 23:005423.64083035979926.198720.6034.92339.33

7-1CH4


11/22/11 17:000005016691812.15240.009.720.00

11/22/11 19:00237375038609928.105620.8022.4833.55

11/22/11 21:00438753029541921.507227.2428.6766.98

11/22/11 22:59636.81125050621536.847427.1229.4794.90

11/23/11 0:59835.61473032895923.948028.4131.93125.76

11/23/11 2:591046.21943034775825.318438.9833.75166.57

11/23/11 4:591248.42423040407829.419847.4539.21219.48

11/23/11 6:5914482903038964028.369545.3737.81263.46

11/23/11 9:001636.23263037910527.599233.3036.79295.73

11/23/11 10:591824.63513038048227.699222.7136.92318.57

11/23/11 15:0022193703037405327.239117.2436.30335.19

11/23/11 19:00263.63733037897927.58923.3136.78338.98

11/23/11 23:00302.43763039711528.90962.3138.54343.05

11/24/11 7:00384.23803039375128.66964.0138.21346.73

11/24/11 15:00463.23833039839229.00973.0938.66350.28

11/24/11 23:005433863038161527.78932.7837.03351.43

7-2CH4


11/22/11 17:000005016981712.36250.009.890.00

11/22/11 19:00238.5395038796528.245621.7422.5934.44

11/22/11 21:00438.2775048609935.387127.0328.3067.18

11/22/11 22:596381153031354722.827628.9130.4398.22

11/23/11 0:59836.41513032857523.928029.0231.89128.70

11/23/11 2:5910562073037369827.209150.7736.27183.85

11/23/11 4:591250.42583038860928.289447.5237.71232.81

11/23/11 6:591448.23063040256629.309847.0839.07281.24

11/23/11 9:001638.23443033885924.668231.4132.89306.46

11/23/11 10:5918273713037697127.449124.6936.58334.86

11/23/11 15:002223.63953037916827.609221.7136.80356.78

11/23/11 19:00266.84013036542726.60896.0335.46361.47

11/23/11 23:00302.64043036374326.47882.2935.30363.60

11/24/11 7:00384.24083038452127.99933.9237.32369.54

11/24/11 15:00463.64123040856429.74993.5739.65375.44

11/24/11 23:00542.94153038246127.84932.6937.12375.60

7.5-1CH4


11/22/11 17:000005019357514.09280.0011.270.00

11/22/11 19:00246465042326130.816228.3424.6441.71

11/22/11 21:00442.4883033834024.638234.8132.8484.71

11/22/11 22:59637.81263037105727.019034.0336.01121.91

11/23/11 0:598511773037945627.629246.9536.82169.68

11/23/11 2:591048.42263040413429.419847.4539.22219.53

11/23/11 4:591241.42673029221721.277129.3528.36238.02

11/23/11 6:591434.43013042459930.9010335.4441.20286.30

11/23/11 10:591830.63323047079834.2611434.9545.69325.73

11/23/11 15:00225.63383039209628.54955.3338.05323.42

11/23/11 19:002643423040194529.25983.9039.01328.28

11/23/11 23:00301.23433038743628.20941.1337.60328.00

11/24/11 23:005413443045001332.751091.0943.67335.16

7.5-2CH4


11/22/11 17:000005018991113.83280.0011.060.00

11/22/11 19:00245455040961729.816026.8323.8539.62

11/22/11 21:00441.8873035828826.088736.3434.7786.88

11/22/11 22:59641.61283041044029.8710041.4239.83133.36

11/23/11 0:598511793037236227.109046.0736.14175.74

11/23/11 2:591047.42273040373129.389846.4339.18225.21

11/23/11 4:591241.22683042972131.2810442.9541.70270.69

11/23/11 6:591433.43013049904636.3212140.4448.43317.85

11/23/11 9:001618.83203041441730.1610118.9040.22328.54

11/23/11 10:591813.83343044481932.3710814.8943.17346.38

11/23/11 15:00228.83433038022427.67928.1236.90348.23

11/23/11 19:00263.83473038246227.84933.5337.12351.97

11/23/11 23:00301.23483041563930.251011.2140.33356.40

11/24/11 23:00541.63493043514731.671061.6942.23359.99

8-1CH4


11/22/11 17:000005022635316.48330.0013.180.00

11/22/11 19:00245.6465043489831.656328.8725.3241.01

11/22/11 21:00441873035292625.698635.1134.2585.04

11/22/11 22:59643.21303041103929.9210043.0839.89133.76

11/23/11 0:59849.61793038807928.259446.7037.66178.23

11/23/11 2:591045.82253047393334.4911552.6645.99239.22

11/23/11 4:591237.42633046798034.0611442.4645.41281.11

11/23/11 6:591433.82963041237830.0110033.8240.02309.53

11/23/11 10:591820.23173048577535.3511823.8147.14340.45

11/23/11 15:00226.23233042903731.231046.4541.63341.40

11/23/11 19:00265.23283041011929.85995.1739.80344.74

11/23/11 23:00300.63293047754834.761160.7046.34351.98

11/24/11 23:005423313046100033.551122.2444.74352.61

8-2CH4


11/22/11 17:000005022792616.59330.0013.270.00

11/22/11 19:00246.6475044063932.076429.8925.6642.27

