Test 3 Postponed until May 3 - Westfield State …...Aromaticity: the rules for aromaticity Section...

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Transcript of Test 3 Postponed until May 3 - Westfield State …...Aromaticity: the rules for aromaticity Section...

Test 3 Postponed until May 3

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Aromaticity: A special case of resonance Section 8.16 & 8.17

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Br2

Br2

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Aromaticity: A special case of resonance Section 8.16 & 8.17

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H2

Pt cat.

2 H2

Pt cat.

2 H2

Pt cat.

3 H2

Pt cat.

ΔHreaction (kcal/mol)per bond (kcal/mol)

cyclohexene –28.6 –28.6

1,4 cyclohexadiene –57.4 –28.7

1,3-cyclohexadiene –55.4 –27.7

benzene –79.8

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Aromaticity: the rules for aromaticity Section 8.16 & 8.17

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Aromatic? Section 8.16, 8.17, 8.18 8.20

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N O

HN

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Antiaromaticity: A case for avoiding resonance Section 8.19

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