11/22/11 21:00444913033911924.688236.2032.9185.73

11/22/11 22:59645.61363040831329.729945.1739.62137.61

11/23/11 0:59849.21853039123828.489546.7037.97182.66

11/23/11 2:591046.42323043550631.7010649.0242.26235.98

11/23/11 4:591239.62713041918330.5110240.2740.68274.66

11/23/11 6:591426.22983044509832.3910828.2943.19305.47

11/23/11 10:5918193173051240637.2912423.6249.72335.62

11/23/11 15:00225.63223044441732.351086.0443.13335.06

11/23/11 19:00265.23273043036031.321045.4341.76339.13

11/23/11 23:00300.83283043826731.901060.8542.53340.74

11/24/11 23:00541.13293046613133.931131.2445.23344.69

9-1CH4


11/22/11 17:000005016920112.32250.009.860.00

11/22/11 19:00240.8415046242133.666727.4626.9244.53

11/22/11 21:00440.8823037107627.019036.7336.0190.35

11/22/11 22:59636.81183040516229.499836.1739.32129.83

11/23/11 0:59836.41553043498131.6610638.4142.21171.14

11/23/11 2:5910251803043715531.8210626.5142.42197.86

11/23/11 4:591216.61963042351330.8210317.0641.10213.59

11/23/11 6:591410.62073048709235.4511812.5347.27232.29

11/23/11 10:591842113051383237.401254.9949.86239.87

11/23/11 19:00264.22153045527933.141104.6444.18238.83

11/23/11 23:003023.22383047684134.7011626.8446.27267.76

11/24/11 7:003843.62823045026732.7710947.6343.69312.81

11/24/11 15:004622.43043048188035.0711726.1946.76342.06

11/24/11 23:005410.83153049999136.3912113.1048.52356.92

9-2CH4


11/22/11 17:00000501321568.08160.006.460.00

11/22/11 19:00237.6385042194826.345319.8121.0734.41

11/22/11 21:00440.8783035605922.197430.1729.5873.09

11/22/11 22:59625.81043040980925.578521.9934.1099.60

11/23/11 0:59836.61413042640626.628932.4735.49133.47

11/23/11 2:591018.61593048900130.5610218.9540.75157.67

11/23/11 4:59124.21643047026129.38984.1139.17160.21

11/23/11 10:59181.21653055024834.421151.3845.89168.31

11/23/11 19:00262.41673046537229.07972.3338.76163.51

11/23/11 23:003027.61953048506930.3110127.8940.42193.05

11/24/11 7:003856.62513044690927.919352.6637.21242.50

11/24/11 15:004631.22833049857031.1610432.4141.55279.25

11/24/11 23:005416.82993050196531.3810517.5741.84297.10

10-1CH4


11/22/11 17:0000050128270.5610.000.450.00

11/24/11 23:00544.2450263091.4130.121.130.80

10-2CH4


11/22/11 17:0000050111970.4610.000.370.00

11/24/11 23:00541.21.250164820.7920.020.630.29

5-1

Sampling timeMethaneGompersVariation

11/22/11 17:0000.003.8714.95

11/22/11 19:0023.464.190.53

11/22/11 21:0045.134.520.37

11/23/11 2:59107.805.634.74

11/23/11 10:59188.567.311.56

11/23/11 23:003011.9710.272.89

11/24/11 23:005415.9517.311.86

MaxMinValue

A500158.59

R2000.32

500.00

RSE27

RSQ0.84

5-2

Sampling timeGompersVariation

11/22/11 17:0000.003.2910.82

11/22/11 19:0023.373.570.04

11/22/11 21:0044.703.880.68

11/23/11 2:59104.404.870.21

11/23/11 10:59189.356.398.78

11/23/11 23:003010.419.061.81

11/24/11 23:005414.0815.411.77

MaxMinValue

A500149.85

R2000.29

500.00

RSE24

RSQ0.83

6-1

Sampling timeGompersVariation019.106.16.3

11/22/11 17:0000.0019.10364.84124.146.5

11/22/11 19:00219.0129.91118.91229.91

11/22/11 21:00440.7143.558.06336.396.4

11/22/11 22:59663.9059.6717.92443.55

11/23/11 0:59882.4977.6823.14551.336.4

11/23/11 2:5910103.2496.8940.29659.67

11/23/11 4:5912122.93116.6140.01768.486.3

11/23/11 6:5914141.30136.1826.20877.68

11/23/11 9:0016157.19155.094.43987.186.1

11/23/11 10:5918176.81172.9414.971096.89

11/23/11 15:0022197.39204.5350.9311106.736.2

11/23/11 19:0026222.76230.1053.8812116.61

11/23/11 23:0030244.32249.9331.5313126.456.3

11/24/11 7:0038267.69275.8967.2214136.18

11/24/11 15:0046284.65289.6625.1115145.756.4

11/24/11 23:0054314.92296.69332.3516155.09

17164.176.5

18172.94

19181.38

20189.476.4

21197.19

MaxMinValue22204.53

A5001303.7023211.49

R2009.8824218.076.3

500.2025224.27

26230.10

27235.57

RSE122028240.696.3

RSQ0.9929245.47

30249.93

31254.09

32257.95

33261.54

34264.876.3

35267.95

36270.81

37273.45

38275.89

39278.14

40280.22

41282.13

42283.906.3

43285.52

44287.02

45288.39

46289.66

47290.82

48291.89

49292.87

50293.776.3

51294.60

52295.36

53296.05

54296.69

6-1

No. 6-1

Gomperz

pH

Time (hr)

Cumulative methane (mL)

pH

6-2


11/22/11 17:0000.0022.17491.64127.536.5

11/22/11 19:00220.7833.59164.03233.59

11/22/11 21:00445.1047.757.02340.346.4

11/22/11 22:59668.8964.3420.69447.75

11/23/11 0:59888.5082.8232.26555.776.4

11/23/11 2:5910110.02102.5855.36664.34

11/23/11 4:5912131.66122.9775.53773.386.3

11/23/11 6:5914150.78143.3954.65882.82

11/23/11 9:0016167.43163.3116.95992.586.2

11/23/11 10:5918185.94182.3412.9110102.58

11/23/11 15:0022207.66216.6881.2911112.746.1

11/23/11 19:0026235.51245.2494.6712122.97

11/23/11 23:0030259.83268.0367.3713133.216.2

11/24/11 7:0038291.39299.0859.0514143.39

11/24/11 15:0046318.01316.452.4315153.446.2

11/24/11 23:0054339.33325.79183.2716163.31

17172.966.2

18182.34

19191.43

20200.196.3

21208.61

MaxMinValue22216.68

A5001336.0123224.37

R20010.2524231.706.4

500.0025238.65

26245.24

27251.46

RSE141928257.336.4

RSQ0.9929262.85

30268.03

31272.90

32277.45

33281.71

34285.696.4

35289.40

36292.86

37296.08

38299.08

39301.86

40304.45

41306.84

42309.076.3

43311.13

44313.04

45314.81

46316.45

47317.96

48319.36

49320.66

50321.856.3

51322.96

52323.98

53324.92

54325.79

6-2

No. 6-2

Gomperz

pH

Time (hr)


pH

7-1

Sampling timeGompersVariation06.5676.8

11/22/11 17:0000.006.5643.04112.707.1

11/22/11 19:00233.5522.05132.44222.05

11/22/11 21:00466.9851.26247.33334.926.8

11/22/11 22:59694.9092.217.25451.26

11/23/11 0:598125.76138.77169.04570.596.7

11/23/11 2:5910166.57184.44319.20692.21

11/23/11 4:5912219.48224.8328.577115.226.6

11/23/11 6:5914263.46258.0529.198138.77

11/23/11 9:0016295.73284.04136.689162.056.8

11/23/11 10:5918318.57303.65222.5210184.44

11/23/11 15:0022335.19328.5643.9411205.467.0

11/23/11 19:0026338.98341.355.6412224.83

11/23/11 23:0030343.05347.7321.8913242.376.8

11/24/11 7:0038346.73352.3931.9514258.05

11/24/11 15:0046350.28353.4910.3115271.916.7

11/24/11 23:0054351.43353.755.3916284.04

17294.576.7

18303.65

19311.45

20318.107.3

21323.76

MaxMinValue22328.56

A5001353.8323332.62

R50023.5824336.047.3

502.1225338.93

26341.35

27343.39

RSE145428345.107.3

RSQ0.9929346.53

30347.73

31348.73

32349.57

33350.27

34350.867.3

35351.35

36351.76

37352.10

38352.39

39352.63

40352.82

41352.99

42353.137.2

43353.25

44353.34

45353.42

46353.49

47353.55

48353.59

49353.63

50353.667.2

51353.69

52353.71

53353.73

54353.75

7-1

No. 7-1

Gomperz

pH

Time (hr)


pH

7-2


11/22/11 17:0000.006.5743.17112.847.0

11/22/11 19:00234.4422.47143.36222.47

11/22/11 21:00467.1852.90204.16335.836.8

11/22/11 22:59698.2296.024.86452.90

11/23/11 0:598128.70145.43279.96573.216.7

11/23/11 2:5910183.85194.18106.75696.02

11/23/11 4:5912232.81237.4821.817120.406.6

11/23/11 6:5914281.24273.2264.368145.43

11/23/11 9:0016306.46301.2327.379170.256.8

11/23/11 10:5918334.86322.42154.6510194.18

11/23/11 15:0022356.78349.3854.8011216.707.1

11/23/11 19:0026361.47363.253.1412237.48

11/23/11 23:0030363.60370.1743.0913256.346.8

11/24/11 7:0038369.54375.2432.4514273.22

11/24/11 15:0046375.44376.440.9915288.156.7

11/24/11 23:0054375.60376.721.2616301.23

17312.606.7

18322.42

19330.85

20338.057.3

21344.18

MaxMinValue22349.38

A5001376.8123353.77

R50025.0824357.497.2

502.2025360.61

26363.25

27365.46

RSE118628367.317.2

RSQ1.0029368.87

30370.17

31371.26

32372.17

33372.94

34373.577.2

35374.11

36374.55

37374.92

38375.24

39375.49

40375.71

41375.89

42376.047.1

43376.17

44376.28

45376.36

46376.44

47376.50

48376.55

49376.59

50376.637.1

51376.66

52376.68

53376.70

54376.72

7-2

No. 7-2

Gomperz

pH

Time (hr)


pH

7.5-1

Sampling timeAccumulation Time (hr)GompersVariation011.457.17.3

11/22/11 17:0000.0011.45131.13121.437.0

11/22/11 19:00241.7135.7136.04235.71

11/22/11 21:00484.7175.9576.71354.127.4

11/22/11 22:596121.91125.3211.61475.95

11/23/11 0:598169.68174.7225.415100.097.4

11/23/11 2:5910219.53217.822.906125.32

11/23/11 4:5912238.02252.15199.607150.507.4

11/23/11 6:5914286.30277.8671.228174.72

11/23/11 10:5918325.73309.30270.029197.297.4

11/23/11 15:0022323.42324.250.6810217.82

11/23/11 19:0026328.28331.067.7211236.127.6

11/23/11 23:0030328.00334.1037.2412252.15

11/24/11 23:0054335.16336.501.7913266.017.9

14277.86

15287.917.5

16296.35

17303.427.4

18309.30

19314.18

20318.208.0

21321.52

MaxMinValue22324.25

A5001336.5223326.49

R50025.3924328.337.5

501.0625329.83

26331.06

27332.07

RSE87228332.897.7

RSQ1.0029333.56

30334.10

31334.55

32334.91

33335.21

34335.458.0

35335.65

36335.81

37335.94

38336.05

39336.14

40336.21

41336.26

42336.317.9

43336.35

44336.38

45336.41

46336.43

47336.44

48336.46

49336.47

50336.487.9

51336.49

52336.49

53336.50

54336.50

7.5-1

No. 7.5-1

Gomperz

pH

Time (hr)


pH

7.5-2


11/22/11 17:0000.009.4288.78119.037.0

11/22/11 19:00239.6233.5836.47233.58

11/22/11 21:00486.8876.9099.55353.117.6

11/22/11 22:596133.36131.971.93476.90

11/23/11 0:598175.74187.66142.215103.687.9

11/23/11 2:5910225.21236.08118.136131.97

11/23/11 4:5912270.69274.1812.227160.357.4

11/23/11 6:5914317.85302.27242.688187.67

11/23/11 9:0016328.54322.1141.309213.077.5

11/23/11 10:5918346.38335.74113.1510236.08

11/23/11 15:0022348.23351.078.0511256.457.6

11/23/11 19:0026351.97357.7933.8212274.18

11/23/11 23:0030356.40360.6918.3413289.387.9

11/24/11 23:0054359.99362.838.0814302.27

15313.097.5

16322.11

17329.587.4

18335.74

19340.80

20344.948.0

21348.32

MaxMinValue22351.07

A5001362.8423353.31

R50028.5624355.127.5

501.3825356.60

26357.79

27358.76

RSE96528359.547.7

RSQ1.0029360.17

30360.69

31361.10

32361.43

33361.70

34361.928.0

35362.10

36362.24

37362.36

38362.45

39362.53

40362.59

41362.63

42362.677.9

43362.71

44362.73

45362.75

46362.77

47362.78

48362.79

49362.80

50362.817.8

51362.82

52362.82

53362.82

54362.83

7.5-2

No. 7.5-2

Gomperz

pH

Time (hr)


pH

8-1


11/22/11 17:00008.5973.84118.217.4

11/22/11 19:0024133.1761.46233.17

11/22/11 21:0048578.3844.32353.518.1

11/22/11 22:596134135.543.18478.38

11/23/11 0:598178192.11192.475106.308.6

11/23/11 2:5910239239.880.436135.54

11/23/11 4:5912281276.3122.967164.567.9

11/23/11 6:5914310302.3551.518192.11

11/23/11 10:5918340332.1069.769217.368.1

11/23/11 15:0022341344.9812.8310239.88

11/23/11 19:0026345350.3531.4511259.508.2

11/23/11 23:0030351.98352.550.3312276.31

11/24/11 23:0054352.61354.052.0713290.508.3

14302.35

15312.158.7

16320.19

17326.768.7

18332.10

19336.428.5

20339.91

21342.72

MaxMinValue22344.98

A5001354.0623346.80

R50029.3924348.258.1

501.3925349.42

26350.35

27351.09

RSE56728351.698.2

RSQ1.0029352.17

30352.55

31352.85

32353.09

33353.29

34353.448.1

35353.57

36353.67

37353.74

38353.81

39353.86

40353.90

41353.93

42353.958

43353.97

44353.99

45354.00

46354.01

47354.02

48354.03

49354.03

50354.048

51354.04

52354.04

53354.05

54354.05

8-1

No. 8-1

Gomperz

pH

Time (hr)


pH

8-2


11/22/11 17:00009.3787.78119.537.5

11/22/11 19:0024235.0552.11235.05

11/22/11 21:0048680.9622.78355.867.7

11/22/11 22:596138137.670.00480.96

11/23/11 0:598183192.81103.085108.808.4

11/23/11 2:5910236238.747.646137.67

11/23/11 4:5912275273.401.617166.068.0

11/23/11 6:5914305297.9456.668192.81

11/23/11 10:5918336325.7297.949217.168.1

11/23/11 15:0022335337.626.5510238.74

11/23/11 19:0026339342.5311.5811257.458.0

11/23/11 23:0030340.74344.5214.2912273.40

11/24/11 23:0054344.69345.871.3913286.808.2

14297.94

15307.138.6

16314.65

17320.768.6

18325.72

19329.738.5

20332.95

21335.54

MaxMinValue22337.62

A5001345.8723339.28

R50028.9624340.628.3

501.2525341.68

26342.53

27343.21

RSE46328343.758.5

RSQ1.0029344.18

30344.52

31344.80

32345.02

33345.19

34345.338.3

35345.44

36345.53

37345.60

38345.66

39345.70

40345.74

41345.76

42345.798

43345.80

44345.82

45345.83

46345.84

47345.85

48345.85

49345.86

50345.868.2

51345.86

52345.87

53345.87

54345.87

8-2

No. 8-2

Gomperz

pH

Time (hr)


pH

9-1


11/22/11 17:0000.0020.19407.64130.898.6

11/22/11 19:00244.5344.210.10244.21

11/22/11 21:00490.3577.23172.24359.838.7

11/22/11 22:596129.83114.86224.18477.23

11/23/11 0:598171.14152.35352.82595.788.9

11/23/11 2:5910197.86186.28134.156114.86

11/23/11 4:5912213.59214.931.797133.889.0

11/23/11 6:5914232.29237.9732.308152.35

11/23/11 10:5918239.87269.40871.939169.919.0

11/23/11 19:0026238.83296.143284.5710186.28

11/23/11 23:0030267.76300.951101.6911201.318.9

11/24/11 7:0038312.81304.6766.1612214.93

11/24/11 15:0046342.06305.631326.8113227.149.0

11/24/11 23:0054356.92305.882604.6014237.97

15247.519.2

16255.86

17263.119.2

18269.40

19274.81

20279.479.1

21283.46

MaxMinValue22286.86

A5001305.9723289.77

R50019.1424292.258.9

500.0025294.35

26296.14

27297.65

RSE1058128298.948.8

RSQ0.9329300.03

30300.95

31301.73

32302.39

33302.94

34303.419.0

35303.81

36304.15

37304.43

38304.67

39304.87

40305.04

41305.19

42305.318.8

43305.41

44305.50

45305.57

46305.63

47305.69

48305.73

49305.77

50305.808.1

51305.82

52305.85

53305.87

54305.88

9-1

No. 9-1

Gomperz

pH

Time (hr)


pH

9-2


11/22/11 17:0000.0015.74247.80123.578.9

11/22/11 19:00234.4133.241.36233.24

11/22/11 21:00473.0957.16253.99344.558.8

11/22/11 22:59699.6084.67223.02457.16

11/23/11 0:598133.47112.57436.65570.679.2

11/23/11 2:5910157.67138.40371.63684.67

11/23/11 4:5912160.21160.750.29798.758.8

11/23/11 10:5918168.31205.241363.788112.57

11/23/11 19:0026163.51228.844269.149125.869.1

11/23/11 23:0030193.05233.401628.3210138.40

11/24/11 7:0038242.50237.1228.9211150.059.1

11/24/11 15:0046279.25238.161688.3712160.75

11/24/11 23:0054297.10238.443440.8613170.468.9

14179.18

15186.969.2

16193.86

17199.929.2

18205.24

19209.88

20213.919.2

21217.40

MaxMinValue22220.42

A5001238.5523223.02

R50014.1124225.268.8

500.0025227.19

26228.84

27230.26

RSE1395428231.478.5

RSQ0.8529232.51

30233.40

31234.16

32234.81

33235.36

34235.838.9

35236.23

36236.58

37236.87

38237.12

39237.33

40237.51

41237.67

42237.808.7

43237.91

44238.01

45238.09

46238.16

47238.22

48238.27

49238.31

50238.358.5

51238.38

52238.40

53238.43

54238.44

9-2

No. 9-2

Gomperz

pH

Time (hr)


pH

Total

TKN iniTKN finNH4+-N iniNH4+-N finOrgN iniOrg finTOC iniTOC finCOD iniCOD finTMAH iniTMAH finMinitialMfinalS0 (TMAH)/X0MPRS.MPRS.MPRaveS.MPRavedevS.MPRerrorpHpHaverageModelVariation50.00002

5-185391311618673672833163283101016837002528715940189600.440.30.00020.00020.000010.00015.55.50.000373E-085.10.00004

5-2765166599322512985199158400.30.00025.50.000305.20.00007

6-1628935118947510-123285551101016835750016360134000.359.90.00680.00690.000130.00116.36.30.007524E-075.30.00013

6-2832948-116593125001476010.30.00706.30.007155.40.00022

7-1559890115915444-253310361105813945323016340149800.3323.60.01620.01670.000510.00466.86.80.015581E-065.50.00037

7-2835935-100398134601480025.10.01726.80.015335.60.00060

7.5-1603915116887486283139584105820675450017540145400.3125.40.01740.01850.001090.00987.37.40.019428E-075.70.00096

7.5-291987345579221201360028.60.01967.50.020205.80.00147

8-1544951107902437483175851120223085303016300142600.3329.40.02020.02000.000150.00138.18.00.019757E-085.90.00219

8-21013900113827235601382029.00.01998.00.0201460.00315

9-1663101310890855410432171088149029815504017080140200.3219.10.01310.01140.001730.01558.98.90.011435E-106.10.00437

9-210119091021107283701406014.10.00979.00.009816.20.00582

10-181873610222671651035774039293347125270537616740150200.310.00.00000.00000.000000.00009.89.80.000614E-076.30.00747

10-2824195629405248564961151800.00.00009.90.000486.40.00922

63611232881394565816614.2857142857148036.50.01098

6.60.01267

6.70.01422

6.80.01558

6.90.01675

maxmin70.01773

Vmax10.010.027.10.01852

pHOpti1407.77.20.01915

KpH1405.17.30.01964

7.40.02001

RSE3E-067.50.02026

RSQ0.997.60.02041

7.70.02047

7.80.02043

7.90.02030

80.02006

8.10.01972

8.20.01926

8.30.01865

8.40.01789

8.50.01695

8.60.01582

8.70.01449

8.80.01298

8.90.01131

90.00955

9.10.00779

9.20.00612

9.30.00462

9.40.00336

9.50.00235

9.60.00159

9.70.00104

9.80.00066

9.90.00041

100.00025

Total

S. MPR

Model

pH

S. MPR (mg CH4-C (mg VSS)-1 d-1)

Table

UnitpH=5pH=6pH=7pH=7.5pH=8pH=9pH=10

CODinitialmg O2-O L-11010101010581058120214902933

TOCinitialmg C L-13316328533103139317532173577

OrgNinitialmg N L-1736510444486437554716

TMAHinitialmg TMA L-17002575053235450530355045270

MLVSSinitialmg VSS L-115940163601634017540163001708016740

CODfinalmg O2-O L-11490146613702139233229094784

TOCfinalmg C L-1325457238058183910984046

OrgNfinalmg N L-1663N.D.N.D.3780103570

TMAHfinalmg TMA L-15243N.D.N.D.N.D.N.D.N.D.5168

MLVSSfinalmg VSS L-117400140801489014070140401404015100

S0 (TOC)/X0mg C (mg VSS)-10.210.200.200.180.190.190.21

S0 (OrgN)/X0mg N (mg VSS)-10.0460.0310.0270.0280.0270.0320.043

S0 (TMAH)/X0mg TMA (mg VSS)-10.440.350.330.310.330.320.31

COD/TOCinitial-0.300.310.320.340.380.460.82

OrgN/TOCinitial-0.220.160.130.150.140.170.200.29

TMAH/TOCinitial-2.111.751.611.741.671.711.471.54

COD/TOCfinal-0.462.563.613.682.782.651.18

S. MPRmg CH4-C (mg VSS)-1 d-10.00020.00690.01670.01850.020.01140

pH

Startup11/22/11 17:0011/22/11 19:0011/22/11 21:0011/22/11 22:5911/23/11 0:5911/23/11 2:5911/23/11 4:5911/23/11 6:5911/23/11 9:0011/23/11 10:5911/23/11 15:0011/23/11 23:0011/24/11 7:002011/11/24 15:00:00 AM2011/11/24 15:00:00 AM

BeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfterBeforeAfter

5155.55.55.55.55.55.75.75.65.65.55.55.45.4555.65.65.65.65.75.75.85.85.75.8

255.55.55.55.45.45.55.55.65.65.45.45.55.5555.65.65.55.55.65.65.85.85.65.6

616.16.56.56.56.36.36.46.46.16.16.16.16.36.36.36.36.56.46.46.36.36.36.36.36.36.36.3

26.26.56.56.56.36.36.46.46.26.26.16.16.16.16.26.26.26.26.46.46.36.36.46.46.36.3

7177.26.96.96.76.76.76.76.47.26.47.36.76.76.86.86.76.67.37.37.37.37.37.37.37.27.2

26.97.26.86.86.76.76.76.76.47.16.57.36.86.86.76.76.76.67.47.27.27.17.17.27.27.17.1

7.517.17.16.87.67.17.67.27.67.17.86.97.97.38.17.67.67.47.37.987.67.47.4887.97.9

27.17.16.87.97.28.27.67.67.17.97.17.87.38.27.67.67.47.37.987.67.47.4887.97.8

818.57.878.77.58.88.38.37.48.57.78.47.98.6898.38.38.78.27.98.28.28.288

28.37.97.18.17.28.788.47.58.47.78.37.78.67.88.88.38.38.78.48.18.58.58.588.2

919.39.1898.49.18.79.38.69.18.898.89.48.69.48.98.99.39.18.798.69.18.88.1

29.29.38.49.18.49.39.19.18.59.38.89.1998.89.58.98.99.598.68.98.19.18.78.5

10110.510.610.310.310.110.19.99.9101010109.59.59.39.39.69.69.99.99.69.69.79.79.49.3

210.510.510.310.310.210.2101010.110.110109.69.69.39.39.79.79.99.99.79.79.79.79.5

5155.55.55.65.75.65.55.25.35.35.65.75.85.85.75.8

255.55.55.55.65.55.55.35.35.35.65.65.75.75.65.6

616.16.56.46.46.36.16.26.36.46.56.46.36.36.36.36.3

26.26.56.46.46.36.26.16.26.26.26.36.46.46.46.36.3

7177.16.86.76.66.87.06.86.76.77.37.37.37.37.27.2

26.97.06.86.76.66.87.16.86.76.77.37.27.27.27.17.1

7.517.17.07.47.47.47.47.67.97.57.48.07.57.78.07.97.9

27.17.07.67.97.47.57.67.97.57.48.07.57.78.07.97.8

818.57.48.18.67.98.18.28.38.78.78.58.18.28.188

28.37.57.78.48.08.18.08.28.68.68.58.38.58.388.2

919.38.68.78.99.09.08.99.09.29.29.18.98.89.08.88.1

29.28.98.89.28.89.19.18.99.29.29.28.88.58.98.78.5

10110.510.510.210.010.010.09.89.49.59.59.89.89.79.69.49.3

210.510.410.310.110.110.19.89.59.59.59.89.89.79.69.5

SS&VSS

V(mL)W0W1W2SSVSSVSS/SS

5-350.24380.33280.253117800159400.90

6-350.24180.33280.25118200163600.90

7-350.2430.33360.251918120163400.90

7.5-350.24470.34080.253119220175400.91

8-350.24360.33660.255118600163000.88

9-350.24340.34050.255119420170800.88

10-350.24410.33770.25418720167400.89

5-150.24640.35190.257121100189600.90

5-250.24440.33240.253217600158400.90

6-150.2460.32110.254115020134000.89

6-250.24380.3270.253216640147600.89

7-150.24230.32750.252617040149800.88

7-250.24380.32790.253916820148000.88

7.5-150.24390.330.257317220145400.84

7.5-250.24480.3260.25816240136000.84

8-150.2440.32970.258417140142600.83

8-250.24320.32680.257716720138200.83

9-150.24390.32940.259317100140200.82

9-250.24520.33190.261617340140600.81

10-150.24470.33080.255717220150200.87

10-250.24650.33320.257317340151800.88

TKN

SampleVolumeDilutionTitrationCalculationConc.H2SO4

Blank101000.10375

Blank10100

5_31050.05744242

6_31050.8642628628

7_31050.7696559559

7.5_31050.8298603603

8_31050.7496544544

9_31050.9124663663

10_31051.1257818818

5_11051.2576913913

5_21051.054765765

6_11051.2879935935

6_21051.145832832

7_11051.2258890890

7_21051.15835835

7.5_11051.2596915915

7.5_21051.2648919919

8_11051.309951951

8_21051.394310131013

9_11051.394410131013

9_21051.392310111011

10_11051.0138736736

10_21051.1349824824

5_31051.1742853853

Ammonium

SampleVolumeDilutionTitrationCalculationConc.H2SO4

Blank1010.003710.10375

Blank10100

5_31010.8049117116

6_31010.8091118118

7_31010.7949115115

7.5_31010.8013116116

8_31010.74107107

9_31010.746108108

10_31010.705102102

5_11011.2782186186

5_21011.1486167166

6_11016.5197947947

6_21016.5274948948

7_11016.3021915915

7_21016.4407936935

7.5_11016.1063887887

7.5_21016.0166874873

8_11016.213902902

8_21016.2901900

9_11016.2538908908

9_21016.2635910909

10_11011.5546226226

10_21011.3445195195

COD

SampleVolumeDilutionTitration (A)B-ACOD conc.FAS

S20110.40.25

B20110.5

5_32058.42.11010

6_32058.42.11010

7_32058.32.21058

7.5_32058.32.21058

8_320582.51202

9_32057.43.11490

10_32054.46.12933

5_120573.51683

5_22057.82.71298

6_120573.51683

6_22057.92.61250

7_12057.62.91394

7_22057.72.81346

7.5_12056.24.32067

7.5_22055.94.62212

8_12055.74.82308

8_22055.64.92356

9_12054.36.22981

9_22054.65.92837

10_12050.79.84712

10_22050.410.14856

TOC

SampleDilutionTCTOCTC conc.TOC conc.TIC conc.

5_310031.933.1631903316-126

6_310031.232.8531203285-165

7_310031.7833.131783310-132

7.5_310030.7631.3930763139-63

8_310031.6931.7531693175-6

9_310033.332.1733303217113

10_310038.135.7738103577233

5_110033.0332.833303328320

5_210033.8532.2533853225160

6_11005.5915.505559.15519

6_21006.5555.931655.559362

7_11006.0853.614608.5361247

7_21009.0773.983907.7398509

7.5_110014.275.8411427584843

7.5_210014.255.7851425579847

8_110016.098.5051609851759

8_210016.148.2711614827787

9_110020.0510.8820051088917

9_210021.5211.07215211071045

10_110044.7340.3944734039434

10_210045.1140.5245114052459

TMAH

SampleDilutionTMAHNH4TMAH conc.NH4 conc.

5_310007.0020.27847002278

6_310005.75010.15335750153

7_310005.32330.15695323157

7.5_310005.45040.13985450140

8_310005.30330.1645303164

9_310005.50380.1355504135

10_310005.26990.11625270116

5_110005.2870.24675287247

5_210005.19880.24315199243

6_1100001.186801187

6_2100001.316401316

7_1100001.378401378

7_2100001.256801257

7.5_1100001.257601258

7.5_2100001.255201255

8_1100001.307401307

8_2100001.130701131

9_1100001.388801389

9_2100001.214501215

10_110005.3760.315376310

10_210004.96090.22924961229.2

3-1 ()TMAHorg-Norg-N NH4+-Norg-N16org-N50%90%Fig11. Fig12.

Org-N90%Org-N90%50%

80ppm150ppm3-2 ()100ppmFig.

3-2 ()Fig. 1.100 mg N/L 0.1 CANON

2.150 mg N/L NH3 + 0.85 O2 0.11 NO3-+ 0.44 N2 + 0.14 H++ 1.43H2OCANONNO3-N/NH4+-NNH4+-NTN

3-2 ()RUN 1

Fig. (1)RUN 1 (NH4Cl+water) (2)100 mg N/L 0.2~0.22 kg N/m3-day 60%Inf-NH4+-NEff-NH4+-NTN VLRTN removal efficiencyTN removal rate

3-2 ()RUN 2

Fig. (1)RUN 2 (2) 0.3~0.5 kg N/m3-day 70%TN removal efficiencyTN VLRTN removal rateInf-NH4+-NEff-NH4+-N

3-2 ()RUN 3

Fig. (1)RUN 3 NH4Cl(2) 0.4~0.6 kg N/m3-day 70%TN removal efficiencyTN VLRTN removal rateEff-NH4+-N

3-2 ()RUN 4

Fig. (1)RUN 4 200 mg N/L (2) 20%TN removal efficiencyTN VLRTN removal rateInf-NH4+-NEff-NH4+-N

3-2 ()RUN 5

Fig. (1)RUN 5 (2) HRT4.8 0.8~1mg/L100 mg N/L 0.7~0.1 kg N/m3-day50%(3)

3-3 () RUN 1

(1~25)2

Run1 OPhaseRun1Operation tim(day)1-25infeffNH4+-N(mgN L-1)481246.19.1NO2--N(mgN L-1)58.47.254.87.9NO3--N mgN L-1)2.41.72.11.7COD(mgO2 L-1 )112.313109.718.5TKN(mgNL-1)46.918.645.415

3-3 () RUN 2(26~62)336(mgN L-1)555(mgN L-1)33(mgN L-1)54(mgN/L)94(mgN L-1)-NO2--Nremoval/NH4+-Nremoval =1.620.32(=1.32)(VLR)=93492 mg N L-1 d-1(NRR)=76962 mg N L-1 d-1837%

Run2 OPhaseRun2Operation tim(day)26-62infeffNH4+-N(mgN L-1)33.4 5.72.63NO2--N(mgN L-1)554.74.73.8NO3--N mgN L-1)52.29.23.6COD(mgO2 L-1 )101.311.438.814TKN(mgNL-1)31.64.95.72.2

3-3 () RUN 3(63~95) (VLR)=2192530 mg N L-1 d-1(NRR)=1799441 mg N L-1 d-1825%>80% TN removal

Run3 OPhaseRun3Operation tim(day)63-95infeffNH4+-N(mgN L-1)94.633.715.116.7NO2--N(mgN L-1) 102.58.15.53NO3--N mgN L-1)22.233.218.83.6COD(mgO2 L-1 )149.323.836.421TKN(mgNL-1)8635.622.421.3

3-3 () (stoichiometry)(Strous et al., 1998) NH4+(-3)+1.32NO2-(+3)+0.066HCO3-+1.3H+ 1.02N2( 0)+0.26NO3-+0.066CH2O0.5N0.15+2.03H2O1.320.26. NO2-Nremoval /NH4+Nremoval 1.41(ANAMMOX)

1.(suger)org-N 16org-N50%90%

2.TMAHpH7~8

3.100 mg N/L 0.1mg/LCANON

4.

5.(VLR)2.20.5 kg N L-1 d-1837%

6.COD100 2 kg N L-1 d-1 80%

以生物處理技術處理含氮廢水之研究

Documents

Transcript of 以生物處理技術處理含氮廢水之研究

以生物處理技術 處理含氮廢水之研究

Documents

Transcript of 以生物處理技術 處理含氮廢水之研究

以生物處理技術處理含氮廢水之研究

Transcript of 以生物處理技術處理含氮廢水之研究